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Showing 2 results for Akbari Jonoush
Removal of Uranium (VI) from aqueous solution by Uranium Benzamide Complex using AC_Fe3O4 Nanocomposite
Z Akbari Jonoush, M Farzadkia, S Naseri, H.r Mohajerani, A Esrafili Dizaji, Y Dadban Shahamat,
Volume 7, Issue 4 (1-2015)
Abstract

Background and Objectives: Increased growing nuclear industry has increased the researchers concerns on uranium presence in the environment and its effects on human health. Uranium is a dangerous radioactive heavy metal with high half-life and chemical toxicity. Therefore, the main objective of this study was to removal uranium (VI) from aqueous solution by uranium benzamide complex using AC_Fe3O4 nanocomposite. Materials and Methods: AC_Fe3O4 nanocomposite was synthesized using co-precipitation method. The experiments were designed as one factor at the time method. The optimum range of pH, contact time, amounts of adsorbent, and concentration of benzamide were determined. Then, kinetic and isotherm of uranium adsorption were studied. In addition, the properties of this adsorbent were characterized using scanning electron microscopy (SEM) and Fourier transform infrared (FTIR). Results: The SEM and FTIR analysis confirmed that activated carbon is coated with Fe3O4 nanoparticles and the magnetic property of AC-Fe2O3 was approved. According to the results, the optimum conditions were pH =6, contact time =30 min, and 0.06 g of adsorbent dose. The adsorption of uranium on the AC_Fe3O4 nanocomposite fitted to Langmuir isotherm and pseudo-second order kinetic model. The removal of U(VI) was increased about 6% with increasing in benzamide concentration to 50 mg/L. The best percentage removal of uranium in aqueous solution was 95%. Conclusion: The removal of U(VI) on AC_Fe3O4 nanocomposite with the aid of benzamide is a rapid and highly pH depended process. The maximum sorption capacity (15/87 mg/g) of AC_Fe3O4 nanocomposite shows that this method is a suitable method for Uranium removal.


Simultaneous removal of nitrate and microbial pollution from water by the electro-catalytic activity of iron and magnetic nanoparticles supported on nickel foam
Zohreh Akbari Jonoush, Abbas Rezaee, Ali Ghaffarinejad,
Volume 15, Issue 2 (8-2022)
Abstract
Background and Objective: This study aimed to provide an effective electro-catalytic system for the simultaneous reduction of nitrate and disinfection of contaminated water by the electro-catalytic performance of Ni-Fe/Fe3O4 cathode.
Materials and Methods: At first, the Ni-Fe electrode was synthesized by the electro-deposition process. Then its physical properties were analyzed by scanning electron microscopy (FESEM), X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) analysis, and photoelectron X-ray spectroscopy (XPS). Simultaneous disinfection and reduction of nitrate were performed under the following conditions: 15 mg Fe3O4 nanoparticles, pH 6.5, NaCl 10 mM, 50 mg/L nitrate, 105 CFU/mL and current density 4 mA/cm2.
Results: According to the results obtained in the absence of nitrate, 100 % of Escherichia coli bacteria were disinfected after 12 minutes. In the presence of nitrate, the time of complete disinfection increased to 120 minutes. In the absence of bacteria, 83% of nitrate was removed in 240 minutes, and in the presence of bacteria, the nitrate reduction efficiency increased slightly to 88%. In the nitrate reduction process, nitrite (0.22 mg/L) and ammonium (3.6 mg/L) were produced. In the presence of bacteria, the amounts of nitrite and ammonium produced increased to 0.42 mg/L and 7.3 mg/L.
Conclusion: The results show the outstanding ability of Ni-Fe/Fe3O4 electrode in electro-catalytic reduction of nitrate and disinfection of contaminated water separately and simultaneously with high efficiency and high selectivity to nitrogen.

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