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P Baratpour, G Moussavi, A Alahabadi, E Fathi, S Shekoohiyan,
Volume 10, Issue 2 (9-2017)
Abstract

Background and Objective: With industrial development and population growth, the emerging contaminants enter into the natural water resources. Therefore, adsorption potential of Ammonium Chloride-induced activated carbon (NAC) to remove metolachlor pesticide from contaminated water was investigated in this study.
Materials and Methods: The effects of operational conditions including solution pH, NAC concentration, metolachlor initial concentration and contact time on the removal of metolachlor by Ammonium Chloride-induced activated carbon (NAC) and standard activated carbon (SAC) were studied.
Results: Over 92.4% of 50 mg/L metolachlor was adsorbed using 0.3 g NAC/L within 5 min, and by increasing the reaction time to 60 min the removal efficiency reached to 100%. Under similar experimental conditions, standard activated carbon (SAC) could only adsorb 20% of metolachlor within 5 min and increase of contact time to 40 min caused the improvement of metolachlor adsorption onto SAC to 48%. The adsorption onto SAC was not influenced by the contact time over 40 min. Kinetic analysis showed that experimental adsorption data for both NAC and SAC were best fitted to the pseudo-second-order model. The maximum adsorption capacities of metolachlor onto NAC and SAC calculated by the Langmuir model were 344.8 and 238.1 mg/g, respectively.
Conclusion: Generally, these results showed that developed NAC was an efficient adsorbent with high removal efficiency for eliminating the halogenated pesticides from the contaminated water streams.
 
Ehsan Manavipour, Akbar Eslami, Abbas Shahsavani, Ahmad Alahabadi, Reza Saeedi, Fatemeh Shokri Dariyan, Mehrnoosh Abtahi,
Volume 17, Issue 1 (6-2024)
Abstract

Background and Objective: In today's society, preparing healthy food has become challenging due to the variety of food production methods. Oil is produced in several ways in our country. In the cold pressing method, there is insufficient monitoring of the manufactured product. The aim of the present study is to investigate the physicochemical characteristics and the levels of heavy metals of industrial oil compared to cold-pressed oil.
Materials and Methods: In this research, 54 samples of sunflower, sesame, and canola oil produced by both cold pressing and industrial refiningmethods were prepared. Their physicochemical characteristics, including refractive index, acid value, iodine value, saponification value, peroxide value, anisidine value, as well as the concentrations of lead, iron, arsenic and copper were determined. Additionally, the effect of storage time on these characteristics was investigated.
Results: The Iodine number showed the highest deviation from the standard (61%), with an average of 136.70 gI/100g for the cold-pressed oil and 134.48 gI/100g for industrially refined oiland. The average value of the physicochemical characteristics, except for the saponification value, were higher in the cold-pressed oil samples  compared to the industrially refined oil samples, but the observed difference was not statistically significant. An investigation into the effect of storage time on physicochemical properties revealed a significant increase in peroxide value (p<0.01) and anisidine (p <0.05) in both oil groups over a two-month period. The average concentration of arsenic, lead, iron and copper in the studied oils was 0.03, 0.78, 0.05 and 0.05 mg/kgoil, respectively. A deviation from the standard was observed only in one sample of cold-pressed sunflower oil, with an arsenic concentration of 0.11 mg/kgoil).
Conclusion: Based on the obtained results, the refined industrial oils exhibited more favorable chemical characteristics and stability.  It is suggested that cold-pressed oils should be consumed within a short period of time. For frying purposes, refined industrial oils are preferable.
 


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