Iranian Journal of

BackgroundandObjectives: Dyes are organic compoundswith complex structures,which due to toxicity, carcinogenicity and nonbiodegredabity, this type of pollutants is one of the most important pollutants of the environment. The goal of this researchwas to study the feasibility of the application of solar irradiation in presence of potassium persulfate (K2S2O8) for the removal of Reactive blue19 (RB19) from synthetic wastewater.

 Materials and Methods:This research wascarri edoutin laboratory scalewith using of 200ml volume of batchphotoreactor.The effectsofoperatingparameters suchas concentrationofK2S2O8,pH,photoexposure time and preliminary concentrations of dye on decolorization have been evaluated.Different concentrations of pollutant inwastewaterwere prepared by solution of variousmasses of RB19 on tapwater. The reactors were exposedwith natural solar irradiation as aUVAsource from11 amto 14 pm.Themaximumabsorbtion wave length of this dye (!max) was determined by spectrophotometer (Unico, 2100). The measurement of dye concentrations was determined with using of standard curve and its best line equation

Results:Analysis of absorbtion spectra showed that the !max of RB19 is 592 nm. The average intensity of the UVA irradiated from solar system was 54.6 µW/Cm2. The results of decolorization process showed that 38.2%of this dye can be removed within 3 hr in the presence of potassium persulfate and decreasing of pH leads to the elevation of dye removal efficiency. Based on these findings, the efficiency of dye removal with 3h photoexposure time and pH ranges of 4,6 and 8 were found to be 98.2 88.5 and 78.5%, respectively.Also, the results showed that increasing of K2S2O8 dosage leads to elevation of dye removal efficiency in 3h photoexposure time and K2S2O8 dosages within 1-5mmol/L, with the removal efficiency of 75,86,92,95 and 98.5%, respectively.Analysis of data indicates that the kinetic of the removal of RB19 with this process is a first order reaction which its rate constant is 0.01min-1.

Conclusion: Due to the operation problems presented in heterogeneous photocatalitical processes such as catalysts separation and high costs of operation and maintenance of these processes caused by manmade sources of irradiations homogeneous photocatalitical process with using of potassium persulfate associated with natural solar irradiation can be used as a suitable process for the removal of dyes from textile industries wastewaters.

Background and Objectives: Wet air oxidation (WAO) is One of the advanced oxidation process which reduce organic matter concentration from industrial wastewater, toxic and non biodegradable substances and, solid waste leachate,etc. In this study the efficiency of wet air oxidation method in leachate treatment generating from Esfahan Composting factory was Evaluated.
Material and Methods: The experiment was carried out by adding 1.5 Lit of pretreated leachate sample the steel reactor with the volume of 3L. The reactor then underwent10 bar pressure at different temperature (100, 200 and 300 °C) and various retention time (30, 60 and 90 min). Leachate sample in 18 stages from composting factory in Isfahan in the volume of 20 Lit was taken and the WAO method, was used for pre-treatments. Removal efficiency of COD, BOD, NH4-N, NO3 and TSS were examined.
Results: The results showed that the removal efficiency was more than 35% for COD, 38% for BOD, and 85% for TSS within one hour of reaction. The Maximum removal efficiency obtained in this study were 53.3% for NH4-N and 73.9 % forNO3-N.
Conclusion: the results indicate that the reaction temperatures are the most important factors affecting degradation of organic matter. COD and BOD5 removal efficiency by WAO process increased as the time of reaction went up. In addition, BOD5/COD ratios of the effluents, which are generally regarded as an important index of biodegradability of leachate sample, were determined and improved grately as it reached to 84%. TheWAO process presented in this paper is considered an efficient process for pretreatment of leachate, as the COD, BOD5 and NO3 reduction observed in leachate samples.

Backgrounds and Objectives: Wet air oxidation (WAO) is one of the advanced oxidation process which is mostly used to reduce organic matter concentration from industrial wastewater, toxic and non biodegradable substance and solid waste leachate.The objective of this paper is comparisons of three advance oxidation in organic matter removal in different conditions from Esfahan composing factory leachate
Material and Methods: The experiment was carried out by adding 1.5 Lit pretreated leachate sample to 3Lit autoclave reactor and adding 10 bar pressure at temperature of 100, 200 and 300 °C and pressure (10 bars) with retention time of 30, 60 and 90 min. leachate sample in 18 stages from composting factory in Isfahan in the volume of 20 lit was taken and the three methodsWAO, WPO, and a combination of WAO/GAC were used for pre-treatments. Pure oxygen and 30% hydrogen peroxide was used as oxidation agent.
Results: The result shows significant improvement on the removal rate of COD (7.8-33.3%), BOD5 (14.7-50.6%)by WAO process.The removal efficiency of 4.6-34% COD, 24-50% BOD, was observed in the reactor.Adding theGACto the reactor improved removal efficiency of all parameters.Combination Process (WAO/GAC) removed 48% of COD, 31-43.6% of BOD.Combination process demonstrated higher efficiency than two other previous methods as BOD5/COD ratio of 90% achieved.
Conclusion: The WAO process presented in this paper is efficient for pretreatment of leachate, And the modified WPO process remove organic materials and ammonia moreover WAO/GAC can be considered as an excellent alternative treatment for removing reluctant organic matter (COD, BOD5) and organic nitrogen compounds, which found in leachate.

Background and Objectives: Water complexes including Jacuzzi are among the most popular water recreation centers that noncompliance with health standards can lead to increased microbial growth in water and thus the risk of infection. This study aimed at comprehensive study of jacuzzis water in Yazd city and comparing the results with national and international standards. Materials and Methods: This was a descriptive - analytical study that statistical society included all Jacuzzis of Yazd city. Sampling of jacuzzis was performed every two weakes for 3 months (Summer 2011). We tested the water samples for parameters such as temperature, pH, amount of residual chlorine, turbidity, alkalinity, hardness, the population of heterotrophic bacteria, Staphylococcus aureus, Pseudomonas aeruginosa, fecal streptococci, and fecal coliforms accordance with standard methods. The SPSS software and ANOVA, T-test statistical tests, and/or Kruskal-Wallis, and Mann-Whitney were used for description of data and the obtained results were analyzed by comparing with standards. Results: we found that the mean of residual free and combined chlorine was equal to 0.628 and 0.337 mg/l respectively. The alkalinityand hardness were 141.928 and 275 mg/lCaCo₃ respectively. Mean of pH, turbidity and temperature were equal to 7.88, 0.457 NTU and 38.121˙C respectively.Moreover, the mean population of fecal streptococci bacteria, heterotrophic bacteria, Staphylococcus aureus, Pseudomonas aeruginosa, and fecal coliforms were 20465.7, 120.77, 209.91 and 7131.4 in 100 ml respectively. Statistical analysis of data showed that there is a direct relationship between water turbidity and pH (Pvalue=0.018) however, population of heterotraphic bacteria and residual free chlorine had indirectl relationship (Pvalue= 0.026). Conclusion: According to the results achieved, the parameters of heterotrophic bacteria population and alkalinity had the least compliance with the standard indicating the need for continuous monitoring of physical, chemical, and microbial parameters of Jacuzzi water and control of the number and density of people using Jacuzzi and continuous monitoring of Jacuzzi water filtration and chlorination process performance.

Background and Objective: Predicting municipal solid waste generation has an important role in solid waste management. The aim of this study was to predict municipal solid waste generation in Isfahan through time series method and system dynamics modeling.

Materials and Methods: Verified data of solid waste generation was collected from Waste Management Organization and population information was collected from the National Statistics Center, Iran for the period 1996-2011. Next, the effect of   factors on solid waste generation such as population, urbanization, gross domestic product was investigated. Moreover, the relationship between each of these factors was identified using generalized estimating equation  model. Finally, the quantity of the solid waste generated in Isfahan city was predicted using system dynamics modeling by Vensim software and time series method by ARMA technique.

Results: It was found that population and gross domestic product have a significant relationship with the amount of solid waste with P value 0.026 and 0 respectively. The annual average of municipal solid waste generation would be 1501.4 ton/day in 2021 estimated by the time series method and 1436 ton/day estimated by the system dynamics modeling. In addition, average annual growth rate achieved was 3.44%.

Conclusion: According to the results obtained, population and gross domestic product have a significant effect on MSW generation. Municipal solid waste generation will increase in future. Increasing solid waste is not the same in different areas and methods. The prediction of the time series method by ARMA technique gives precise results compared with other methods.