Iranian Journal of

Background and Objective: Vegetables are an essential part of our diet and a major dietary exposure route to heavy metals. Therefore, this study aimed to investigate the concentration and potential health hazards of heavy metals in the vegetables sold in Kashan markets.
Materials and Methods: 4 types of widelyraw-consumed vegetables, including parsley, coriander, basil, and fresh chives, were investigated in this study. Questionnaires were randomly given to individuals to determine vegetable consumption rate. Heavy metal were quantified using inductively coupled plasma- optical emission spectroscopy. Monte-Carlo Simulation was utilized to identify the associated health risks.
Results: Among tested heavy metals, Pb showed the highest concentration in parsley (4.8 ± 0.98 µg/g), coriander (3.8 ± 1.3 µg/g) and basil (3 ± 0.94 µg/g). Cr levels in fresh chives (2.8 ± 1.6 µg/g) was higher than other heavy metals. Also, the highest total hazard quotient values among examined heavy metals (Taking into account 95% confidence interval) were found for Pb (0.7), Cr (0.39), and Pb (1.034) in coriander, basil, and fresh chives, respectively.
Conclusion: Cr and Pb concentrations were generally beyond WHO/FAO guidelines in the samples. The THQ value for Pb in parsley was greater than 1, suggesting elevated adverse health effects due to parsley consumption.

Background and Objective:  The presence of pesticides in milk and dairy products poses a potential risk to consumers. The current study aimed to determine the concentrations of diazinon and cypermethrin in milk, cheese, and butter distributed in Gonbad-Kavus City.
Materials and Methods: A total of 50 samples including raw milk, pasteurized milk, ultra-high-temperature milk, traditional cheese, and traditional butter, were randomly collected from supply centers in Gonbad-Kavus from between 2021 and March 2022. The concentrations of diazinon and cypermethrin in the samples were measured using high-performance liquid chromatography (HPLC).
Results: The mean diazinon levels in raw milk, pasteurized milk, and ultra-high-temperature milk samples were 41.91 ± 9.68, 28.07 ± 5.86, and 40.21 ± 9.52 µg/kg, respectively. The mean cypermethrin levels in raw milk, pasteurized milk, and UHT milk samples were 34.06 ± 8.20, 22.63 ± 5.88, and 29.82 ± 8.09 µg/kg, respectively. Significant differences were observed among the sample types for both diazinon and cypermethrin levels. In cheese samples, the mean diazinon and cypermethrin levels were 57.23 ± 10.59 and 38.12 ± 8.69 µg/kg, respectively. In butter samples, the mean diazinon and cypermethrin levels were 16.77 ± 4.15 and 17.50 ± 6.47 µg/kg, respectively.
Conclusion: The results of the present study showed that the various types of milk distributed across Gonbad-Kavus contain excessive diazinon residues, while the residual cypermethrin levels were below the allowable limit. Therefore, a codified program to reduce diazinon the residuals in milk, cheese, and butter distributed in Gonbad-Kavus should be implemented.