Iranian Journal of

Backgrounds and Objective: In arid and semi-arid regions of the world, urban runoff as a source of water restoration and is considered valuable. Wastewater treatment, while preserving the environment, it can be considered as water source. The aim of this study to evaluate the possibility of using powder grain Peregrina in wastewater treatment in comparing with Alum and PloyAluminum Chloride (PAC).
Materials and Methods: Flocculation and coagulation tests were done by Jar test. Wastewater quality parameters were measured according to standard method.
Results: Studies have been showed that in optimum Peregrina concentration, efficiency of turbidity reduction, total hardness, calcium hardness, magnesium hardness, total E. Coli are 95.11, 38, 55.5, 46.6, 97 and 97 percent respectively. It is noted that turbidity reducing directly related with coli form reduction. As, with increasing turbidity reduction, coliform reduction is increased. The most reduction of E. coli with combination of Alum, Ploy Aluminum Chloride and Peregrina was 100 percent. In optimum concentration of Alum, Ploy Aluminum Chloride and Peregrina, the quality of treated wastewater would be in the range of environmental standards. Therefore, treated wastewater can be entering to surface water and reuse as irrigation water.
Conclusion: The results derived from this study showed that the treated wastewater can be use in a variety of irrigation except sprinkler irrigation due to burn the leaves of plants. (high electrical conductivity).Also, the low cost of seed Peregrina and good performance in the refining operations, it is suggested that Peregrina as a replacement for poly aluminum chloride and an alum to be used for wastewater treatment.

Background and Objective: The contamination of agricultural crops with heavy metals due to soil and atmospheric contamination is a potential threat for their quality and their safety. Heavy metals such as Cd and Pb have been reported for their carcinogenic effects. The aim of this study was to investigate the lead and cadmium concentration in some of crops grown in Isfahan province, Iran. Materials and Methods: During two seasons (spring and summer), 80 samples of four different crops (20 samples from each crop) were randomly harvested from some of the agricultural lands of Isfahan province. After sample preparation, lead and cadmium contents were determined by atomic absorption spectrometry. Results: The average concentration of Pb and Cd were different in different crops. A significant difference (p<0.05) was observed between mean concentration of lead in beetroot with onion and also cabbage whereas no significant difference was observed for lead between beetroot and lettuce (p>0.05). Means comparison showed a significant difference for cadmium between beetroot and cabbage and also beetroot and onion (p<0.001). Results showed that the concentration of Pb and Cd in most of the samples was higher than the standard limits reported by Iran (maximum tolerance of heavy metal in lettuce, cabbage, rootbeet and onion is 0.2, 0.3, 0.1, and 0.1 for lead and 0.1, 0.05, 0.05 and 0.05 UNIT for cadmium respectively) and FAO-WHO. Conclusion: The findings of this study indicated that although most of the sampling plants were contaminated with lead and cadmium, the estimated daily intake of each metal (EDI) showed that except lead in lettuce, other crops have EDI below the provisional tolerable daily intake (PTDI) recommended by the Institute of Standards and Industrial Research of Iran. In order to better management, preventing pollution and also finding the origin of elements, analyzing heavy metals content in soil, water, and dust of this region is recommended.

Background and Objectives: Increased growing nuclear industry has increased the researchers concerns on uranium presence in the environment and its effects on human health. Uranium is a dangerous radioactive heavy metal with high half-life and chemical toxicity. Therefore, the main objective of this study was to removal uranium (VI) from aqueous solution by uranium benzamide complex using AC_Fe3O4 nanocomposite. Materials and Methods: AC_Fe3O4 nanocomposite was synthesized using co-precipitation method. The experiments were designed as one factor at the time method. The optimum range of pH, contact time, amounts of adsorbent, and concentration of benzamide were determined. Then, kinetic and isotherm of uranium adsorption were studied. In addition, the properties of this adsorbent were characterized using scanning electron microscopy (SEM) and Fourier transform infrared (FTIR). Results: The SEM and FTIR analysis confirmed that activated carbon is coated with Fe3O4 nanoparticles and the magnetic property of AC-Fe₂O₃ was approved. According to the results, the optimum conditions were pH =6, contact time =30 min, and 0.06 g of adsorbent dose. The adsorption of uranium on the AC_Fe₃O₄ nanocomposite fitted to Langmuir isotherm and pseudo-second order kinetic model. The removal of U(VI) was increased about 6% with increasing in benzamide concentration to 50 mg/L. The best percentage removal of uranium in aqueous solution was 95%. Conclusion: The removal of U(VI) on AC_Fe₃O₄ nanocomposite with the aid of benzamide is a rapid and highly pH depended process. The maximum sorption capacity (15/87 mg/g) of AC_Fe₃O₄ nanocomposite shows that this method is a suitable method for Uranium removal.