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N Rouniasi , H Parvizi Mosaed,
Volume 9, Issue 2 (9-2016)
Abstract

Background and Objectives: Heavy metals are seriously dangerous for the human body and their accumulation in the body can cause pathological changes in the organs and this can result in cardiovascular, liver and bone diseases, and even cancer. Human is exposed daily to these pollutants via consumption of food and water.

Materials and Methods: Considering the cumulative properties of these metals in plant organs, the amount of Cr, Mn, and Fe in soil and leaf, stem, and root tissues of cabbage, lettuce, spinach, and onions in Karaj City were investigated. For this purpose, 15 samples were randomly collected from each part of the plants, and then, the density of heavy metals was measured via atomic absorption spectrometer after cleansing, grinding, drying, and acid digestion. The data were then analyzed using SPSS software.

Results: It was found that leaves of spinach, cabbage, lettuce, and onion have higher concentrations of Cr, Mn, and Fe rather than their stems and roots. The roots of plants contain the least densities of metals. Moreover, concentrations of Fe, Cr, and Mn in soil were 11.87, 3.99 and 17.78 mg/kg, respectively. This was due to the high transportation of these metals to air-related parts of the plant like leaves. This research also showed that the densities of Cr, Mn, and Fe in leaves of studied spinach, onion, cabbage, and lettuce exceeded the FAO/WHO standard limitations (0.15, 0.3, and 0.3 mg/kg for Cr, Fe and Mn, respectively).

Conclusion: Due to the high concentrations of Cr, Mn, and Fe in studied vegetables in Karaj City, the consumption of these kinds of vegetables by citizens must be taken into consideration by regulatory agencies.


N Rouniasi, Sm Monavari, Ma Abdoli, M Baghdadi, A Karbasi,
Volume 11, Issue 2 (9-2018)
Abstract

Background and Objective: Water pollution due to heavy metals is a critical and increasing problem worldwide. In this study, removal of cadmium and lead heavy metals using a graphene oxide (GO) adsorbent was examined.
Materials and Methods: GO nanosheets were synthesized through Hummer’s method, and its characterizations were examined using FTIR, XRD, and SEM. The effect of independent variables pH, contact time and initial concentration of the solution on removal efficiency of Cd2+and Pb2+ using response surface methodology was evaluated according to Box-Behnken experimental design. Applying quadratic model, adsorption rate of Cd2+ and Pb2+ achieved 99%. ANOVA was applied for statistical analysis of responses.
Results: According to SEM images, the average size of graphene oxide sheets was 1 to 3 µm. After optimization through RSM, the adsorption capacity for Pb2+ and Cd2+ was 136 mg/g and 68 mg/g, respectively. Examination of the isotherms suggested that Cd2+ and Pb2+ adsorption follows Langmuir and Freundlich isotherm, respectively.
Conclusion: the results show that the graphene oxide performed well in removing both Cd2+ and Pb2+ ions from aqueous solutions. The most influential parameters on the above-mentioned heavy metals adsorption were pH of the solution and the initial concentration.
 


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