Iranian Journal of

Background and Objective: Monitoring of traffic emissions is a good way to build a safe ecosystem for living organisms. Therefore, the present study was conducted to assess the feasibility of using Achillea wilhelmsii and Cardaria draba located along the suburban roads of Hamadan for Zn, Pb and Ni removal by their aerial and underground organs in 2020.
Materials and Methods: In this descriptive study, after selecting 3 sampling stations, a total of 126 plant samples and 63 soil samples were collected. In the laboratory, the samples were prepared, and were then digested with acid. Subsequentely, the concentration of each heavy metal was measured by inductively coupled plasma-optical emission spectroscopy (ICP-OES). Moreover, bioconcentration factor (BCF), bioaccumulation factor (BAF), transfer factor (TF) and metal accumulation index (MAI) were also calculated. Statistical analyses of the results were performed using SPSS statistical software.
Results: The mean values of BCF and BAF in both A. wilhelmsii and C. draba for all tested elements were greater than 1. On the other hand, A. wilhelmsii showed TF greater than 1 for zinc while C. draba showed TF greater than 1 for zinc and lead. The highest mean values of MAI in unwashed and washed shoots and roots of A. wilhelmsii were 98.48, 64.87 and 72.38, respectively.
Conclusion: Based on the calculated average values of BCF, BAF and TF of each elements, it can be argued that A. wilhelmsii and C. draba species have the potential of phytoextraction and Phytostabilization of the measured heavy metals and can be used for biomonitoring and bioremediation from soil and air in the heavy metals polluted areas.

Background and Objective: Limited water resources in arid and semi-arid regions are one of the major limiting factors in agricultural production. Thus, unconventional water resources, such as urban treated wastewater, may be used for irrigation. Application of wastewater to the soil may cause accumulation of heavy metals (HMs). Soil pollution causes uptake of these metals by plants and their entrance to the food chain. In the present greenhouse research, concentration variations of HMs (lead (Pb) and cadmium (Cd)( in soil and sweet pepper (Capsicum annuum) plant were investigated.
Materials and Methods: The experiment was conducted as a completely randomized design with three replications and irrigation with different wastewater treated (well water, wastewater treatment and diluted wastewater). To evaluate the effects of different irrigation treatments on soil, parameters of acidity (pH), electrical conductivity (EC), the concentration of heavy metals Pb and Cd in soil were studied.  Additionally, for the effects of irrigation treatments on sweet pepper plant, parameters of biomass weight, fresh and dry weight and Pb and Cd concentrations (in branches, fruits and roots) were measured. The amount of Pb and Cd in the pepper were measured by ICP-OES. The obtained average concentrations were compared using one-way analysis of variance (ANOVA), and the Duncan test was used to determine the differences between groups (p <0.05). The independent t-test was also used to investigate the difference in concentrations of Pb and Cd in soil and water (p <0.05).
Results: The results of chemical analysis of soil and pepper showed that irrigation with wastewater did not cause a significant increase in the concentration of Pb and Cd in the soil and in the branches, fruits and roots of the pepper. The concentration of Pb and Cd in the soil and in the branches, fruits and roots of the pepper was within the allowable and standard concentration range. The difference in lead and cadmium concentrations in the soil before planting was not significant; however, at the end of the study period, the Pb concentration in pepper was higher than the Cd concentration. The use of wastewater increased the fresh and dry weight of branches, fruits and roots of the pepper.
Conclusion: The results showed that Pb and Cd concentration in roots and aerial parts of pepper plant was not increased significantly as a result of wastewater irrigation (p <0.05). The results of this study are limited to one growing season and by the continued use of municipal wastewater, the concentration of Pb and Cd in the soil and then in the plant may exceed the standard. Especially in the case of Pb, which seems to have shown a slight tendency to increase relative to the primary soil and the pepper. Therefore, the continuation of this study is recommended to evaluate the long-term effects of Bushehr municipal treated wastewater on the concentration of heavy elements in soil and plants, and soil properties. Overall, it should be acknowledged that based on technical recommendations, the use of treated wastewater are not recommended.

Background and Objective: Today, soil and water pollution with heavy metals is one of the major challenges around the world. The aim of this study is to investigate the contamination of soils around a lead and zinc mine.
Materials and Methods: In the summer of 2019, 100 soil samples were taken from the mine vicinity and the characteristics of texture, acidity, salinity, calcium carbonate, organic matter and heavy metals chromium, cobalt, zinc, lead and cadmium were measured. Pollution indices including pollution factor (PI), enrichment coefficient (EF), geoaccumulation (Igeo), toxicity probability (MERMQ), contamination load (PLI), background enrichment (PIN), pollution security (CSI) and Nemerow index (PINemerow) ) Were calculated. Correlation between soil variables and determination of metal origin were determined using Pearson correlation and principal component analysis (PCA) analysis.
Results: The average concentrations of chromium, cobalt, zinc, lead and cadmium were obtained as 92, 21.33, 453.98, 351.24 and 4.28 mg/kg, respectively. The metals pollution evaluated based on PI, EF and Igeo indices were moderate for chromium and cobalt, considerable for zinc and significant for lead and cadmium. The results of MERMQ, PLI, PIN, CSI and PINemerow indices showed high soil contamination with heavy metals. According to the PCA test, the elements lead, zinc and cadmium are in a group with high correlation with each other that are of anthropogenic origin. Chromium and cobalt with a correlation of 88% also showed the same geological origin.
Conclusion: mining activities should be done with more caution and measures should be taken to reduce pollution.

Background and Objective: Due to the importance of Mordab river, the concentration and distribution of heavy metals in sediments and part of Caspian sea coast, mostly affected by the Mordab river, were evaluated. Additionally, considering the possibility of heavy metals release from sediments to water column and transfer to crops, the health risk of rice consumption in the region was assessed.
Materials and Methods: 21 sediments samples and 4 rice samples from paddy fields along the Mordab River were collected. Heavy metal contents of the samples were measured using ICP-MS. Data analysis was performed using enrichment factor (EF), ecological risk index (RI), health risk index, principal component analysis (PCA) and Mann-Whitney test.
Results: The maximum concentrations of elements was higher in coastal sediments than the Mordab River. The results showed low to moderate risk of elements in most stations except for two coastal stations which exhibited considerable risk of contamination with regard to Cr. Principal component analysis categorized the elements into three components of different origin. Moreover, the estimation of weekly intake of elements through rice consumption were less than their permissible concentration set by World Health Organization.
Conclusion: The concentration of chromium in sediments, especially coastal sediments, is high, which may be partly due to the concentration of heavy minerals (chromium) in this fraction. Therefore, the origin of elements, particularly chromium, should be determined through sequential extraction methods. On the other hand, despite the pollution of river sediments and high consumption of rice among the residents of the study area, there is no danger to rice consumers in terms of heavy metals.

Background and Objective: Heavy metal (HM) pollution of settled dust on the interior surfaces of elementary schools may affect the health of young students; hence, the health risk of such pollution should be assessed. Therefore, the aims of this study were to measure the content of heavy metals in the settled dust in the indoor of elementary schools in Bandar Abbas and to assess the attributed health risks.
Materials and Methods: In this study, dust samples were collected from the interior surfaces of elementary schools in Bandar Abbas. Settled dust samples were digested using aqua regia solution and then their metals contents were measured using ICP-OES. To assess the health risk attributed to this pollution, daily intake doses through ingestion, inhalation and skin absorption routes were estimated. Then, non-carcinogenic and carcinogenic risks were calculated considering the daily intake doses and toxicity factors.
Results: The average concentrations of arsenic, cadmium, cobalt, chromium, nickel and lead in settled dust were 5.45, 0.58, 11.44, 69.72, 83.95 and 66.72 mg/kg, respectively. The non-carcinogenic risk level for all metals was below threshold, while the carcinogenic risk level for arsenic (2.18×10^-6) exceeded the threshold.
Conclusion: This study showed that the settled dust in elementary schools of Bandar Abbas is polluted with various levels of heavy metals. Health risk assessment showed that the exposure to dust containing heavy metals in the elementary schools of Bandar Abbas does not pose significant non-carcinogenic risk, but the carcinogenic risk of As exceeded the threshold limit and should be considered.

Background and Objective: Environmental pollution with heavy metals and consequently their entry into food chains leads to irreparable damage to human health. The aim of this study was to determine the concentration of heavy metals including copper, zinc, lead and cadmium in blood and milk of grazing livestock around Zinc industry in Zanjan province (VSIPZ).
Materials and Methods: A total of 10 samples of grazing blood and milk were taken in each of the four geographical directions of the desired location. Also, in order to compare the current situation in the study area with the non-polluted areas, the control area (Qarah Poshtlu area of Zanjan) was considered. Dry ash method was used to digest organic matter.
Results: The results showed that the concentration of copper in the blood of cows and sheeps and the concentration of lead in the blood of cows in the west of VSIPZ was higher than the control group (p <0.05). There was no significant difference between the study areas and the control in terms of zinc and cadmium concentration in blood samples. Copper concentrations in cows and sheeps milk were lower than the control group in the southern and eastern regions of the VSIPZ, respectively (p <0.05). Zinc and lead concentrations in sheeps’ milk were higher than the control in the south and west of the VSIPZ, respectively (p <0.05).
Conclusion: In general, the results implied that the accumulation of lead in sheeps’ milk in the west of VSIPZ is more than maximum allowable concentration and can endanger the health of consumers.

Background and Objective: With the expansion of urbanization and the development of industry, environmental pollution, including sources of drinking water to heavy metals, has become a global problem. Therefore, the present study was conducted to measure the concentration of lead and cadmium in the water of Gorgan distribution network.
Materials and Methods: This is a descriptive cross-sectional study in which the concentrations of heavy metals lead and cadmium were measured in 25 different stations of the Gorgan drinking water distribution network from April to September 2018 by atomic absorption device. Statistical analysis was used from SPSS ver 22 software. Also, zoning maps based on the concentration of these two metals were prepared by Geographic Information System (GIS) software.
Results: The results of measuring the lead and cadmium concentration showed that all measured values are less than national and international standards. In general, the average concentrations of lead and cadmium were 4.38 and 0.1 μg/L, respectively. The results of Kruskal-Wallis test showed that there was a significant difference (p <0.01) between the concentrations obtained from lead metal in different months. Additionally, the distribution map of this lead and cadmium exhibited that in the central areas and some border areas, the concentration of these two metals is higher.
Conclusion: According to the obtained results, it can be seen that the concentration of heavy metals lead and cadmium in the water of Gorgan distribution network is within the permitted standards.
 

Background and Objective: The aim of this study was to investigate the concentration of potentially toxic elements (arsenic, lead, copper, cadmium and mercury) in black tea imported to southern Iran and to assess the risk of carcinogenic and non-carcinogenic exposure to consumers.
Materials and Methods: For this purpose, 94 samples of black tea from 15 brands imported from India in 2021 were selected. Heavy metals concentrations were measured using an atomic absorption spectrometer (GBC model SAVANTAA). After determining the concentration of heavy metals in black tea samples, health risk assessment was determined using Montocarlo simulation technique.
Results: According to the results, the average concentrations of heavy metals namely arsenic, lead, copper, cadmium and mercury were 0.03±0.02, 0.02±0.16, 15.67±7.69, 0.02±0.01 and 0.006±0.005 mg/kg, respectively. The hazard quotient (HQ) of the heavy metals arsenic, lead, copper, cadmium and mercury were 1.07×10^-2, 6.37×10^-3, 3.45×10^-5, 2.05×10^-2 and 7.19×10^-4, respectively.
Conclusion: Therefore, according to the findings, it can be concluded that the concentrations of potentially toxic elements (arsenic, lead, copper, mercury and cadmium) in black tea were consistent with the standard level of Iran and World Health Organization. Additionally, the average carcinogenic risk index for arsenic metal was 4.49×10^-6, which is much lower than the acceptable level of carcinogenic risk (10^-6). Therefore, the concentrations of five potentially toxic elements in the studied black tea did not show any significant risk for consumers.
 

Background and Objective: The city of Tehran is always exposed to adverse consequences due to the establishment of various sources of heavy metals. Therefore, the purpose of this study is to identify the types of heavy metals in airborne particles and the origin of heavy metals in the 21st district of Tehran.
Materials and Methods: According to the EPA standard, 5 stations from District 21 of Tehran were selected for sampling. Using the ASTM D4096 method and using a high volume sampling pump, 50 samples of total airborne particles were collected. The samples were transferred to the laboratory and the concentration of heavy metals was measured by ICP-OES. The UNMIX source model was used to identify heavy metal sources.
Results: The average concentration of heavy metals in 1400 is a decreasing trend including Li according to the concentration of heavy metals in the air in the SPECIATE database, the role of light vehicle sources was 47 percent 34 percent on the street and 18 percent at the airport.
Conclusion: The source of light vehicles exhibited the highest share of emissions and the element aluminum showed the highest concentration among heavy metals in Region 21. Therefore, the UNMIX source model can correctly identify index elements and priority sources for contaminant control.
 

Background and Objective: In some villages of Mazandaran, drinking water may be polluted with various pollutants, especially heavy metals (HMs), due to the shallow depth of drinking water sources and the proximity of these sources to farmlands. Therefore, this study aimed to measure the HM pollution level of drinking water in some villages of Mazandaran province and to assess the attributed health risks.
Materials and Methods: HMs content of drinking water in 30 villages with separate water sources in Mazandaran province was measured. Concerning the HMs concentration and toxicity, and exposure route through water drinking, carcinogenic and non-carcinogenic risks were assessed using a Monte-Carlo simulation-based method.
Results: The concentration values of arsenic, cadmium, chromium, nickel and lead in water were <1/0-4.26, < 0.05, <0.15-3.74, <0.3-10.89, and <0.8-4.68 µg/L, respectively. The hazard index (HI) values for non-carcinogenic risk due to the exposure to HMs through drinking of water in various age groups ranged from 3.04E-04 to 9.94E-04. Values of cumulative excess lifetime cancer risk (ELCR_T) for As and Cr were 9.72E-08 and 6.13E-08, respectively.
Conclusion: The results of this study showed that, fortunately, the concentration of metals in drinking water in the studied area was much lower than the national standards and the attributed health risk. Therefore, the drinking water sources in the studied villages had acceptable quality. However, due to the existence of rice paddies in some villages of Mazandaran province, continuous monitoring of pollution levels in the drinking water sources of these areas is essential.
 

Background and Objective: Due to the presence of heavy metals (HMs), sludge produced in industrial wastewater treatment plants (WWPT) is classified as special waste and can cause adverse health effects. The present study aimed to identify special wastes and assess the risk associated with the presence of HMs in the sludge of WWTP from an Industrial City.
Materials and Methods: Identifying the special wastes was conducted using a checklist, and classification was performed in accordance with the Basel Convention. Ecological risk assessment was done by determining the geo-accumulation and ecological indexes. The estimation of health risk was done by determining HQ and ELCR indexes.
Results: The highest amount of special waste was allocated to sludge with a value of 3900.0 kg/month. Chromium was detected in the highest concentration (95.89 ± 52.15 mg/kg). The level of chromium and nickel pollution was evaluated in the low range, and cadmium was very severe. The ecological risk of lead was estimated in a significant range and was very high for cadmium. The HQ was less than 1, and the ELCR for inhalation and dermal exposure was estimated to be lower than the acceptable risk level of WHO.
Conclusion: The present study showed that the largest amount of special waste is dedicated to sludge. Although the concentration of  HMs was lower than the acceptable limits, the sludge had a high ecological risk level. Therefore, the accumulation and transfer of sludge must be carried out under the provisions of the Basel Convention and environmental considerations.

Background and Objective: Soil contamination with heavy metals is the most important challenge and common environmental, economic, and public health issue in the world. Therefore, this research was conducted to evaluate the contamination and source identification of Fe, Zn, Cd, and Cr in the surface soils of Khorramabad county, west of Iran in 2020.
Materials and Methods: In this descriptive study, after dividing the study area into 11 homogeneous units, a total of 65 surface soil samples were collected. After preparing the samples, the content of the elements was determined using inductively coupled plasma-optical emission spectroscopy (ICP-OES). Also, enrichment factor (EF), pollution factor (CF), and Nemrow integrated pollution index (NIPI) were calculated. Statistical analyses of the data were performed using SPSS statistical software.
Results: The results showed that the average content of Fe, Zn, Cd, and Cr (mg/kg) in soil samples were 3.14, 1.13, 0.021, and 0.529, respectively. The EF values showed that the enrichment of Zn, Cd, and Cr was "extremely severe" and the average values of EF for the elements followed the descending order of Cd > Cr > Zn. The average values of CF and NIPI varied from 3.30×10^-5 to 0.182 and 0.043-0.136, respectively, indicating the level of "low pollution" and quality conditions of "no pollution" in all the studied stations. Based on the results of multivariate statistical analysis (PCC, PCA and HCA), Fe has a geological origin; while, Zn, Cd, and Cr mainly originated from a combination of geological processes and anthropogenic activities.
Conclusion: Although the average values of CF and NIPI showed that the study area has an acceptable soil quality, the values of EF indicated the impact of anthropogenic activities on soil contamination. Therefore, regular and periodic monitoring of soil samples as well as management and control of pollutant emission sources is recommended for maintaining environmental and human health.

Background and Objective: Heavy metals in water can pose risks to human health. Therefore, it is necessary to monitor and measure metals to ensure the health of consumers.
Materials and Methods: This study aimed to measure heavy metals such as arsenic, lead, cadmium, chromium, zinc, and mercury in water resources and urban water distribution networks in spring and summer of 2021 in Maragheh city. Accordingly, 25 samples were taken to investigate the presence of heavy metals. The presence of these metals in water sources was investigated using qualitative maps and finally, by evaluating the health risk caused by the presence of these metals, their effect on the health of consumers has been studied.
Results: Examining the concentration of metals in water resources upstream of the dam shows a relatively high concentration of metals, especially arsenic (13.2 µg/L). Despite this, the amount of arsenic after the water treatment plant and in the distribution network is reduced to an insignificant level. On the other hand, the results show that the amount of zinc metal in the network is higher than in the reservoir of the dam, and its concentration in the dam is equal to zero and in the network, it reaches the highest value of 578 µg/L. Finally, the health risk assessment shows that the calculated THI values for all samples vary between 0.01 and 0.99.
Conclusion: Based on the calculated health risk, there is no threat to the health of consumers regarding heavy metals in Maragheh drinking water. Also, these results double the necessity of additional studies regarding the leakage of zinc metal from the pipes and accessories of the city's drinking water distribution network in the future.
 

Background and Objective: Mining is one of the important economic activities all over the world. It causes the release of various emissions, especially heavy metals in the soil, due to the weak exploitation and improper disposal of mineral wastes. Different techniques are used for soil remediation and heavy metal extraction; including the electrokinetic method (so effective in fine-grained soils). In this research, the electrokinetic process was used to extract copper from the waste of the mine in Birjand.
Materials and Methods: In this research, a 24 cm long PVC reactor was used. The retention time was 2, 4, and 6 days and the voltage gradient was 1 V/cm. Graphite electrodes and electrolyte solutions of nitric acid and citric acid were investigated for copper extraction. The electrode polarity was alternately changed in order to pH control and improve the extraction process.
Results: According to the results, the highest removal efficiency (54%) was obtained after 6 days using 0.1 M citric acid and distilled water in the anode and cathode reservoir, respectively. Further, by 24-hour polarity reversing, the copper removal efficiency increased to about 60%.
Conclusion: The use of citric acid in anode was more effective than nitric acid, leading to more copper removal. In addition, by periodically polarity change and keeping the soil pH in the neutral range, further dissolution of the metal and reducing its sedimentation in the soil occurred. As a result, the rate of its transfer outside the treatment area and removal efficiency increased.
 

Background and Objective: During the last few decades, heavy metal pollution in indoor dust has been widely studied; While, the quality of the environment inside the cars has not been considered enough. Therefore, the specific objectives of this study generally include investigating the levels of selected heavy metals in the dust of private cars collected from Ahvaz city, as well as evaluating the health risk of carcinogenesis and exposure to the dust inside these cars through ingestion, inhalation, and skin absorption.
Materials and Methods: 10 cars were selected for this study. The condition of choosing the cars was not to wash the car for a week. Then, samples were collected and coded from the dust of the air conditioner filter and the cabin of each car. To determine the composition of heavy metals, spectroscopic analysis (ICP) was performed on the samples.
Results: The study of non-carcinogenic risk index (HI) in the present study indicates that the values of more than 1 and the health risk is high. The sequence of HI index values for heavy metals was obtained as  Pb>Cu>Cr> Fe> Zn> Cd> Ni. Evaluated risks from different pathways in children was HQ_ing < HQ_inhder while in adults follows HQ_ingder< HQ_inh process. Additionally, the values of enrichment factor of the studied samples showed the maximum and minimum values for Cu (4.3) and Ni (8.3), the maximum and minimum geoaccumulation index for Fe (12.75) and Ni (1.9) and the amount of integrated pollution and pollution index were estimated to be 1.34+E27 and 2.07+E9, respectively, indicating the average range for the studied heavy metals.
Conclusion: According to this study, the risk of non-carcinogenic risk of heavy metals (except Fe and Cu) for children is estimated to be higher than that of adults. Furthermore, the investigation of the CR index for the three carcinogenic heavy metals (cadmium, chromium, and arsenic) has exceeded the safe level, which indicates ingestion and inhale as the target pathways for the worst adverse effects of heavy metals in children andadults, respectively. In the present study, the amount of heavy metals studied is more than the set standards. The results of the current study showedthe more enrichment of heavy metals in the car filter as compared with  the cabin.
 

Background and Objective: Monitoring and remediation of metal contaminants in aquatic ecosystems is of particular importance to estimate, control, and reduce the level of threats to alive creatures and humans. Therefore, this study was conducted to evaluate metal contamination of surface sediments and the ability to monitor and bioremediation of iron, lead, and copper by aerial and underground tissues of Typha Latifolia and Nasturtium microphyllum located along the aquatic ecosystem of the Lar River, Tehran, Iran in 2021.
Materials and Methods: In this descriptive study, after selecting four sampling sites, 48 plant samples and 12 sediment samples were collected. After preparation and acid digestion of the samples in the laboratory, the contents of the elements were determined using inductively coupled plasma-optical emission spectroscopy (ICP-OES). Also, pollution index (PI), pollution load index (PLI), bioconcentration coefficient (BCF), bioaccumulation (BAF), and translocation factor (TF) were calculated. Statistical analyses of the results were performed using SPSS statistical software.
Results: The highest values of Fe, Pb, and Cu (mg/kg) in sediment samples were 11.8 ± 0.665, 0.915 ± 0.030, and 0.710 ± 0.026, respectively, and belonged to station 4; and in plant tissues 11.4 ± 1.25, 0.578 ± 0.180, and 0.298 ± 0.095, respectively, and were belonged to the roots of T. Latifolia. The PI values showed that the pollution of Fe, Pb, and Cu was "low" and the average PI values for the elements followed the descending order of Pb > Cu > Fe. The average values of PLI also vary from 0.003 to 0.006, indicating the quality conditions of "no pollution" in all the studied stations. On the other hand, T. Latifolia had a BCF > 1 and TF < 1 for Fe.
Conclusion: Based on the results obtained, it can be concluded that T. Latifolia is a suitable species for stabilizing Fe in sediments and could be used to monitor and remediate potentially toxic elements from polluted aquatic ecosystems.
 

Background and Objective: Heavy metals are dangerous pollutants in the environment that accumulate in food. This research was conducted with the aim of evaluating the health risks and contamination of some heavy metals in lettuce and cabbage in the cities of Hamidieh, Dezful and Ramhormoz in Khuzestan province.
Materials and Methods: The sampling was completely random, with three repetitions, and 15 samples of each of the lettuce and cabbage vegetables grown in each region were prepared. Heavy metals were measured using the Perkin Elmer 4100 atomic absorption device. Heavy metal risk assessment was conducted using soil pollution indicators and health risk assessment method.
Results: The highest amount of metal in cabbage is related to zinc (5.84±0.15 mg/kg), while the lowest amounts of chromium metal in lettuce (0.11±0.005 mg/kg) was achieved. Based on the daily absorption of heavy metals in lettuce and cabbage products, the results showed that the highest hazard index (HQ) values, ​​related to lead metal in cabbage for children and adults, were 3.9376 and 3.4253, respectively, compared to other heavy metals. The highest value of the carcinogenicity index in children was 0.0133 for cabbage consumption. The carcinogenic index of chromium metal in lettuce and cabbage products had the lowest values (0.0003 and 0.0004). Regarding the metal enrichment factor, lead, chromium, copper and cobalt were higher in the agricultural soils of Ramhormoz compared to other regions, while nickel and zinc were higher in the soils of Hamidiyeh than in Dezful and Ramhormoz. The soil index of accumulation of chromium, zinc and copper in the soil of Dezful agricultural fields was higher, whereas lead and cobalt were higher in Hamidiyeh soils than in Dezful and Ramhormoz. Additionally, nickel was higher in Ramhormoz agricultural fields.
Conclusion: According to the soil pollution indicators, cobalt metal played an important role in the soil pollution in Dezful, Hamidiyeh and Ramhormoz, while the metals lead, nickel, chromium, copper and zinc showed minimal pollution levels in the soil of the studied areas. The health risk assessment of soil heavy metals showed that the risk index for lead, nickel, chromium, copper, zinc and cobalt was lower than 1. Additionally, the carcinogenicity index of heavy metals for both adults and children was less than 10^-4. The health risk assessment of heavy metals and their risk index showed that the consumption of lettuce and cabbage in these areas can lead to various health problems in people.
 

Background and Objective: In today's society, preparing healthy food has become challenging due to the variety of food production methods. Oil is produced in several ways in our country. In the cold pressing method, there is insufficient monitoring of the manufactured product. The aim of the present study is to investigate the physicochemical characteristics and the levels of heavy metals of industrial oil compared to cold-pressed oil.
Materials and Methods: In this research, 54 samples of sunflower, sesame, and canola oil produced by both cold pressing and industrial refiningmethods were prepared. Their physicochemical characteristics, including refractive index, acid value, iodine value, saponification value, peroxide value, anisidine value, as well as the concentrations of lead, iron, arsenic and copper were determined. Additionally, the effect of storage time on these characteristics was investigated.
Results: The Iodine number showed the highest deviation from the standard (61%), with an average of 136.70 gI/100g for the cold-pressed oil and 134.48 gI/100g for industrially refined oiland. The average value of the physicochemical characteristics, except for the saponification value, were higher in the cold-pressed oil samples  compared to the industrially refined oil samples, but the observed difference was not statistically significant. An investigation into the effect of storage time on physicochemical properties revealed a significant increase in peroxide value (p<0.01) and anisidine (p <0.05) in both oil groups over a two-month period. The average concentration of arsenic, lead, iron and copper in the studied oils was 0.03, 0.78, 0.05 and 0.05 mg/kgoil, respectively. A deviation from the standard was observed only in one sample of cold-pressed sunflower oil, with an arsenic concentration of 0.11 mg/kgoil).
Conclusion: Based on the obtained results, the refined industrial oils exhibited more favorable chemical characteristics and stability.  It is suggested that cold-pressed oils should be consumed within a short period of time. For frying purposes, refined industrial oils are preferable.
 

Background and Objective: Identifying the quality of non-conventional waters and exploring their optimal utilization are fundamental measures for maintaining public health. This study aims to investigate the effluent quality of the irrigation canals in Pakdasht farms.
Materials and Methods: In this cross-sectional descriptive study, 120 samples were collected from 6 irrigation canals in Pakdasht fields over a period of 5 months. The physicochemical and microbial characteristics of the canal effluents were determined based on the standard methods of water and wastewater tests. The concentration of heavy metals was measured using an ICP device. To determine the possibility of using the effluent of Pakdasht canals for agricultural purposes, the Environmental Protection Organization of Iran and FAO standards were used.
Results: The average concentrations of COD, BOD₅, TSS, TDS, NO₃^-, SO₄^-2, PO₄^-3 parameters were 259, 125, 105, 697, 4.5, 94.4, 13.5 mg/L. Additionally, the average number of total and fecal coliforms in the effluent of the canals exceeded the standard values set by IRNDOE and FAO. The mean pH was 6.97, the electrical conductivity (EC) was 1014 μm/cm, and the turbidity was 76.2 NTU. The detected concentrations of heavy metals were awithin the following ranges: Cr (0.025-0.045 mg/L), Cd (0.0006-0.001 mg/L), Pb (0.0006-0.001 mg/L), Co (0.038-0.059 mg/L), and Ni (0.05-0.06 mg/L), which were roughly lower than the suggested standards. However, both HEI and WWQI indices confirmed that the water was unsuitable for agricultural irrigation.
Conclusion: Based on the comparison of the results of the parameters measured in this study with the environmental and FAO standards, the effluent from the irrigation canals of Pakdasht city is deemed unsuitable for the irrigation of warm-season crops but suitable for fodder and industrial crops.
 

Background and Objective: Heavy metals are regarded as serious contaminants due to their toxicity, persistence in natural conditions, and ability to enter and accumulate (bioaccumulation and biomagnification) in food chains. The aim of this study was to investigate the concentrations of the heavy metals Pb, Cd, Cu, Zn, Cr, Fe and Ni in surface agricultural soils of the Miandoab landfill area.
Materials and Methods: In this study, 57 soil samples were collected from a depth of 0-20 cm. After preparing and digesting in the laboratory, the samples were analyzed using a inductively coupled plasma spectrometer (ICP-OES). The Ecological Risk Potential Index (EPRI), Earth Accumulation Index (Igeo), Principal Components Test (PCA) Pearson's Correlation, Cluster Analysis, and One-T-test were utilized. Statistical processing was conducted using SPSS software.
Results: According to the results of the single T-test, the average concentrations of Pb, Cd, Cu, Zn, Cr, Ni did not significantly differ from their background concentration in the soil (p≥0.05). A significant difference was pbserved only for Fe (p<0.05), indicating a geological origin for this element. The EPRI was within the low-risk range, with an average value of 46.95. PCA revealed that the first factor was positively associated with Cr, Pb and Fe; the second factor with Zn and Cu; and the third factor with Cd. Cluster analysis showed that Fe was predominantly influenced by natural resources. According to the land accumulation index, all metals, except Cu, were classified non-polluted or slightly polluted at stations 2 and 4.
Conclusion: The origin of elements is related to both natural and human factors. Specifically, Cr, Pb and Cd are more likely to originate from man-made sources, while Fe primarily comes from natural sources. The decrease in the concentration of metals can be attributed to continuous and annual ploughing, inactivity of the landfill, biological absorption by crops, soil leaching and transporting to lower depths.