Showing 68 results for Heavy Metal
N Sistani, M Moeinaddini, N Khorasani, Ah Hamidian, Ms Ali-Taleshi, R Azimi Yancheshmeh,
Volume 10, Issue 1 (6-2017)
Abstract
Background and Objective: Urban and industrial development has increased concentration of heavy metals in the environment. The goal of this study was to assess the impact of Kerman steel complex on their surrounding soil by heavy metals.
Materials and Methods: This study was a snapshot and its type was descriptive-analytical research. Heavy metals contents from 60 soil samples (top soil, 0-15 cm) near two Steel Complexes were analyzed using flame atomic absorption spectroscopy (AAS). Source identification and pollution degree indices including enrichment factor (EF) and its percentage (EF%), geo-accumulation index (Igeo), contamination factor (Cf), degree of contamination (Cd) and modified degree of contamination (mCd) were calculated to assess the soil pollution level.
Results: The average concentration of Ni, Zn, Fe, Pb, Cr and Cd were 9.98, 54.38, 15063.33, 20.86, 3.54 and 0.038 mg/kg, respectively. The order of average EF for heavy metals was Pb > Zn> Cd> Fe> Ni> Cr. Cf index also showed that 90% of the samples were moderately to significantly polluted with lead element. The results of EF% indicated that Fe (68.18%) had higher enrichment than others. The average values of Cd and mCd indices were 2.90 and 0.48, respectively, that showed low degree of pollution.
Conclusion: In this study, Pb and Cd concentration were related with activities of the steel complexes and other metals had a combination of natural and anthropogenic emission sources. The steel complexes should plan to reduce pollutants emission to their environment.
A Nazarpour, N Ghanavati, T Babaenejad,
Volume 10, Issue 3 (12-2017)
Abstract
Background and Objective: The aim of the present study was to investigate the concentration, enrichment factor, Nemrow integrated pollution index, and potential ecological risk of heavy metals including (Pb, Ni, Cu, Zn, Cd, V and Cr) in surface soils of Ahvaz oil filed.
Materials and Methods: For this purpose, 49 soil samples with a systematic scheme from Ahvaz oil field were analyzed by atomic absorption method.
Results: The mean concentration of heavy metals was as follow: Pb (251.20), Ni (94.6), Cu (75.80), Zn (132.84), Cd (0.69), V (4.97) and Cr (141.48) (mg/kg). The average value of enrichment factor in the soil samples decreased as Pb>Ni>Cu>Cr>Zn>Cd>V. Nemrow integrated pollution index (NIPI) indicated high level of pollution for the studied heavy metals except V. The Potential ecological risk of the studied heavy metals showed a low potential ecological risk for V, Cd, Zn and Cr; Cu showed a moderate risk and Ni and Pb indicated a considerable ecological risk. The mean value of the risk index indicated that 27 (55.10%) of the soil samples with a moderate risk, 21 (42.85%) with a considerable risk and one sample (2.05%) with a high ecological risk.
Conclusion: The obtained results from the enrichment factor, Potential ecological risk, and risk index indicated that the main source of heavy metals in the study area were anthropogenic sources such as oil drilling activities.
B Mohammad Moradi, S Sobhanardakani, M Cheraghi,
Volume 10, Issue 4 (3-2018)
Abstract
Background and Objective: Heavy metals are the most frequent pollutants of urban soils. In general, human health and especially children are directly at risk if the soil is being accidentally ingested orally or nasally. Therefore, this study was conducted to assess potential ecological risk index (RI) of Pb, Cd, Cr and Cu in surface soils of urban parks in Tehran City in 2016.
Materials and Methods: A total of 60 surface soil samples were collected from Mellat, Laleh, Velayat, Ekbatan and Pirouzi parks. The heavy metals contents in samples were determined using ICP-OES after acid digestion of soil samples. Also, RI of heavy metals was determined. All statistical analyses were performed according to the Shapiro-Wilk test, One-Way ANOVA, One Sample T-Test and Pearson Correlation Coefficient.
Results: The lowest and highest contents of the metals (mg/kg) with an average of 0.52 ± 0.25 and 153.81 ± 31.83 were related to Cd and Pb, respectively. Pb and Cu were higher than MPL. Also, the highest surface soil contamination was related to Velayat Park located at the south of Tehran. The value of RI was 99.16 and therefore the soil contamination was categorized in low ecological risk.
Conclusion: Although the value of RI categorized as low ecological risk, due to mean concentrations of Pb and Cu were higher than MPL, control of soil-contamination sources, periodic monitoring of surface soil in the urban parks where citizens spend most of their free time. Additionally, it should be avoided to construct urban parks close to the regions with high traffic intensity.
Z Nejatijahromi, Hr Nassery, M Nakhaei, F Alijani,
Volume 10, Issue 4 (3-2018)
Abstract
Background and Objective: Irrigation of agricultural lands with treated wastewater in the main part of the Varamin plain, the highly populated urban areas of the middle part of the plain, and the presence of industries have increased the actual risk of heavy metal contamination of groundwater. Therefore, the concentrations of heavy metals were investigated in this study in order to assess the risk of using groundwater of Varamin aquifer for drinking purposes.
Materials and Methods: A total of 78 groundwater samples were collected to measure the concentrations of Cu, Pb, Zn, Cr, Cd, Fe, Co, and Mn ions. The bivariate correlation analysis has been used to describe the correlation between hydrochemical parameters in the Varamin area. Heavy Metal Evaluation Index (HEI) and Heavy Metal Pollution Index (HPI) of the groundwater were determined to determine the feasibility of drinking supply in Varamin plain.
Results: The average concentrations of cadmium in dry and wet periods were 7.5 and 8 μg/L, respectively. In the wet period, the average concentration of lead in the groundwater of the Varamin plain was 12.5 μg/L. The concentrations of both heavy metals were more than the permissible amount for drinking. Pearson correlation analysis of qualitative data of the water samples of the Varamin plain showed a strong correlation between some heavy metals such as Pb and Co with Cd, Cu and Mn. This reflected a similar source of contamination of the groundwater, inter-correlations, and the same mobility behaviors in the aquifer media. The results obtained from HEI and HPI showed that the pollution of Varamin aquifer in most parts was not dangerous with respect to the heavy metals concentrations, but in some areas, significant variations in the concentrations of some metals can be observed.
Conclusion: It may be expected that the risk of groundwater contamination continues with respect to heavy metals due to the persistence of contamination sources in the Varamin plain. Hence, some measured should be taken with regards to the agricultural recycle water, dispose of domestic and industrial wastewater, and the quality of transferring treated effluent from Tehran to the plain.
H Izanloo, K Solaimani, K Shahedi,
Volume 10, Issue 4 (3-2018)
Abstract
Background and Objective: Important information can be obtained about the sources of pollutants in the atmosphere by studying the concentration of heavy metals in atmospheric precipitation.. Therefore, in this study concentrations of Pb, Zn and Cu were measured in samples of urban watershed of Bojnourd in autumn and spring seasons to help urban managers to control pollution in Bojnourd area.
Materials and Methods: This study was a descriptive and cross-sectional research. 24 samples of rain water were collected to measure heavy metals. The amount of heavy metals in the samples was measured using atomic absorption.
Results: Results showed that the pH was alkali in the Bojnourd urban watershed. Concentrations of Pb, Zn and Cu in rainwater in both autumn and spring were compared to international standards of WHO and EPA. The difference was significant (P <0.05) and was less than the standards values. Also, the results of the Pearson correlation test showed that the highest positive correlation was between zinc (r = 0.733) and copper (r = 0.190) in the samples of autumn and spring. This correlation was approved using hierarchical cluster analysis method.
Conclusion: The low levels of pH and low concentrations of heavy metals in comparison with global standards indicated low rainwater pollution to heavy metals. Thus, there is no a health threat to the people of the city. The concentration of heavy metals in the metropolitan area of urban watersheds had been higher than other basin levels and the most dominant contaminant was lead in the residential and commercial areas with the highest urban traffic. The pollution to heavy metals varied in different seasons and the value was higher in spring rainwater samples than the autumn ones.
Mh Dehghani, Gr Jahed Khaniki, R Fallah, N Khodamoradi Vatan, L Tabande,
Volume 10, Issue 4 (3-2018)
Abstract
Background and Objective: Heavy metals are toxic and can enter the food and thus the health of people who consume these kinds of foods may be affected. The aim of this study was to investigate the concentration of heavy metals in fruits and to estimate the exposure level of heavy metals by fruit consumption.
Materials and Methods: In this descriptive cross-sectional study, 60 samples (35 samples of apple fruit and 25 apricot fruit samples) were randomly collected from gardens around Zanjan and Mahneshan city in 2016. The concentration of Pb, Cd, Zn, and Cu were determined by atomic absorption spectrometer. Statistical analysis was done with SPSS software.
Results: The average concentration of the elements in the samples was as follows: Pb (0.121 mg/kg wet weight), Cd (0.052 mg/kg wet weight), Zn (10.63 mg/kg dry weight), and Cu (4.99 mg/kg dry weight). The average lead concentration in apple and apricot was, respectively, 0.17 and 0.057 mg/kg wet weight, cadmium 0.08 and 0.003 mg/kg wet weight, zinc 9.15 and 12.7 mg/kg dry weight, Copper 4.4 and 5.583 mg/kg dry weight. Furthermore, it was found that 28.3% of the samples were contaminated with Pb, 13.3% with Cd and 3.3% with Zn. Cu contamination was not detected above permitted concentration. The concentrations of heavy metals in Zanjan were more than Mahneshan and the concentrations of Pb and Cd in the apple samples were higher than the apricot samples but the concentration of Zn and Cu in the apricot samples were higher than the apple samples.
Conclusion: Heavy metals pollution was found in samples belonging to the gardens around the factories and mines of lead and zinc. However, there is no risk of non-cancerous diseases with the use of these fruits in accordance with the national standard declared per capita.
E Solgi, S Mirmohammadvali, M Solgi,
Volume 11, Issue 1 (6-2018)
Abstract
Background and Objective: Measurment of metals concentrations in scalp hair is a well known method for monitoring exposure to heavy metals, assessment of heavy metal poisoning, evaluation of nutrient levels and diagnoses of diseases. The present research was conducted to evaluate the concentrations of heavy metals in the scalp hairs of the local fishermen from Shif Island (Bushehr) and assess the effect of various factors on heavy metals levels in hair.
Materials and Methods: Thirty hair sampls were collected from fishermen of Shif Island. After sample preparation and chemical digestion, the heavy metals were analyzed by Atomic Absorption Spectrometer. The information required to evaluate the exposure was obtained via a questionnaire that was distributed among the fishermen.
Results: The concentration of Fe, Zn, Cu, Mn, and Ni were 72.79, 148.11, 8.6, 4.72, and 19.71 mg/kg, respectively. There were significant correlations among Zn, Mn, and Ni. In addition, the results showed that use of hair colour increased the metal concentrations.
Conclusion: Our findings recommend that the population of Shif area and neighbouring county may be exposed to some of these heavy metals, particularly Ni that is an industrial and oil pollutant. The most likely exposure pathways seemed to be fish consumption; however, more detailed studies should be performed.
N Ghanavati,
Volume 11, Issue 1 (6-2018)
Abstract
Background and Objective: The aim of the present study was to investigate risk of heavy metals on human health including (Pb, Zn, Cu, Cr, Cd, Ni, V, As and Co) in street dusts in Abadan.
Materials and Methods: 30 dust samples were collected from sidewalks of main streets of Abadan and analyzed by inductively coupled spectroscopy (ICP-OES) method.
Results: The mean concentration of the heavy metals was as follows: Pb (59.13), Zn (287.50), Cu (112.97), Cr (50.30), Cd (0.52), Ni (56.77), V (35.83), As (10.7) and Co (7.33) (mg/kg). The concentration of all of the heavy metals, except V, in the dust samples was several times higher than the field concentration (concentration in the earth's crust). The average value of the potential ecological risk of the heavy metals V, Cr, Zn, Ni, As, Cu and Pb was low and had a low potential ecological risk. Cd had a moderate potential ecological risk. Also, based on the average value of Risk Index, the samples were at medium risk. Cumulative non-carcinogenic hazard of all the heavy metals in the street dust was higher for children than adults. This indicates that children are more at risk for heavy metals than the adults. In both age groups, Cr had the highest risk of carcinogenicity and Pb had the lowest risk.
Conclusion: The results indicated that the main source of the heavy metals in the study area is anthropogenic sources such as traffic, industrial facilities and burning of fossil fuels.
T Naseri, N Bahaloo Horeh, Sm Mousavi,
Volume 11, Issue 1 (6-2018)
Abstract
Background and Objective: Batteries can be hazardous to the environment and human health due to their toxic compounds. In this study, for detoxification and recovery of metals from spent coin batteries, a two-step bioleaching using Acidithiobacillus ferrooxidans was investigated.
Materials and Methods: A number of spent coin batteries were powdered. The powder was added to the bacterial culture medium and after 12 days the concentration of leached metals was determined. For investigating the effect of how to add the powder on metals recovery, the gradual addition of powder to the medium was carried out. For this purpose, the powder was added to the medium every 48 h at a rate of 20 g/L until the pulp density of 100 g/L. All experiments were run in triplicate and the standard deviation was shown as an error bar in the graphs.
Results: With an increase in pulp density, the metals recovery rate reduced. The highest recovery rates for lithium, cobalt and manganese was 100%, 88% and 20%, in pulp density of 40 g/L after 12 days. Leaching of lithium, cobalt and manganese was 66%, 8% and 0%, if the powder was added gradually until pulp density of 100 g/L.
Conclusion: The two-step bioleaching using Acidithiobacillus ferrooxidans was an appropriate method for recovery of metals from spent coin batteries. Also, gradual powder addition to the medium did not have a positive effect on the metals recovery and on improvement of bacterial growth characteristics. The metals recovery in high pulp densities was mainly due to chemical leaching.
N Rouniasi, Sm Monavari, Ma Abdoli, M Baghdadi, A Karbasi,
Volume 11, Issue 2 (9-2018)
Abstract
Background and Objective: Water pollution due to heavy metals is a critical and increasing problem worldwide. In this study, removal of cadmium and lead heavy metals using a graphene oxide (GO) adsorbent was examined.
Materials and Methods: GO nanosheets were synthesized through Hummer’s method, and its characterizations were examined using FTIR, XRD, and SEM. The effect of independent variables pH, contact time and initial concentration of the solution on removal efficiency of Cd2+and Pb2+ using response surface methodology was evaluated according to Box-Behnken experimental design. Applying quadratic model, adsorption rate of Cd2+ and Pb2+ achieved 99%. ANOVA was applied for statistical analysis of responses.
Results: According to SEM images, the average size of graphene oxide sheets was 1 to 3 µm. After optimization through RSM, the adsorption capacity for Pb2+ and Cd2+ was 136 mg/g and 68 mg/g, respectively. Examination of the isotherms suggested that Cd2+ and Pb2+ adsorption follows Langmuir and Freundlich isotherm, respectively.
Conclusion: the results show that the graphene oxide performed well in removing both Cd2+ and Pb2+ ions from aqueous solutions. The most influential parameters on the above-mentioned heavy metals adsorption were pH of the solution and the initial concentration.
Y Abbasi, F Mirzaei, T Sohrabi,
Volume 11, Issue 3 (12-2018)
Abstract
Background and Objective: The main objective of this study was to evaluate the surface and deep distribution of Pb, Ni and Cu in the wastewater-irrigated area of south of Tehran using GIS and Hydrus. It was expected to find a comprehensive information of heavy metals distribution and their accumulation in the soil.
Materials and Methods: This study was carried out in wastewater-irrigated area of south of Tehran. Soil sampling from the top surface layer (0-15 cm) and wastewater channels was done. After sample analysis, ordinary Kriging method using different variogram in GIS was applied to explore the surface distribution of Ni, Pb and Cu heavy metals. Moreover, the deep percolation of heavy metals in the soil profile was simulated by Hydrus-1D in a duration of 210 days and the heavy metals concentrations in the soil were estimated.
Results: Exploration of the distribution of Pb using spherical model showed that the variation of this element was in the range of 20-70 mg/kg. This amount varied to 50-60 mg/kg for Cu and about 30 mg/kg for Ni. Moreover, the simulation of heavy metals deep percolation using Hydrus revealed that the most accumulation of heavy metals happened in the 0-15 cm soil surface layer and for deeper layer, this trend was descending.
Conclusion: Comparing the concentration of Pb, Cu and Ni with the maximum allowable amounts of WHO standards demonstrated that Pb concentration was more than the threshold limit. Finally, the applied models could simulate soil’s heavy metals content for both surface and deep distribution in the studied area.
M Moradi Baseri, H Kamani, Sd Ashrafi, E Bazrafshan, F Kord Mostafapour,
Volume 11, Issue 3 (12-2018)
Abstract
Background and Objective: Street dust is an important factor in urban pollution which consists of soil, particulate matters and heavy metals. At present, over half of the world’s population lives in urban areas. Therefore, this study aimed to investigate health risks of heavy metals in street dusts in Zahedan.
Materials and Methods: The samples of street dust were collected in Zahedan. After preparation, the samples, were injected to ICP-MS for determination the amount of Hg and Cu. According to the measured concentrations, Hazard quotient (HQ) and hazard index (HI) were calculated to evaluate the health risk assessment.
Results: Results showed that Hazard quotient for both Hg and Cu was less than 1 for children and adult. HQ for Hg and Cu was in order of HQingestion >HQdermal >HQinhalation> HQvapour for adults and HQvapour > HQingestion > HQdermal > HQinhalation for children. HI was also less than 1.
Conclusion: The value of HQ showed that inhalation of mercury vapor and ingestion were the main routes of exposure to Hg for children and adults. The non-carcinogenic risk was within the safe value (HI <1) in this study.
Ghr Siyahati Ardakani, M Mirsanjari, Hr Azimzadeh, E Solgi,
Volume 11, Issue 3 (12-2018)
Abstract
Background and Objective: The establishment of pelletizing and steel industries in Ardakan suburbs has increased the pollutants such as heavy metals into the environment. The purpose of this study was to investigate the contamination of the area soil by heavy elements around these industries using the pollution index (PI), comprehensive pollution index (NIPI), accumulation index (Igeo) and enrichment index (EF).
Materials and Methods: 57 soil samples were prepared by systematic-random sampling from 0 to 5 cm depth and levels of As, Cd, Cr, Mo, Ni, Pb, V and Zn were analyzed by ICP-OES.
Results: The highest and lowest mean of Igeo (0.49 and 0.36) and PI (2.16 and 1.17), were related to nickel, and the highest EF was calculated for Zn at about 25.1 and the lowest were detected for molybdenum approximately that was 17.1. The EF index of lead, vanadium and zinc, which was 15.8%, 5.3% and 1.8%, respectively, classified the study area in a medium enrichment class. Hot spots of lead, vanadium, nickel and zinc was at the nearest distance to these industries and downstream of wind direction.
Conclusion: Indicators of Igeo and EF showed a low level of soil pollution. The PI and NIPI indices in most stations were classified in medium pollution class, and the highest of these indicators was related to the surface soil of station 30, which was located near the steel industry. Therefore, it can be concluded that the activities of these industries had affected the soil contamination of the study area.
H Malvandi, N Hassanzadeh,
Volume 11, Issue 3 (12-2018)
Abstract
Background and Objective: Heavy metals contaminations are readily bioaccumulated in aquatic systems and lead to increased concentrations in food chains, posing a serious threat to human health, water-related organisms and aquatic ecosystems. The purpose of the present study was to determine the concentration of heavy metals in surface sediments of CheshmehKile River, to evaluate environmental and ecological risk and to determine the degree of contamination of the elements studied.
Materials and Methods: In this study, 25 samples of surface sediment were collected from the CheshmehKile River. The heavy metals content of the samples was measured by inductively coupled plasma-optical emission spectrometry. According to the content of heavy metals in sediment samples, environmental and ecological risk indices were calculated. Also, river contamination was evaluated by comparing the elements studied values with the sediment quality guidelines values.
Results: The mean concentration of chromium, manganese, iron, cobalt, nickel, zinc and arsenic were 41.27, 356.35, 16756.32, 9.17, 11.87, 41.24 and 24.60 µg/g, respectively. Based on the values of the CF and Igeo indices, all of the elements, with the exception of arsenic, showed a low degree of contamination. The indices of Eir and RI also showed the lowest ecological risk at all stations.
Conclusion: The results of this study showed that the surface sediments of CheshmeKile River in Mazandaran province were somewhat contaminated with arsenic. However, fortunately, the river sediments were of good quality from the point of view of the content of chromium, manganese, iron, cobalt, nickel and zinc.
S Mortazavi, M Hatami-Manesh, F Joudaki,
Volume 11, Issue 4 (3-2019)
Abstract
Background and Objective: Considering the toxicity, health and ecological hazards of heavy metals in the environment and the impact on organisms, it looks essential to measure and evaluate their concentrations at the various levels in indigineous ecological strctures. The present study evaluated the concentration of Lead, Nickel, Copper and Zinc and their ecological risk assessment in surface sediments of Sezar River in Lorestan province.
Materials and Methods: 16 stations along the Sezar River were selected for sampling. After preparation and acid digestion of the samples, the concentrations of these metals were determined by Atomic absorbtion.
Results: The average total concentration of the detected metals Ni, Zn, Cu and Pb in the sediment was 71.84 > 40.56> 7.75 > 5.61 mg/kg, respectively. In addition, the evaluation of the Potential acute toxicity, ecological risk, and Pollution Load Index represented a low pollution in the sediments. The environmental risk of the metals in the sediment was evaluated as: Ni> Pb> Cu> Zn. The findings showed that among metals, the contamination factor and modified hazard quotient (mHQ) for nickel was moderate and in the mediun to severe pollution level to the contamination, respectively.
Conclusion: According to the results, it can be concluded that Potential acute toxicity, pollution and ecological risk in the region for investigated metals were low. However, a rapid expansion of various human activities in the area and the pollution of nickel in the river along with the probability of its biological effects require continuous monitoring of the river in order to assess the health risk and its ecological risk.
H Abbaszadeh, M Mohammadi Roozbahani, S Sobhanardakani,
Volume 12, Issue 1 (5-2019)
Abstract
Background and Objective: Environmental pollution emitted from industrial areas while enter the food chain can cause serious adverse health effects. Therefore, this study was conducted to use Ziziphus spina-christi and Prosopis cineraria leaves as bio-indicators of environmental pollution emitted from the complex of Steel Company.
Materials and Methods: In this descriptive study, a total of 90 surface soil samples and also 90 leave samples were collected. After acid digestion of samples, the heavy metal contents were measured using atomic absorption spectrophotometer. Also, the Bioconcentration Factor (BCF) of metals were computed. All statistical analyses were performed using SPSS statistical package.
Results: The highest content of the metals (mg/kg) with an average of 2180.3 ± 202.3 and 2237.9 ± 315.1 for Fe, 76.6 ± 9.6 and 114.3 ± 4.5 for Pb and 69.2 ± 16.8 and 107.2 ± 6.8 for Cd were found to be in Z. spina-christi and P. cineraria unwashed leaves respectively. Also, the BCF of all studied metals were higher than 1.
Conclusion: Based on the values of BCF, it can be concluded that Z. spina-christi and P. cineraria can be considered as a suitable species for phytoextraction of heavy metals in the most polluted regions including industrial and urban areas.
F Jaffari, N Hassanzadeh,
Volume 12, Issue 2 (9-2019)
Abstract
Background and Objective: Research has shown that assessing the toxicity and ecological risk of various types of pollutants, including heavy metals, using specific indicators, is indispensable in the ecological risk assessment of the ecosystem. Accordingly, the aim of this study was the assessment of the ecological effect of heavy metals presence (Pb, Zn, Cu, Cd and, As) in Anzali wetland using Heavy Metals Pollution Index (HPI).
Materials and Methods: 43 water samples were collected from the eastern, western and central parts of Anzali wetland. The samples were transferred to the laboratory, and the preparation steps were carried out using the ASTM method. Concentration of the elements was determined by Inductively Coupled Plasma -Atomic Emission Spectroscopy (ICP-AES). According to the concentration of heavy metals in the water samples, the index (HPI) was calculated. The results of the HPI index were classified into three classes: low risk (<15), moderate (15-30), and high risk (> 30).
Results: The numerical value of the HPI index was 3.59-23.3 with an average of 27.97, indicating the average level of heavy metals pollution in Anzali wetland. Indicator (HPI) in the eastern part of Anzali wetland and the Pirbazar area showed a severe contamination and ecological hazard of the heavy metals and in the Abkenar region showed an acceptable ecological status.
Conclusion: Although the average of HPI in the whole Anzali wetland was modest, but at some stations, especially in the east of the wetland, the HPI indicates the occurrence of ecological hazards in the wetland in the event of uncontrolled entry of pollutants in future. Therefore, monitoring the sources of these pollutants entering to the wetland and controlling the ecological risks is necessary.
Z Farahbakhsh, A Akbarzadeh, P Amiri, A Naji,
Volume 12, Issue 2 (9-2019)
Abstract
Background and Objective: Heavy metals enter to water resources through various ways, causing dangers such as illness, cancer, and, in general, a disorder in the body of living organisms. Mullet (Liza aurata) is highly consumed by the people living in Guilan province, Iran. Therefore, the amount of heavy metals included copper, zinc, and nickel was investigated in the muscle tissue of mullet.
Materials and Methods: A total number of 11 mullet were obtained from Bandar Anzali. After a preparation step, the fish samples were digested using chemical digestion, and the amounts of heavy metals were determined by atomic absorption.
Results: The average concentration of copper, zinc, and nickel in muscle tissue was 10.07±0.93, 28.39 ±3.99, and 4.01 ± 0.55 μg/g dry weight, respectively. The concentrations of the studied metals were lower than the FAO, WHO, FDA, NHMRC and UKMAFF international standards, except for the nickel. The daily absorption rates of the studied metals (EDI) for children and adults were lower than the reference dose set by the EPA and the TI provided by the FAO / WHO Organization. The risk potential (THQ) of seven days, three days and one day consumption per week of Golden grey mullet for both adults and children were found less than 1. The hazard index (HI) of 7 days a week consumption of mullet for children was greater than 1.
Conclusion: According to the results of the present study, the consumption of this fish has a harmful effect on consumer health in children age group.
S Shojaee Barjoee, Hr Azimzadeh, A Mosleh Arani,
Volume 12, Issue 4 (2-2020)
Abstract
Background and Objective: Non-biodegradation in nature and creation of adverse health effects in humans is important features of heavy metals. The main objective of this study was to determine the level of contamination, carcinogenic and non-carcinogenic risks of falling dust containing heavy metals on residents around the industrial areas of Ardakan. Another objective was to identify potential sources of heavy metal release into the environment.
Materials and Methods: In this cross-sectional analytical study, the falling dust was collected in summer around Tile and Ceramic, Khak-e-chini, sand and gravel and glass industries by installing 35 Inverted Frisbee traps with artificial grass cover. The concentration of Cd, Ba, Cu, Ni, Cr, Mn and V were measured by ICP-MS. Probable sources of the heavy metal of the dust were evaluated using Pearson correlation coefficient and cluster analysis. Ecological risk indices for determining the level of contamination and proposed relationships proposed by the US Environmental Protection Agency were used to assess the carcinogenic and non-carcinogenic risks.
Results: The highest and lowest mean concentrations of heavy metals were measured for Cd and Ba, respectively. The results of Pearson correlation analysis and cluster analysis revealed three anthropogenic and also natural sources for heavy metals of the falling dust. According to the Ecological Risk Potential Index, Cd in 45.10% of the samples was in a very high class and in 54.88% of the samples was a high class. Pollution class of the ecological risk index of all the heavy metals was medium to high. The carcinogenic risk of Cr and Ba in children and adults was estimated to be higher than 10–4. In both age groups, the Hazard index for each metal was less than 1 and its sum was measured as 1.29 for children and 0.16 for adults.
Conclusion: Cd increases the ecological risk of the falling dust in the area. Ther heavy metal carcinogenic risk results showed that the concentrations of Cr and Ba were higher than standard. Also, the non-carcinogenic risk was higher in children than in adults.
A Atamaleki, N Naimi, Y Fakhri, H Sharifi Maleksari, H Nosrati, S Fallah,
Volume 12, Issue 4 (2-2020)
Abstract
Background and Objective: Nowadays, water shortage crisis leads to wastewater reuse in agriculture sector. The presence of pollutants such as heavy metal in wastewater results in the accumulation of them in vegetables, and it will finally be transferred to consumers and will have irreversible effects on their health. Therefore, the present study was performed to do a systematic review along with meta-analysis on heavy metal accumulation in mint plant that is irrigated with wastewater.
Materials and Methods: Related articles were collected from databases like SID, Magiran, Iranmedex, IranDoc, Embase, Medline, PubMed, Web of Science, Scopus, and Google scholar between 1982 and 2019 and the required data were extracted. Then, due to the heterogeneity of studies entered in the research, a random effect model was applied to analyze them using STATA 14 software. Non-carcinogenic risk was assessed for children and adults.
Results: According to the search results, 1693 articles were entered in the review process until the beginning of 2019 and finally only 12 articles were included in the research. According to the results of the meta-analysis, the order of the metals based on concentration (mg/kg) were: Zn > Ni > Cr > Cu > Pb > Cd. Also, based on the non-carcinogenic risk assessment results, mint consumption showed a significant health effects on children age group compared to adults, especially in India and Pakistan.
Conclusion: wastewater reuse in agriculture sector leads to increase concentration of metals in vegetables like mint. This increased the risk of non-carcinogenicity in the age groups, especially children. Therefore, it is recommended that continuous monitoring of irrigation sources, soils, and vegetables is done to prevent the transmission of these pollutants to the human food cycle.
