Showing 46 results for Process
Reza Shokoohi, Salah Azizi, Said Amir Ghiasian, Javad Fredmal,
Volume 7, Issue 2 (10-2014)
Abstract
Background and Objectives: Pentachlorophenol (PCP) is an organic compound and phenolic derivatives categorized as priority pollutants that have harmful effects on humans, animals, and plants in low concentrations. Therefore, PCP removal from water and wastewater is very important. The aim of this study was to assess the efficiency of A. niger fungus biomass in PCP absorption. Materials and Methods: This was an experimental study in which different steps of the experiments were performed. A. niger strain was prepared from Persian Type Culture Collection of Iranian Research Organization for Science and Technology (IROST). After activation in potato dextrose agar (PDA) culture plates, fungi were incubated for 7 to 10 days at 25 °C. The prepared A. niger biomass was modified by NaOH and then it was used for PCP absorption assay. The concentration of PCP was measured using high-performance liquid chromatography. Results: The findings of present study showed that contact time is an important and effective factor in the PCP absorption rate. Two hours was selected as the optimum retention time in this experiment and after that the removal percentage did not raise significantly. The results of PCP absorption in different pH demonstrated that the adsorption efficiency decreases by rising pH and initial PCP concentration. The effects of contact time, pH and initial PCP concentration on the absorption process was significant (P-value <0.001). Conclusion: The results show that absorption efficiency increases by rising retention time under constant conditions. In addition, at low pH the modified A. niger biomass could be a good absorber for PCP.
S. A. Mirzaee, M.m Amin, M Sarafraz, M Heidari, M.m Ahmad Moazzam,
Volume 7, Issue 4 (1-2015)
Abstract
Background & Objectives: Disposal of pharmaceutical compounds to environment as an emerging pollutants cause concerns significantly and it is necessary to use new methods of sewage treatment for removal of these compounds. The aim of this study was to investigate the inhibition effects of metronidazole before and after using UV254/H2O2 process on specific methanogenic activity of.anaerobic biomass. Materials & Methods: Fourteen anaerobic digestion tests were carried out at batch scale before and after using UV254/H2O2 process in 500 ml reactors with 30% anaerobic biomass and 70% substrate. The liquid displacement method was used. Duration of each test was in the range of 10-17 days. Results: Cumulative Biomethane production in concentrations of 1, 5, 10, 25, 50, and 100 mg/l metronidazole was 34.04, 95.12, 100.86, 3.28, 27.88, and 6.97 ml respectively. This production was 800.73, 243.54, and 10.66 ml in concentrations of 25, 50, and 80 mg/l respectively using UV254/H2O2 process as pretreatment at 60 min retention time. Biomethane production in concentrations of 80,120, and 150 mg/l was 377.2, 380.48, and 63.14 ml respectively at 90 min retention time. Conclusion: Different concentrations of metronidazole had an inhibition effect on anaerobic digestions and therefore the efficient pretreatment method is needed to reduce this inhibition effect. The UV254/H2O2 process is an effective method for degradation and conversion of metronidazole to more biodegradable compounds for anaerobic bacteria consumption and, in turn, to increase biogasproduction in anaerobic digestions.
A Shahbazi, F Bagheri Zonoz, H Aboomaash-Zadeh,
Volume 8, Issue 1 (8-2015)
Abstract
Background and Objectives: Although amount of hospital waste generation is less than urban waste generation, but because of health risks involved, these wastes need to be managed precisely and specifically. Therefore, the purpose of this study was to survey quality and quantity of waste generation in Emam Khomaini Hospital, Karaj, Iran and to estimate its generation process in future. Materials and Methods: the total amount of different waste percentage and its weight were examined and analyzed through monthly sampling from segregated waste (including general, infectious, pharmaceutical, and sharp wastes) in Emam Khomaini Hospital in Karaj during four years (2010-2013). Results: the hospital waste generation rate became double during four years of study. Among different types of waste, the highest monthly averages per bed for general and infectious waste was 48.3 and 46.5% respectively. In addition, the most and least amount of waste generation was observed in April and September respectively. Analysis of variance showed that the increasing trend of waste generation had a significant difference (P<0.001). Moreover, the estimate of waste generation process through ARIMA time series model represented continuation of increasing trend of waste generation up to 6.3 (kg bed-1 day-1) on December 2014. Conclusion: Waste generation in Emam Khomaini’s hospital follows an increase trend ( average generation from 2.98 to 4.44 kg bed-1 day-1 in 2010 to 2012 respectively, reflecting the increasing trend in the waste generation. ARIMA time series model shows that the waste generation rate would be 1.5 fold more in autumn 2014. Estimate of waste generation is necessary for planning and designing of waste management.
Sar Mousavi, M Parvaneh,
Volume 9, Issue 2 (9-2016)
Abstract
Background and Objectives: Conventional methods of leachate treatment are inefficient due to high pollution loads and characteristics of the leachate. In recent years, an integrated method has been developed considerably. The aim of this research was to evaluate the effect of powdered activated carbon on the treatment of landfill leachate of Kermanshah City by a columnar aerobic sequencing batch reactor.
Materials and Methods: This study was carried out in three reactors having a total volume of 2000 mL and each having an effective volume of 600 mL in the bench scale. To the reactors 2 and 3 that were similar from environmental conditions and operation point of view with reactor 1 (with no carbon powder), 5 and 10 g/L of PAC were added, respectively. The effects of different doses of PAC (0, 5, 10 g/L) and hydraulic detention times (HRT = 48, 96, 144 h) were investigated in order to remove the Chemical Oxygen Demand (COD) and ammonia nitrogen (NH3-N) from the leachate. The efficiency was investigated using two -way ANOVA test in SPSS software (Ver. 16).
Results: The results of two-way ANOVA showed that there was a significant difference (P-value=0.001) between the removal efficiency of COD and NH3–N at different HRTs with different doses of PAC. The highest removal efficiency achieved at HRT=144 h for COD and NH3-N was in Reactor 1 were 50.11 ± 4.42 and 19.85 ± 1.49%; in reactor 2: 55.67 ± 1.6 and 25.7 ± 0.89%; and in reactor 3: 58.02 ± 3.99and 25.48 ± 1.7%, respectively.
Conclusion: It can be concluded that the combination of biological - activated carbon compared with the biological process, can remove COD and NH3–N of strong sewages such as landfill leachate, although achieving standard treatments using this method is not possible.
V Past, K Yaghmaeian, R Nabizadeh Nodehi , Mh Dehghani, M Momeni, M Naderi,
Volume 10, Issue 2 (9-2017)
Abstract
Background and Objective: Environmental pollution due to dumping construction and demolition wastes has adverse effects on public health. This study aimed to select the best method for managing construction and demolition wastes disposal in Tehran by AHP.
Materials and Methods: This research was a descriptive study. The study population consisted of environmental health experts in the field of construction waste management. Initially, criteria and alternatives for construction waste management, recycling and reuse and landfilling were identified and classified. Using Analytical Hierarchy Process (AHP), different outcomes were compared based on scoring by Expert Choice 11 software.
Results: The results of this study showed that the discharge percentage in the permanent landfills was 68%, in temporary pits was 9% and in recovery centers was 23% in the last 6 years. The final priority of criteria with respect to the economical criterion was reuse (0.492), recycling (0.274) and landfilling (0.235), respectively. Also, according to the environmental criterion, the scores for reuse, recycling and landfilling were 0.492, 0.373 and 0.198 respectively. Based on social criterion the calculated scores were 0.5, 0.279 and 0.222 for landfilling, recycling and reuse, respectively.
Conclusion: In this study, the reuse option with the weight of 0.439 was the best disposal option; and the recycling option with the weight of 0.312 was the second priority. Landfilling showed the lowest score with the weight of 0.250.
M Kermani, M Farzadkia, A Esrafili, Y Dadban Shahamat, S Fallah Jokandan,
Volume 10, Issue 2 (9-2017)
Abstract
Background and Objective: Discharge of industrial wastewater containing Catechol has adverse effects on human and environmental health. Purpose of this study was to determine the effects of catechol toxicity before and after advanced oxidation process (ozonation process) by bioassay test with Daphnia Magna.
Materials and Methods: This study is an applied research in which the toxicity of catechol was determined by Daphnia Magna bioassay test during the ozonation process. First, Catechol stock solution was prepared at a concentration of 250 mg/L. Then, 10 samples were prepared that each contained 0 (control), 0.5, 1, 3, 6, 12, 25, 50, 75 and 100% of volume of primary solution. Initial samples were prepared from reactor effluent in the same volume as those of the samples. According to standard method, 10 Daphnia infants were added to each sample. The samples were observed after 24, 48, 72 and 96 hours. Finally, lethal concentration (LC50) and toxicity unit (TU) were calculated using Probit analysis.
Results: According to the results, Daphnia magna was affected by the toxicity of catechol. LC50 (24-hour) for raw effluent was increased from 13.30 mL/100 mL to 30.4 mL/100 mL after 60 minutes Treatment. The toxicity unit was decreased from 7.51 TU to 3.29 TU accordingly, showing reduction of 56% in toxicity. The toxicity of the treated effluent decreased during ozonation process of catechol.
Conclusion: Based on the bioassay test, ozonation process was able to reduce the toxicity of catechol. Therefore, this process can be used as an option to treat wastewater that contains catechol.
M Fahiminia, H Jafri Mansoorian, R Shaikh Bigloo, S Bahari, A Eskandari,
Volume 10, Issue 4 (3-2018)
Abstract
Background and Objective: Today, workshop industries play an important role in urban development by creating effective employment in urban areas. It has been stated that these small industries can cause environmental pollution. The purpose of this study was to investigate and analyze the contaminations caused by the workshops in Qom in 2016.
Materials and Methods: The present study was descriptive-analytic-cross sectional. First, all of the city's businesses were listed in 67 relevant :::::::union:::::::s. After identifying the polluting businesses, a total of 223 classes of all :::::::union:::::::s were randomly screened. Sewage, solid waste, air, sound, soil and landscape pollution were investigated. According to 15 specialists and using Expert Selection software, each pollution type and rating of each class were weighed and determined.
Results: The results showed that the wastewater, solid waste, air, noise, and landscape pollution with a score of 0.399, 0.259, 0.169, 0.097, and 0.027, respectively, are important. Accordingly, in terms of the total contamination of the studied occupational units, authorized dealers of car sales, carwash, guest house, carpet cleaning, bath, brick plants, chalk plants, gemstones, chelokbaby, mosaic making, lathes and blacksmans, iron doors and window making, general blinds and shuttering, ceramic making, wood processing industry, mechanical, polishing with a total score of 1, 0.889, 0.881, 0.872, 0.709, 0.644, 0.644, 0.641, 0.62, 0.609, 0.582, 0.569, 0.552, 0.546, 0.518, 0.499, and 0.499 had unfavorable status, respectively.
Conclusion: In order to reduce the environmental pollution caused by these businesses, continuous monitoring and inspections should be carried out in the short term. Moreover, the polluting industries should be relocated out of the city in the long term.
R Rafiee, M Moeinaddini, N Khorasani,
Volume 11, Issue 1 (6-2018)
Abstract
Background and Objective: The aim of this study was to assess the sensitivity and uncertainty analysis of a mass balance model to estimate the rate of aerobic processes in a landfill.
Materials and Methods: Monte Carlo simulation is a common method to evaluate uncertainty of the results of a model. Here, we used a Monte Carlo (MC) simulation. The data obtained from the experiments were used as a baseline. Considering a uniform Probability Distribution Function (PDF) within ±15% deviation, samples were taken from the baseline data. Using randomly selected inputs, model was executed for 1000 iterations and outputs were evaluated. Then, the total Sobol index for each input parameter was determined. The uncertainty of each output was presented by standard error and means observed in MC simulation.
Results: The results of this study revealed that while the uncertainty for the rate of composting process was mainly originated from the measured value of CO2 flux, the evaluated value for the rate of anaerobic digestion process was highly influenced by the value measured for CH4 emission flux. All inputs contributed equally to the uncertainty in the evaluated values for the rate of methane oxidation process. Although a variability of 15% was assumed for the model inputs, the mean value for the outputs from Monto Carlo simulations were close to those obtained by using base values that were in most cases within ±10% limit.
Conclusion: The majority of the uncertainty in the outputs came from the variability in the measurement of the flux of CH4 and CO2. The error in these parameters, however, can be minimized by increasing frequency and replicates of gas samples as these parameters are measured directly for each location.
M Kalhor, S Ghaleh Askari, M Bozorgi,
Volume 11, Issue 3 (12-2018)
Abstract
Background and Objective: Concentration prediction with Gaussian dispersion models is highly sensitive to meteorological data. The lack of sounding data station in developing countries may lead to large error and uncertainty in air pollution modeling results. In this paper, the effects of estimated upper air data on the model output concentration values were investigated.
Materials and Methods: AERMOD model was executed once with real upper air data and also with estimated upper air data separately. T-Student and LEVENE tests were used to evaluate the significant differences between concentrations in two modes of using actual and estimated upper air data.
Results: The results showed that large differences in concentration between the two methods. In long term modeling, there was up to 33% differences between real and estimated upper meteorological data and up to 63% differences for short term modeling. A large difference was also observed between boundary layer parameterization values in each case. The statistical analysis showed a meaningful difference (p=0.00) between the cases. The differences between ZICNV, DT/DZ, W* were 7.1%, 48%, and 19%, respectively.
Conclusion: The use of estimated upper meteorological data in comparison with measured data may lead to a large error. The AERMOD modeling results with estimated meteorological data must be expressed with appropriate uncertainties and confidence interval.
M Hadi, M Solaimany Aminabad, M Amiri, M Arjipour,
Volume 11, Issue 3 (12-2018)
Abstract
Background and Objective: Treatment of hospital wastewaters has an important role in reducing the discharge of organics and pharmaceutical compounds into aquatic environments. Nowadays, advanced oxidation processes were extensively used for the removal of organic compounds from treated effluents. The study aimed to examine organic compounds removal from real treated effluent of a hospital treatment plant using a lab scale UV/H2O2/TiO2 process by optimizing the process.
Materials and Methods: The effluent characteristics including COD, TOC and DOC were measured and recorded. A hybrid advanced oxidation process (UV/H2O2/TiO2) was used for the removal of organic compounds. The experiments were designed using surface response methodology (RSM). The effects of the independent factors including pH, duration of UV irradiation, H2O2 and TiO2 concentrations on COD, TOC, DOC and the approximate cost of treatment were assessed by analysis of variance (ANOVA).
Results: The optimal condition was 7.2 for pH, 50 mg/L for H2O2, 100 mg/L for TiO2 and 19.65 min for irradiation time. This condition provided the maximum removal percentage for organic compounds with a minimum cost. The removal efficiency for TOC, DOC and COD were 63.9, 52.9, and 64.7%, respectively. The treatment cost was approximated to be $ 0.71 per one liter of the effluent.
Conclusion: Irradiation and H2O2 concentration had the greatest impact on the cost of the treatment. UV/H2O2/TiO2 process seems to be an expensive process for tertiary treatment of wastewater. However, further investigations are required to evaluate the cost effectiveness of the process for a full scale operation.
M Moradzadeh, Kh Ashrafi, M Shafiepourmotlagh,
Volume 11, Issue 4 (3-2019)
Abstract
Background and Objective: Hydrocarbon processing industries are considered as potential sources of volatile organic compounds (VOCs) due to their specific nature. These compounds can directly or indirectly through producing secondary pollutants have adverse effects on the health of individuals. Therefore, identification of them is an important step in the formulation of control programs. This study aimed to identify the type and amount of the most important volatile organic compounds in the South Pars region.
Materials and Methods: In this study, industrial processes located in the region were investigated and information was gathered for estimation of VOCs emissions. The emission was estimated over a one-year period and was ranked according to three criteria including emission, health hazards and ozone production potential.
Results: The results showed that the greatest emission was due to equipment leakage and storage tanks (64%), cooling towers (21%) and flaring (11%). The 171 VOCs were determined in Plum of these processes and propylene had the greatest contribution (21%). The alkenes had the highest share in total mass (41%) and ozone production (78%). By weighting the list based on the three criteria mentioned above, formaldehyde is the most important emitted VOC and the main sources of it were olefins and aromatic units.
Conclusion: This method can be a useful tool for identifying effective organic compounds in such areas. Here, the optimum control strategy is mitigating of emission of formaldehyde from the aromatic and olefins processes. The next priority is to control propylene, ethylene and butylene emission sources.
Mr Samarghandi, Ar Rahmani, Z Darabi, J Mehralipour,
Volume 12, Issue 4 (2-2020)
Abstract
Background and Objective: Electroproxone process is a combination of ozonation process and electrolysis in which the production of hydroxyl radical and ultimately degradation of a pollutant occurs. The aim of this study was to estimate the E-Proxone process in removing ceftriaxone from a synthetic solution.
Materials and Methods: In this experimental study, a semi-continuous reactor equipped with four graphene electrodes having 2 × 10 cm dimension and 3 mm thickness was used. The effect of pH (3-11), concentration of ozone gas (1-5 mg/min), direct electric current (1-3 A), initial concentration of ceftriaxone (5-50 mg/L) and radical scavenger dose (tertbutanol = 20 mmol/L) was studied in a 0-60 minutes reaction time. The Ceftriaxone concentration was measured by HPLC, COD was measured with spectrophotometer (DR6000) and TOC with a TOC analyzer.
Results: The results of this study indicated that this process had sufficient performance in the degradation of the antibiotic and diminishing of COD and TOC. The excellent condition was pH = 3, the electric current of 3 A, the ozone concentration of 5 mg/min, and the sodium sulfate as an electrolyte was 50 mmole/L. The ceftriaxone concentration was 5 mg/L in the duration of the 30 minutes experiment. 99.39% of the Ceftriaxone was destroyed. The process efficiency in COD and TOC removal was highest at 90 minutes. The presence of tertbutanol reduced the process efficiency to 83%.
Conclusion: The E-Proxone process, as one of the advanced oxidation processes, has the ability to reduce the pollution load of pharmaceutical industry, especially the ceftriaxone in this wastewater. This process is considered an environmentally friendly process.
Somayeh Mokhtari, Mahdi Farzadkia, Leila Janani, Ahmad Jonidi Jafari,
Volume 13, Issue 2 (8-2020)
Abstract
Background and Objective: The purpose of this cross-sectional study is to evaluate the microbial contamination of food-handlers' hands and food contact surfaces in food preparation and distribution centers.
Materials and Methods: This study was performed in 2019 in Fardis city of Alborz province. In this study, 100 samples of food contact surfaces and 48 samples of staff hands were collected from three traditional bakery units, pastry centers and snack shops and the microbial load was determined using a luminometer device. The samples were then analyzed for the presence of coliforms, Escherichia coli and Staphylococcus aureus bacteria.
Results: Among the samples studied, 62 samples (62%) of contact surfaces and 27 samples (56.25%) of food-handlers' hands had microbial load more than 30 RLU. According to the results, the main cause of microbial contamination of equipments were 44.40% of Coliform bacteria and 11.10% of Staphylococcus aureus on the equipment of confectionery centers, 10% of Escherichia coli, 20% of coliforms and 20% of Staphylococcus aureus were detected on food tools and 2.30% of Escherichia coli, 14% of coliforms and 14% of Staphylococcus aureus –on the tools of traditional bakeries.Moreover coliform bacteria was noticed onconfectionary-handlers' hands and all three types of bacteria were also found on the hands of bakers.
Conclusion: The results showed that the cleanliness of food contact surfaces and the personnel hands hygiene was in poor condition which may pose serious threat to public health. Therefore, adequate personal hygiene practices, food safety and inspections should be implemented to protect the health of society.
Mohamad Amin Daneshfar, Mehdi Ardjmand,
Volume 13, Issue 2 (8-2020)
Abstract
Background and Objective: Improper landfilling of drilling waste has adverse effects on the environment and human health. This study aims to select suitable landfills for oil and gas drilling waste on Qeshm Island using GIS and AHP.
Materials and Methods: In this study, a weighted map was prepared based on each criterion affecting the site location. In the next step, each of the prepared layers was ranked. Higher rating indicated the importance of each layer while lower values corresponded to their insignificane.
Results: The reasults of this study showed that the distance from population centers (weight 0.222), communication network (roads) (weight 0.169) and surface waters (weight 0.142) are important parameters for landfill siting. The combination of ranked maps and the weights obtained from AHP, divided the landfill area to “completely suitable”, “suitable”, “relatively suitable”, “relatively unsuitable” and “unsuitable”.
Conclusion: Priorities identified in “completely suitable” areas can be the basis for decision-making, and appropriate locations can be on the agenda as next priorities.
Hanieh Mirbolooki, Mehrshad Hajibabaei,
Volume 14, Issue 2 (9-2021)
Abstract
Background and Objective: Antibiotics are hardly decomposable and resistant contaminants in the environment that according to their anti-biological properties, it is necessary to eliminate or reduce the amount of them before entering the environment. Therefore, the main goal of this research is to investigate the Fenton and Fenton-like process efficiency for the treatment of wastewater containing Spiramycin antibiotic.
Materials and Methods: The effect of independent variables including pH, contact time, oxidant concentration (H2O2), and catalyst concentration (Fe2+ and Fe3+) on the COD removal efficiency were measured using COD meter. The ranges and number of experiments were assigned by RSM (Response surface method) using design expert software.
Results: The optimum conditions of Fenton process with treatment efficiency of 63.31% were obtained at pH 4, hydrogen peroxide concentration of 50 mg/L, Fe2+ concentration of 75 mg/L and contact time of 5 min. The optimum conditions of Fenton-like process with treatment efficiency of 51.21% were obtained at pH 3, hydrogen peroxide concentration of 60 mg/L, Fe3+ concentration of 137.5 mg/L and contact time of 32.5 min. Based on the ANOVA analysis results, the f value in Fenton method indicates that the model is significant.
Conclusion: According to the results, Fenton oxidation process was selected as the optimum method to remove COD from synthetic wastewater containing Spiramycin antibiotic which may be applied as an efficient method for the treatment of wastewaters containing antibiotic.
Alireza Rahimi, Nabi Shariatifar, Ali Heshmati,
Volume 14, Issue 3 (12-2021)
Abstract
Background and Objective: The Pesticides used in agriculture have caused great concern due to their adverse effects on human health. In this study, the effect of rinsing, crushing, filtering, clarifying with bentonite and pasteurization on the reduction of diazinon, ethion and phosalone during Asari grape juice was investigated.
Materials and Methods: Vineyard was sprayed during three growth stages before flowering, sour grape (ghooreh) and during grape ripening with phosalone, diazinon, ethion and in doses of 525, 600, 750 g of active substance per hectare, respectively. Twenty-four hours after the last spraying step, the grape sample was harvested and exposed to the process of rinsing (20-30 s), crushing, filtering, clarifying and pasteurizing. Then, the pesticides residue concentration was determined after each step by GC-MS/MS.
Results: The initial concentrations of diazinon, ethion and phosalone in unprocessed grape samples were 0.640, 0.716 and 0.550 mg/kg, respectively. The reduction values of diazinon during the juicing processes of rinsing, crushing, filtering, clarifying with bentonite and pasteurization, in comparison with the concentration of unprocessed grapes, were 25.72, 41.96, 74.54, 90.21 and 100% (not found), respectively; while these values were 9.78, 28.50, 69.45, 89.38 and 96.74% for ethion and 17.32, 28.47, 46.40, 80.25, 93.28% for phosalone, respectively. All processes significantly reduced insecticides residue.
Conclusion: Findings showed that the processes of grape juice production could significantly decrease the diazinon, ethion and phosalone residues.
Narjes Khodaygani, Roya Mafigholami,
Volume 14, Issue 4 (3-2022)
Abstract
Background and Objective: Pharmaceutical wastewater has a high level of pollution load that should be treated before discharging to the environment. Integrated processes using different mechanisms are one of the most fruitful methods in wastewater treatment. In this study, combined Integrated Fixed Film Activated Sludge (IFAS) and photocatalytic processes are utilized using of Fe3O4/TiO2 nanocatalysts to decrease the COD value of pharmaceutical wastewater.
Materials and Methods: In this study, the variables of each process are optimized using Response Surface Methodology (RSM). In the IFAS process, the variables were dissolved oxygen (DO), media filling percentage and hydraulic retention time (HRT); while in the photocatalytic process, the effects of pH of wastewater, catalyst dose and reaction time were investigated.
Results: In optimal conditions (DO 3 mg/L, HRT 24 h and media filling percentage 65%), COD removal rate was obtained 59.15%. With the initial concentration of 1725 mg/L COD and the mentioned efficiency, the concentration of COD in the effluent diminished to 704 mg/L. However, in the photocatalytic process, during optimal conditions (pH 6.8, reaction time 105 min and catalyst dose 60 mg/L), The efficiency of the process was determined 81%, which by considering the input COD (704 mg/L), the output concentration was reduced to 134 mg/L.
Conclusion: According to the standards provided by the Environmental Protection Agency (EPA), the effluent from the combined process can be discharged into the environment.
Mehrab Aghazadeh, Amirhesam Hasani, Mehdi Borghei,
Volume 15, Issue 3 (12-2022)
Abstract
Background and Objective: Based on its unique characteristics, oil industry wastewater must be treated before discharging into the environment. The study aimed to optimize the catalytic sonopraxone process in the treatment of petroleum wastewater using a statistical method.
Materials and Methods: The synthesis of Iron Oxide-Zinc Oxide was carried out by air oxidation and layer-by-layer self-assembly method. XRD, SEM, EDAX, FT-IR, BET, DRS, VSM and TGA techniques were used to investigate the structure. In this study, applied CCD method optimization of pH parameters, reaction time, ozone gas concentration, hydrogen peroxide concentration and catalyst amount in the process. In optimal conditions, BOD5 and TPH removal values, reaction kinetics and synergistic effect of mechanisms were studied. COD, TPH and BOD5 were measured by spectrophotometer (DR6000), GC-FID and incubator, respectively.
Results: The results indicated that the Fe3O4@ZnO structure is well formed. A quadratic model was proposed to model the process based on the correlation coefficient. Based on ANOVA analysis and p and f indices, the proposed model was reported to be significant. Optimum conditions include pH 6.4, ozone concentration 1.3 mg/L.min, hydrogen peroxide concentration 2.5 mL/L, reaction time 51 min and catalyst amount equal to 0.64 g/L. In these conditions, the amount of COD reduction was 82.3 and 70% theoretically and experimentally, respectively. Also, in optimal conditions, BOD5 and TPH removal rates were 90.5% and 85.8%, respectively. The kinetics of the process follows the kinetics of the first order (R2=0.98) and the presence of different mechanisms together causes a synergistic effect and increases the efficiency of the process.
Conclusion: This process can improve the quality of oil effluent based on COD, BOD5, and TPH removal.
Mohammad Fahiminia, Hossein Jafari Mansoorian, Akbar Eskandari, Mohammad Ghafoori, Enayat Afsar,
Volume 15, Issue 3 (12-2022)
Abstract
Background and Objective: Visual pollution is one of the important components of the man-made environment in urban spaces. The purpose of this research was to investigate the visual pollution of workshops in Qom city using Expert Choice software and then the occupational ranking was done in terms of visual pollution.
Materials and Methods: This study was a descriptive-analytic cross-sectional study conducted in 670 trade units associated with 67 urban trade unions. The data collection tools were local visits, database preparation and completion of a questionnaire based on urban-environmental aesthetic criteria. The purpose of this study was to investigate the visual pollution caused by the occupations and workshops of Qom.
Results: The results showed that, in terms of total visual pollution, the units of oil changes with a total score of 1, materials and construction materials with 0.988, Smoothies with 0.980, Mechanics with 0.973, ceramic makers with 0.944, Chips and grills with 0.933, mosaics with 0.914, carwash with 0.885, stones cutting with 0.872, carpet with 0.870, trowel and blacksmiths with 0.857, burners with 0.830, battery makers with 0.825, iron manufacturers with 0.872 and manufacturers of general blinds and blinds with 0.753 were inadequate.
Conclusions: In order to reduce the number of visually impaired businesses in the short term, continuous inspections of businesses must be undertaken and, in the long run, by organizing the program, the polluting industries must be transferred out of the city.
Anasheh Mardiroosi, Hanieh Fakhri, Ali Esrafili, Masoumeh Hasham Firooz, Mahdi Farzadkia,
Volume 15, Issue 4 (3-2023)
Abstract
Background and Objective: Pharmaceutical compounds can cause potential risks to aquatic and terrestrial organisms. So far, different methods have been used to eliminate these pollutants, photocatalytic processes are one of the most efficient processes to eliminate pharmaceutical compounds. In this study, the efficiency of a novel MOF-based nanocomposite, PMo/UiO-66 as a photocatalyst for amoxicillin degradation under visible light irradiation was evaluated.
Materials and Methods: The study of the chemical decomposition of amoxicillin using the PMo/UiO-66 system was conducted at different stages. First, the PMo/UiO-66 MOF nanocomposite was synthesized using the solvothermal method, then the properties of the synthesized nanocomposite were investigated using XRD, FTIR, and SEM techniques. The effect of different operational parameters such as pH (3, 6, and 9), catalyst concentration (15, 20, 25, and 30 %w/w), initial concentrations of amoxicillin (20, 30, 40, and 50 mg/L) at different times on the removal efficiency was investigated. The reusability of the catalyst for four cycles was assessed.
Results: The results showed that PMo/UiO-66 nanocomposite at pH 6, 25 %w/w nanocomposite concentration, and the amoxicillin concentration of 20 mg/L led to complete decomposition of amoxicillin after 120 min. The kinetic of amoxicillin removal followed the first-order model. Reusability tests showed that the photocatalytic efficiency of the synthesized catalyst was not substantially reduced after four cycles.
Conclusion: The current study confirmed that the PMo/UiO-66 system has an appropriate efficiency for photocatalytic removal of amoxicillin under optimized test conditions.
