Showing 42 results for Kia
M Ansari, M Fahiminia, M Farzadkia,
Volume 11, Issue 4 (3-2019)
Abstract
Background and Objective: Rural wastewater management is recognized as one of the pillars of sustainable development. Therefore, the purpose of this study was to assess needs and prioritization of establishment of rural wastewater management facilities in order to supply a safe and alternative water source in the provinces of Iran experiencing severe water stress.
Materials and Methods: This is a cross-sectional descriptive study which was carried out in rural areas of the provinces with severe water stress (South Khorasan, Khorasan Razavi, Fars, Isfahan, Yazd, Semnan, Qom, Sistan and Baluchistan) in 2017-2018. In this study, the number of sample rural areas was calculated by Cochran method and the determination of the sample rural area was done by stratified sampling. The data related to the sample rural area was collected using a validated constructor questionnaire.
Results: The results of this study showed that the difference among all the studied provinces in terms of their priority in establishing rural waste water management facilities to provide a safe and alternative water source was very low. The provinces of Isfahan, Semnan and Fars were rated at 76 out of 100, while the provinces of South Khorasan and Sistan and Baluchestan scored 71 points.
Conclusion: With emphasis on comprehensive decision making criteria based on sustainable development, the results of this study showed that the provinces with severe water stress have a high priority regarding the establishment of rural sewage management projects in order to provide a safe and alternative water sources.
H Nik Nejad, H Pasalari, M Yegane Badi, J Abolghasemi, R Ghasem Nejad, M Farzadkia,
Volume 12, Issue 1 (5-2019)
Abstract
Background and Objective: Clinics, laboratories and health care centers are considered as one of the main waste generating sources in solid waste management. The problems associated with the generated health-care waste in clinics, laboratories and health care centers have been rarely investigated in Iran. Therefore, the present study was developed to investigate the status of health care waste in clinics, laboratories and health care centers of Mahmoudabad, Mazandaran in 2017.
Methods and Materials: This cross-sectional study was conducted to determine the status of solid waste management in 117 medical centers in Mahmoudabad, Mazandaran, 2017. The solid waste data in terms of waste generation rate, storage, collection, and disposal were surveyed through interview and questionnaire that were validated by Iran’s ministry of health.
Results: The average health-care waste generation in medical centers in Mahmoudabad was found to be 248 g/day. The mean and standard deviation for environmental health criteria in all medical centers were 248.3 and 41.1, respectively. In addition, there was a statistically significant difference between the amount of waste generation in private and governmental medical centers (p=0.111).
Conclusion: The results obtained from the present research indicated that the medical waste management in Mahmoudabad, particularly in private centers, face serious problems. Improper waste collection technology, mixing municipal and medical waste, requirement for training the personnel in medical waste management and surveillance can be considered as important concerns in health-care waste management in Mahmoudabad.
J Gorgani, R Nabizadeh, M Gholami, H Pasalari, M Yegane Badi, M Farzadkia, Ha Asgharnia, Ma Zazouli,
Volume 12, Issue 3 (12-2019)
Abstract
Background and Objective: Hospital wastes with the content of infectious, pathologic, sharp, pharmaceupitical and genotoxic materials are classified as hazardous wastes. Of which, genotoxic residues wirh mutagenic and teratogenic effects are of most great concern on human health. Genetic wastes are referred to as cytotoxic, chemical, and radioactive drugs used to treat cancer or treat transplantation. The purpose of this study was to evaluate the management of hospital wastes in Mazandaran province with emphasis on genotoxic waste.
Materials and Methods: This descriptive cross-sectional study was carried out in 35 governmental and social hospitals in Mazandaran province to determine the satus of hospital waste with focus on geotoxic waste. The quanity, quality and management approaches of hospital and genotoxic wastes in the studied hospitals were surveyed with a validated questionnaire. Results obtained from the present study were analyzed with Excel software.
Results: The average waste per each hospital bed was estimated to be 3.51 kilograms. Of which, 2.2, 1.24, 1.9 kg were categorized as municipal, chemical, and genotoxic wastes, respectively. The average of the hospital waste management index in Mazandaran province was found to be about 84 out of 100, indicating good management of these wastes. The management of genotoxic waste in 7 specialized chemotherapy hospitals was estimated to be 64 out of 100, indicating the average state of genotoxic waste management for these hospitals. In 28 non-chemotherapy hospitals, the genotoxic waste management index was approximated 42 out of 100, indicating poor management of these wastes.
Conclusion: The main weaknesses in hospital waste management are associated with the management of chemical-pharmaceutical and genotoxic wastes. Accordingly, improvement the quality of genotoxic and chemical-pharmaceutical wastes should be concerned in the future planning.
H Niknejad, M Farzadkia, A Esrafili, M Kermani,
Volume 12, Issue 4 (2-2020)
Abstract
Background and Objective: 2,4 dinitrophenol is observed in sewage produced from chemical and petrochemical industries. Contamination of drinking water with these pollutants causes toxicity, health problems and change in taste and odor. The present study was developed to evaluate the efficiency of removal 2,4-DNP through dried sludge adsorbent and modified calcium chloride sludge adsorbent.
Materials and Methods: At first, sludge was dried at temperature of 60 °C. Next, CaCl2 was used to improve adsorption capacity. The removal efficiency of 2,4 dinitrophenol were determined by HPLC at wavelength of 360 nm. The effects of influencing factors including pH, initial pollutant concentration, contact time, and adsorbent dose were examined.
Results: The optimum pH of adsorption for both adsorbents was found to be 7. The optimum concentration of 2,4-DNP was 10 ppm. The results obtained from the present research showed that the removal of the contaminant using dried and modified sludge sorbent was increased from 72.6% to 86% at a dosage of 1.5 g. The adsorption kinetics were fitted with the pseudo second order kinetics model for both adsorbents. The isotherm data also showed that the adsorption of this pollutant on both adsorbents is fitted with the Freundlich model.
Conclusion: Results obtained from the present study indicated that the efficiency of the modified sludge ash is more than the non-modified sludge in 2,4 dinitrophenol removal. This can reduce adsorbent consumption in industrial treatment plants.
Mohsen Ansari, Mahdi Farzadkia,
Volume 13, Issue 1 (4-2020)
Abstract
Background and Objective: Considering 829000 annual diarrhoeal deaths due to water pollution worldwide, the World Health Organization has emphasized that countries should reduce this rate by upgrading their wastewater treatment systems. The purpose of this study was to evaluate the performance of a modified up flow septic tanks reactor for treatment of synthetic wastewater.
Materials and Methods: In this experimental study, a modified septic tank system based on the upstream hydraulic regime, and also a conventional septic tank system was designed, manufactured, and operated. The municipal wastewater was used to operate, and synthetic wastewater was used to maintain. The major performance indicators of septic tanks include: volatile solids (VS), volatile suspended solids (VSS), total suspended solids (TSS) and chemical oxygen demand (COD) were sampled and measured in triplicates. The experiments were done in three hydraulic retention times of 24, 48, and 72 hr. Finally, the results of the study were analyzed by statistical tests in the SPSS software.
Results: The average removal of TSS, VS, VSS, and COD in HRT 24 h for the conventional reactor were 55.07, 27.36, 30.82, and 55.52%, respectively, and for the upstream-modified reactor at HRT 24 h were 66.57%, 34.05%, 38.47%, and 65.57%, respectively.
Conclusion: Changing septic tanks to up flow regimes and creating a cylindrical shape in conventional septic tanks, the removal efficiency of conventional septic tanks was improved, and the effluent contamination load was reduced.
Somayeh Mokhtari, Mahdi Farzadkia, Leila Janani, Ahmad Jonidi Jafari,
Volume 13, Issue 2 (8-2020)
Abstract
Background and Objective: The purpose of this cross-sectional study is to evaluate the microbial contamination of food-handlers' hands and food contact surfaces in food preparation and distribution centers.
Materials and Methods: This study was performed in 2019 in Fardis city of Alborz province. In this study, 100 samples of food contact surfaces and 48 samples of staff hands were collected from three traditional bakery units, pastry centers and snack shops and the microbial load was determined using a luminometer device. The samples were then analyzed for the presence of coliforms, Escherichia coli and Staphylococcus aureus bacteria.
Results: Among the samples studied, 62 samples (62%) of contact surfaces and 27 samples (56.25%) of food-handlers' hands had microbial load more than 30 RLU. According to the results, the main cause of microbial contamination of equipments were 44.40% of Coliform bacteria and 11.10% of Staphylococcus aureus on the equipment of confectionery centers, 10% of Escherichia coli, 20% of coliforms and 20% of Staphylococcus aureus were detected on food tools and 2.30% of Escherichia coli, 14% of coliforms and 14% of Staphylococcus aureus –on the tools of traditional bakeries.Moreover coliform bacteria was noticed onconfectionary-handlers' hands and all three types of bacteria were also found on the hands of bakers.
Conclusion: The results showed that the cleanliness of food contact surfaces and the personnel hands hygiene was in poor condition which may pose serious threat to public health. Therefore, adequate personal hygiene practices, food safety and inspections should be implemented to protect the health of society.
Behnam Nazari Alamdarloo, Asghar Mosleh Arany, Saeed Shojaee Barjoee, Hamidreza Azimzadeh, Bahman Kiani,
Volume 13, Issue 2 (8-2020)
Abstract
Background and Objective: Urban traffic, while affecting human health, causes physiological and biochemical changes in plants. The aim of this study was to investigate the bioaccumulation potential of Pb and Cd and assess air pollution tolerance index for a number of plants grown high traffic areas of Yazd.
Materials and Methods: This cross-sectional, descriptive-analytical study was performed in both control and high traffic areas of Yazd city by random sampling of trees, shrub and herb species. After transferring the samples to laboratory, relative water content, pH of leaf extract, total chlorophyll and ascorbic acid content (the factors for calculating APTI) in plants were measured using standard methods. Furtheremore, Pb and Cd concentrations were measured to find their relation with APTI index in plants. All statistical analysis, including Kolmogorov–Smirnov test, ANOVA, Duncan test and Pearson correlation coefficient between the studied parameters, were performed in SPSS software version 22.
Results: The highest relative water content (84.73%) and ascorbic acid (5.98 mg/g) were measured in contaminated area for Canna indica and Rosa damascena, respectively. Also, the highest acidity (7.01) and total chlorophyll (1.48 mg/g) in the control area were measured for Verbena hybrida and Ligustrum vulgar, respectively. The highest air pollution tolerance values were recorded in Rosa damascena and Ligustrum vulgar. Moreover, the results obtained showed that APTI index was positively and significantly correlated to Pb, ascorbic acid and relative water content.
Conclusion: According to the classification of air pollution tolerance index, two species of Rosa damascena and Ligustrum vulgar exhibited moderately tolerant to traffic pollutant. Therefore, based on ecological requirements of these two species, they can be used to develop green spaces in high-traffic areas of Yazd. This study showed that Pb increased physiological response of the studied plants, while the plants did not exhibit a significant physiological response to the Cd element. The results also showed that the relative water content and ascorbic acid were more important in the air pollution tolerance index than other factors.
Reza Barati Rashvanlou, Mahdi Farzadkia, Abbas Ali Moserzadeh,
Volume 14, Issue 1 (5-2021)
Abstract
Background and Objective: Hydrolysis of fat, oil and grease by ultrasonic waves is a pre-treatment method before anaerobic digestion which can change their physical, chemical and biological properties. The main purpose of this study was to investigate the efficiency of ultrasonic waves to improve the hydrolysis process and its use as an auxiliary substrate to increase the efficiency of anaerobic digestion process along with municipal sewage sludge.
Materials and Methods: Sampling of fat and oil of the degreasing unit and physical preparation by conducting ultrasonic waves with frequencies of 20 kHz and current density of 0.012-0.14 W/mL within 0-12 min were performed. The efficiency of pretreatment process were performed through tests such as soluble chemical oxygen demand (SCOD), and lipase enzyme activity. In addition, the anaerobic digestion process were evaluated by measuring the TS, VS, VA (volatile acidity), alkalinity, biogas production and biogas methane content.
Results: The results showed that the highest increase in the activity of lipase enzyme under ultrasonic effect with a power of 0.1 w/mL was obtained after 8 minutes. Organic loading with 10%, 20% and 40% FOG/MSS ratios: resulted in 55%, 66% and 64% increase in methane production compared to the control samples, respectively. Organic loading over the 40% FOG/MSS caused a limitation in the simultaneous digestion process.
Conclusion: The results show that ultrasonic wave pretreatment with optimal power and time can improve the hydrolysis of TFOG while increasing the activity of lipase enzyme and also its use as an auxiliary substrate can enhance digestion performance and make digestion more stable.
Mohsen Ansari, Mahdi Farzadkia,
Volume 14, Issue 2 (9-2021)
Abstract
Background and Objective: Wastewater treatment and stabilization always imposes costs and consequently a lot of energy on wastewater treatment plants. To achieve the purification and stabilization of as much sludge as possible, breaking complex components into simpler components is considered a critical step. Therefore, this study aimed to evaluate the feasibility of treating the produced sludge in the municipal wastewater treatment plant using ozonation method.
Materials and Methods: In this study, sludge was obtained from the return line of activated sludge from the wastewater treatment plant in the south of Tehran. An ozonation generator with a discharge rate of 3 L/min and an ozone concentration of 40-35 mg/L was discharged to the reactor and the residual ozone concentration was measured by iodometric method. Finally, the total suspended solids and volatile, soluble chemical oxygen demand, total organic carbon, and biochemical oxygen demand during ozonation processes were measured using the Standard Method.
Results: The results of this study showed that the amount of TSS and VSS in the activated return sludge decreased from 4060 to 2100 mg/L and from 3300 to 1850 mg/L during the ozonation process, respectively. However, SCOD, TOC, and SBOD had an upward trend of about 18, 11.7, and 14 times in the same reaction time, respectively.
Conclusion: According to the results of this study, it can be concluded that the ozonation system can be proposed as a suitable process for the decomposition of sludge produced in wastewater treatment plants and increasing the biodegradability of these sludges.
Mohsen Ansari, Mehdi Farzadkia,
Volume 15, Issue 2 (8-2022)
Abstract
Background and Objective: The high concentration of petroleum hydrocarbons, along with some other parameters such as aromatics, paraffin, naphthene, and heavy metals, has led to the sludge of oil sludge listed as hazardous materials with a specific source by the US Environmental Protection Agency. Therefore, the purpose of this study is to investigate the potential of oil-contaminated soil in changing the biodegradability indices of oil sludge.
Materials and Methods: Moisture, pH, total organic carbon, total nitrogen, total phosphorus, elemental analysis, and amount and type of TPH of oil sludge samples were identified. The microbial consortium was isolated from contaminated oil soil around the oil refinery and poultry manure. Finally, biodegradability indices of oil sludge were examined.
Results: The results showed that the amount of organic carbon and nitrogen in oil sludge samples were 32.65 and 0.21%, respectively. Also, iron, calcium, and potassium with 5862, 2921, and 524 mg/kg, respectively, were the most elemental components in petroleum sludge. According to the SARA analysis, the highest TPH compounds in oil sludge samples included saturated compounds, aromatics, resins, and asphaltene with 70.45%, 15.2%, 10.9%, and 3.45%, respectively.
Conclusion: According to the results of biodegradability indicators of oil sludge, it can be concluded that the isolated consortium can be proposed as a suitable tool for the treatment of petroleum sludge at the bottom of crude oil storage tanks.
Zohreh Naderi, Hiwa Hossaini, Meghdad Pirsaheb, Akbar Barzegar, Sara Kianpour,
Volume 15, Issue 3 (12-2022)
Abstract
Background and Objective: Toluene is one of the most important volatile organic compounds that threaten human health and introduce many environmental problems. Therefore, the present study aims to determine the performance of a biofilter based on pine cones/compost to remove toluene vapors from polluted air streams.
Materials and Methods: In this research, a biofilter with a volume of 19.468 L was designed and built. The biofilter bed consisted of two parts 26 cm in height and packed with a mixture of compost and pine cones in 1:1 volumetric ratio. After inoculating the bed with sludge from a municipal wastewater treatment plant and making it compatible with toluene, the performance of the biofilter in different parts of the bed was investigated at the inlet toluene concentrations of 2.5-5.5 g/m3 and Empty Bed Retention Times (EBRTs) of 1.3, 1.7, and 2.43 min. Also, the results were analyzed statistically.
Results: At EBRT of 2.43 min and different inlet toluene concentrations of 2.5-5.5 g/m3, the removal efficiency reached 100 percent. Also, the removal efficiency decreased with the reduction of EBRT. The results showed that removal efficiency was higher in the first part of the biofilter bed relate to the second part. At an inlet toluene concentration of 2.62 g/m3 and EBRT of 1.7 min, the maximum elimination capacity (ECmax) of 2.74 g/m3.min was obtained.
Conclusion: In all experimental conditions the outlet concentration of pine-cone/compost biofilter was below the WHO standard (260 µg/m3). Also, the high elimination capacity of biofilter verified its capability toward toluene removal from polluted gas streams.
Mohsen Ansari, Mahdi Farzadkia,
Volume 15, Issue 3 (12-2022)
Abstract
Background and Objective: Today, the issue of health aspects in urban waste management, especially recycling, has received a lot of attention during Covid-19 around the world. Therefore, the purpose of this research is to investigate the knowledge, attitude, and performance of workers of one of the waste recycling centers in Tehran metropolis regarding health aspects during the spread of Covid-19.
Materials and Methods: This was a descriptive-analytical cross-sectional study and the study population was all workers working in one of the recycling centers of Tehran Municipality. The data collection tool was a researcher-made questionnaire with validity and reliability in four sections: demographic, knowledge, attitude, and practice of workers toward Covid-19 and solid waste.
Results: Findings of the study showed that the highest number of workers employed were in the age group of 20 to 40 years (60 percent). The level of knowledge was about 80 percent and the lack of awareness was 20 percent. The level of workers' positive attitude, negative attitude, and lack of attitude were 79.71, 14.56, and 5.72 percent, respectively. The level of positive practice among workers was about 67.43 percent and the negative practice was 32.57 percent.
Conclusion: The results clarified that in order to succeed in waste management programs in recycling centers, municipal waste managers should pay more attention to educational aspects, especially through the focus on programs and their development and adaptation for different age groups, especially 20 to 40 years.
Anasheh Mardiroosi, Hanieh Fakhri, Ali Esrafili, Masoumeh Hasham Firooz, Mahdi Farzadkia,
Volume 15, Issue 4 (3-2023)
Abstract
Background and Objective: Pharmaceutical compounds can cause potential risks to aquatic and terrestrial organisms. So far, different methods have been used to eliminate these pollutants, photocatalytic processes are one of the most efficient processes to eliminate pharmaceutical compounds. In this study, the efficiency of a novel MOF-based nanocomposite, PMo/UiO-66 as a photocatalyst for amoxicillin degradation under visible light irradiation was evaluated.
Materials and Methods: The study of the chemical decomposition of amoxicillin using the PMo/UiO-66 system was conducted at different stages. First, the PMo/UiO-66 MOF nanocomposite was synthesized using the solvothermal method, then the properties of the synthesized nanocomposite were investigated using XRD, FTIR, and SEM techniques. The effect of different operational parameters such as pH (3, 6, and 9), catalyst concentration (15, 20, 25, and 30 %w/w), initial concentrations of amoxicillin (20, 30, 40, and 50 mg/L) at different times on the removal efficiency was investigated. The reusability of the catalyst for four cycles was assessed.
Results: The results showed that PMo/UiO-66 nanocomposite at pH 6, 25 %w/w nanocomposite concentration, and the amoxicillin concentration of 20 mg/L led to complete decomposition of amoxicillin after 120 min. The kinetic of amoxicillin removal followed the first-order model. Reusability tests showed that the photocatalytic efficiency of the synthesized catalyst was not substantially reduced after four cycles.
Conclusion: The current study confirmed that the PMo/UiO-66 system has an appropriate efficiency for photocatalytic removal of amoxicillin under optimized test conditions.
Nabi Shariatifar, Jafar Hajavi, Seyed Hosein Abtahi Eivary, Mojtaba Kianmehr,
Volume 15, Issue 4 (3-2023)
Abstract
Background and Objective: The present study aimed to explore the shielding effects of aqueous and ethanolic extracts of Zataria multiflora Boiss on human lymphocyte DNA damage using the comet assay.
Materials and Methods: This study was conducted as a laboratory experiment to investigate the protective effects of thyme in preventing DNA damage. Peripheral blood lymphocytes were isolated from 16 healthy volunteers. First, the cells were treated with 100 μM H2O2 and aqueous and alcoholic extracts of thyme leaves with a concentration of 2.5 mg/mL separately. Finally, the cells were incubated in a mixture of H2O2 to cause DNA damage with each of the two aqueous and alcoholic extracts at 4°C for 30 minutes. The amount of DNA migration in cells was measured using the Comet method, and DNA damage was expressed as three indicators: sequence length, percentage of DNA in the sequence, and the amount of sequence movement.
Results: The results showed that the DNA damage of lymphocytes exposed to the ethanolic extract of Z. multiflora Boiss was significantly lesser than the H2O2-treated lymphocytes. In addition, tail length (µm) was 5.48±1.62 versus 22.82±6.90, tail DNA (%) was 4.56±1.55 in contrast to 16.00±4.55, and tail moment (µm) was 0.28±0.11 against 2.33±0.83 (p < 0.001). The results showed that Z.multiflora Boiss aqueous and ethanolic extracts were significantly able to scavenge DPPH radicals through a possible radical scavenging activity mechanism.
Conclusion: As a result, the ethanolic extract had a better effect than the aqueous extract of Z. multiflora Boiss in preventing oxidative DNA damage to human lymphocytes.
Behnaz Abdollahinejad, Hasan Pasalari, Mahdi Farzadkia,
Volume 16, Issue 1 (6-2023)
Abstract
Background and Objective: The purpose of this study is to identify and comprehensively evaluate international studies related to bioaugmentation and biostimulation methods for the remediation of soils contaminated with petroleum compounds.
Materials and Methods: This systematic review study was conducted in April 2022. The present systematic review study was conducted to address two main questions: 1) Is biostimulation an effective process in the bioremediation of soils contaminated with petroleum hydrocarbons; and 2) Is bioaugmentation an effective process for bioremediation of soils contaminated with petroleum hydrocarbons? Global electronic databases (PubMed, Web of Science, and Scopus) were used to identify relevant studies. After a comprehensive review of studies, 123 studies consistent with the purpose were selected.
Results: The results showed that biostimulation methods can have profound changes in bacterial, Archaebacteria, and soil fungal communities in terms of activity, frequency, and composition. In general, the nutrients and electron receptors added in the biostimulation process improve soil microbial activity, increasing the overall abundance of bacteria, and fungi and promoting selective replication of bacterial, archival, and fungal polyaromatic hydrocarbons (PHC) destroyers. The use of bioaugmentation technology in an environment contaminated with petroleum hydrocarbons has a positive effect on the refining process. However, it is necessary to precisely select the appropriate microbial strains. The most important factor in the removal of hydrocarbons in the soil is the selection of oil-decomposing microorganisms that can survive in high concentrations of pollutants.
Conclusion: Therefore, the result indicated that biostimulation and bioaugmentation can efficiently improve the THP removal efficiency in contaminated soil by considering the environmental conditions.
Mohammad Ghafoori, Mehrdad Cheraghi, Maryam Kiani Sadr, Bahareh Lorestani, Soheil Sobhanardakani,
Volume 16, Issue 2 (9-2023)
Abstract
Background and Objective: Antibiotics are emerging pollutants that enter the human environment through pharmaceutical, hospital, and urban wastewater. Therefore, this study was conducted to investigate of removal efficacy of tetracycline (TC) from aqueous solutions using GO@Fe3O4@β-CD.
Materials and Methods: In this descriptive study, GO@Fe3O4@β-CD was synthesized and then used as an adsorbent for the removal of TC from aqueous solution. GO@Fe3O4@β-CD was characterized using X-ray diffraction (XRD), Scanning electronic microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and vibrating sample magnetometry (VSM) methods. Also, the influence of variables including pH (3-9), amount of adsorbent (0.003-0.050 g), contact time (0-100 min), and temperature (25-55 °C) so assessed on the efficacy of TC removal.
Results: The results of TGA analysis showed that GO@Fe3O4@β-CD nanoparticles were resistant to temperatures up to 400 °C. Also, the results indicated that β-cyclodextrin was uniformly dispersed on the surface of GO@Fe3O4.
The results indicated that removal efficiency increased up to 60 min contact time, 0.01 g of adsorbent, and decrease temperature to 25 °C. The optimum pH for TC removal was 7.0. Also, under these conditions, the adsorption process followed the Langmuir adsorption isotherm with a correlation coefficient of 0.992 and the pseudo-second-order kinetic model with a correlation coefficient of 0.997, 0.999, and 0.998. The maximum adsorption capacity of the prepared adsorbent was 357 mg/g.
Conclusion: The GO@Fe3O4@β-CD could be an effective and efficient adsorbent for the removal of TC from industrial wastewater.
Lieli Amirkia, Arash Shakouri,
Volume 16, Issue 4 (3-2024)
Abstract
Background and Objective: Microplastic pollution due to its small size can be used by a wide range of marine organisms and accumulate mainly in their digestive system, as they have been found in the tissues of aquatic animals, including fish. Due to the nutritional importance of fish for humans, it is very important to check their contamination. The main purpose of this research is to investigate the presence of microplastics in skipjack tuna (Katsuwonus pelamis) in the Oman Sea.
Materials and Methods: 17 pieces of skipjack tuna were used. After the biometry, dissection and isolation of the digestive system of the fish, the digestion and extraction of microplastics were done using KOH solution. Identification and counting were also done by a stereomicroscope equipped with a digital camera. FTIR spectrophotometric analyses were performed to investigate the polymers.
Results: The total frequency and average frequency of microplastics are 331 particles and 19.4±7.3 particles per individual, respectively. String (64.35%) and pieces (28.7%) were the dominant forms in the samples. The highest color spectrum was assigned to red (28.7%) and the lowest to violet (1.51%). The largest number of identified microplastics had a size of 0.5-1 mm (53%). Analysis of particles by ATR-FTIR method showed that nylon polymer and polycarbonate were the dominant polymer particles.
Conclusion: Microplastics are present in all samples. The abundance of microplastics in water, sediments and contaminated bait makes them easily available and swallowed by fish, which is most likely the main reason for the presence of microplastics in fish.
Alireza Zand Abbas Abadi, Mehrdad Cheraghi, Soheil Sobhanardakani, Bahareh Lorestani, Maryam Kiani Sadr,
Volume 16, Issue 4 (3-2024)
Abstract
Background and Objective: Monitoring of pollutants in urban ecosystems is of particular importance. Therefore, this study was conducted to evaluate the capability of Robinia pseudoacacia and Pinus elderica for biomonitoring of Pb, Cr and Ni in urban areas of Hamedan in 2023.
Materials and Methods: A total of 36 soils and 72 plant samples were collected from 12 sites. The contents of elements were determined using ICP-OES. Also, the values of PI, PLI, BAF, and CR indices were computed.
Results: The highest values of Pb, Cr, and Ni (mg/kg) in soil samples with 72.2, 67.5 and 101 values belonged to the commercial, industrial, and commercial sites, respectively. The highest average content of analyzed elements in unwashed and washed leaves/needles for Pb both belonged to the commercial areas; for Cr and Ni, all belonged to the industrial areas. The average values of PI followed the descending order of Cr > Ni > Pb. The average values of PLI varied from 1.22 to 1.34. Moreover, BAF values of Pb, Cr, and Ni of R. pseudoacacia leaves and P. elderica needles were found to be in the range of 0.100-1.00. Also, the highest mean values of CR of Pb and Cr were both found in P. elderica; and the highest mean value of CR of Ni was found in R. pseudoacacia.
Conclusion: R. pseudoacacia and P. elderica could be used as suitable and efficient species for monitoring and remediation of toxic elements from soil and air in polluted ecosystems.
Mojtaba Yeganeh, Sevda Fallah, Hanieh Fakhri, Mahdi Farzadkia,
Volume 17, Issue 1 (6-2024)
Abstract
Background and Objective: Phenol compounds are commonly applied as raw materials in the production of pesticides, herbicides, and dyes. These compounds are toxic to animals, plants, and microorganisms. In this study, the sonophotocatalytic degradation of 2,4-dinitrophenol in aqueous solutions was investigated using organic-mineral polymer catalysts containing Zink and Cobalt oxides under visible light and ultrasonic (US) irradiation.
Materials and Methods: The characteristics of the synthesized catalyst were determined using XRD, FTIR, and SEM techniques. The effect of several key parameters, including pH (3-9), catalyst dosage (0.3-1 g/L), time (0-90 min), US power (100-200 W/m2), and initial concentration of 2,4-dinitrophenol (20-100 mg/L), on the degradation efficiency was also investigated.
Results: After 75 minutes of sonophotocatalytic processing, complete degradation of 2,4-dinitrophenol (20mg/L) was achieved with catalyst dosage of 0.5 g/L, pH of 9.0, and US intensity of 200 W/m2. Kinetic studies indicated that the sonophotocatalytic degradation process followed a first-order kinetic model. The results of radical scavenging experiments confirmed that HO° and O2˚- radicals are the main oxidative species involved in the degradation of 2,4-dinitrophenol. Furthermore, the reuse of the catalyst for five consecutive tests showed a slight decrease in removal efficiency.
Conclusion: The results demonstrate that the sonophotocatalytic process, using the modified organic-mineral polymers with mixed Zink and Cobalt oxides catalyst, can be an effective method for removing 2,4-dinitrophenol from aqueous media.
Behnaz Abdollahinejad, Mahdi Farzadkia,
Volume 17, Issue 2 (9-2024)
Abstract
Background and Objective: Earthworms are important in soil formation. They maintain soil structure and fertility and can be used as indicators to evaluate various changes and impacts. Therefore, the present study was developed to investigate the effects of diesel pollutant on the population and survival of the earthworm species E.fetida in the co-vermicomposting process.
Materials and Methods: This experimental study was conducted over 90 days to investigate the effects of diesel concentration on the survival of E.fetida in the co-vermicomposting process. One kilogram of soil contaminated with diesel, vermicompost, and raw activated sludge was added to each reactor in a ratio of 0.25:0.35:1. 10. Additionally, 20 adult E. fetida were added to the reactors with diesel concentrations of 10 and 30 g/L after the adaptation process.
Results: The survival of earthworms and the formation of cocoons in reactor number 3 were higher than in other reactors. Additionally, the amount of diesel removal in reactor number 3 (diesel concentration: 10 g/kg dried soil +20 E.fetida) was higher (70.5%) compared to the other reactors.
Conclusion: The results of the study showed that earthworm reproduction is more sensitive than survival or weight change to higher concentrations of diesel-contaminated soil. The presence of petroleum compounds in the soil is harmful for the growth of E.fetida, and its acute effects on the production of earthworm cocoons were observed.
