Iranian Journal of

Background and Objective: The aim of this study was to evaluate the chemical and microbial quality of bottled water in Iran and to calculate the water quality index (WQI).
Materials and Methods: Different brands of bottled water (4 samples from 71 brands) were randomly collected from the market. Chemical and microbial characteristics of the samples were examined and determined. Finally, the calculations related to the WQI index were performed and the water samples were classified as excellent, good, poor, very poor and unsuitable.
Results: None of the samples exhibited concentration of heavy metals beyond Iranian water standards, and the concentration of sulfate (SO₄), chloride (Cl) and fluoride (F) did not exceed international standards. However, in some samples, nitrite (NO₂) and nitrate (NO₃) concentrations were higher than recommended standards. With Regard to other water quality parameters, 8% to 89% of the samples exhibited concentration higher than the values provided on the water bottle label. 5 species of different bacteria were found in 15 water samples. According to the WQI index, about 63% of the samples were of excellent quality. Also, the water quality of 34% and 3% of the samples fell in good and poor quality categories, respectively. None of the bottled water samples was of very poor quality.
Conclusion: The quality of bottled water investigated in this study was generally suitable, but due to the wide range of bottled water in Iran based on brand and seasons, continuous evaluation of water treatment methods in companies and careful monitoring of chemical and microbial quality of bottled water in all seasons is recommended.

Background and Objective: Corrosion and precipitation are important indicators of water quality assessment. The aim of this study was to analyze water stability water in Semnan distribution networks.
Materials and Methods: To achieve the purpose, samples were taken from 5 points (3 points of storage tanks and 2 distribution network points) and analyzed for physical-chemical analysis. The concentration of common anions and cations was determined by ion chromatography (IC). The sediment formed in the water distribution network was also investigated for studying its structure and main elements by using X-ray fluorescence spectroscopy (XRF) and induced coupling plasma spectroscopy (ICP). The corrosion and scaling indices, including the Ryznar stability index (RSI), Langelier index (LI), and calcium carbonate precipitation potential (CCPP) were also studied.
Results: According to the obtained results, the quality (physically-chemically) of most of the taken samples lies within the permissible limits of Iran's national standard (1053). However, in terms of total harness all sampling point showed values beyond WHO guidelines for drinking water. Magnesium and sulfate concentrations were also exceeded in one of the reservoirs. The results also showed the main sediment structures were calcium carbonate (calcite) and silica oxide. Moreover, According to the results, the average values of LSI and CCPP represented the scaling due to carbonate calcium nature of water. Water stability analysis indicated major roles of calcium and magnesium bicarbonate formation as temporary hardness and minor roles of magnesium sulfate and chloride as permanent hardness.
Conclusion: According to the results, to prevent water scaling in pipes it is recommended to use lime softening at pH=10 which not only removes temporary hardness but enhances silicate ions removal by co-precipitation with Mg(OH)₂ formed followed by filtration.

Background and Objective: Groundwater is the primary water source for drinking and agricultural activities in arid and semi-arid regions. Rainfall, land use, geological structure, aquifer mineralogy, and duration of water contact with the environment in the basement are the main factors affecting the chemical quality of groundwater. This study aimed to determine the physicochemical properties of groundwater by considering the water quality index (WQI) and its quality assessment for drinking water.
Materials and Methods: In this study, 71 wells of Kashan were sampled in summer 2020 with three samplings from each well, and physical and chemical parameters were studied, water quality index was determined using mathematical methods, and Pearson correlation coefficient was determined. Correlation analysis was used. Finally, the collected data were analyzed using SPSS-16 software, Excel 2013, and statistical tests. 
Results: The calculated WQI of 71 wells in Kashan shows that 67% of the wells were of excellent quality, and 33% were of good quality in terms of water quality parameters. In total, out of 71 samples, the numerical index of water quality was 44.94, and the water was of excellent quality.
Conclusion: The results show that ions such as sodium, sulfate, and chlorine are directly related to the counting in an area and increase the concentrations of EC and TDS, and can impair the balance of anionic and cationic aqueous solution. It was also found that more than half of the wells have excellent quality due to using water wells for drinking.

Background and Objective: With the industrialization of communities, population increase and use of surface water, river pollution has been increased by agricultural, industrial pollutants and urban wastewater. Therefore, investigation of river pollution for regional and environmental planning is of great importance. To evaluate surface water pollution, a number of surface water quality indices have been investigated.
Materials and Methods: Iran water quality index for surface water resources (IRWQI_SC) approach was used to evaluate the water quality of the Mahabadchai river, Iran. Sampling was carried out along the Mahabadchai river based on some criteria such as approximately to drainage areas for landfills/domestic and agricultural effluents.
Results: Pearson correlation coefficient between physical, chemical and microbial parameters of water showed that fecal coliform, BOD, COD, nitrate, ammonium, phosphate, turbidity and total hardness had a significant positive relationship with each other at 99% confidence. According to this index, upstream samples of the river are classified as good, mid-stations relatively good to moderate category, and downstream samples of the river are classified as relatively bad.
Conclusion: Based on the relationship between each variable, fecal coliform, BOD, COD, ammonium, and turbidity were more effective in determining the IRWQI_SC. Most of the examined variables showed low concentrations in upstream areas of the river while their concentration gradually increased along the river to downstream areas, especially close to urban and industrial districts.
 

Background and Objective: Water distribution networks are prone to terrorist attacks by injecting toxic substances, due to their vastness and availability. The main objective of this paper was detecting the extent of intentional pollution in the urban water distribution network by self-organizing map (SOM).
Materials and Methods: The existing hydraulic condition of the water distribution network covered by reservoir No. 4 in Tehran was modeled as a pilot. Possible injection scenarios of contamination in different parts of the water distribution network were performed using qualitative analysis of the water distribution network, using the EPANET analyzer engine and coding in R software environment. Artificial neural network of SOM was used to find the contamination range for the injection of arsenic at different times and places in the distribution network.
Results: The concentration of contamination at a certain point decreased over time and a high correlation was observed between time and concentration. The extent of contamination depended on the consumption of subscribers and consequently, the time of contaminat injection. The results of the artificial neural network model showed that the method developed in this research was 91% accurate and was able to determine the extent of contamination in the water distribution network at high speed.
Conclusion: SOM can be used as a complement to the water quality monitoring and pollution detection system in the urban water distribution network to determine the extent of pollution when detecting potential pollution in the shortest possible time, and as an alternative to quantitative-qualitative modeling of the water network.
 

Background and Objective: Microplastics can have harmful effects on living things, including humans. These particles have been identified in all water, soil, and food sources. Among these, freshwater resources are more important, because they are considered a water source for humans through drinking water treatment plants (DWTPs). Therefore, this study investigates the performance of Tehran DWTPs in removing these particles.
Materials and Methods: In this study, the performance of three DWTPs in Tehran in removing these particles was investigated. In most studies worldwide, particles larger than 1 µm were examined, but in this study, nanoplastic particles smaller than 1 µm, as well as the effect of the warm and cold seasons of the year on the concentration of these particles were also examined.
Results: According to the results of the study, the amount of micro and nanoplastic particles at the inlet of treatment plants in the warm season of the year was 2569 ± 309 to 3918 ± 425 MP/L, and the output was 1492 ± 32 to 2279 ± 146 MP/L, which indicates an increase in these particles in the warm season. As a result, the studied treatment plants were only able to remove 32.1 to 59.9% of these particles. In addition, using electron microscopy, MPs were classified into three categories in terms of appearance: fiber, fragment, and film. This study completes the knowledge of MPs in this area.
Conclusion: Based on the results of this study, Tehran DWTPs have poor performance in removing these particles.
 

Background and Objective: With the expansion of urbanization and the development of industry, environmental pollution, including sources of drinking water to heavy metals, has become a global problem. Therefore, the present study was conducted to measure the concentration of lead and cadmium in the water of Gorgan distribution network.
Materials and Methods: This is a descriptive cross-sectional study in which the concentrations of heavy metals lead and cadmium were measured in 25 different stations of the Gorgan drinking water distribution network from April to September 2018 by atomic absorption device. Statistical analysis was used from SPSS ver 22 software. Also, zoning maps based on the concentration of these two metals were prepared by Geographic Information System (GIS) software.
Results: The results of measuring the lead and cadmium concentration showed that all measured values are less than national and international standards. In general, the average concentrations of lead and cadmium were 4.38 and 0.1 μg/L, respectively. The results of Kruskal-Wallis test showed that there was a significant difference (p <0.01) between the concentrations obtained from lead metal in different months. Additionally, the distribution map of this lead and cadmium exhibited that in the central areas and some border areas, the concentration of these two metals is higher.
Conclusion: According to the obtained results, it can be seen that the concentration of heavy metals lead and cadmium in the water of Gorgan distribution network is within the permitted standards.
 

Background and Objective: In some villages of Mazandaran, drinking water may be polluted with various pollutants, especially heavy metals (HMs), due to the shallow depth of drinking water sources and the proximity of these sources to farmlands. Therefore, this study aimed to measure the HM pollution level of drinking water in some villages of Mazandaran province and to assess the attributed health risks.
Materials and Methods: HMs content of drinking water in 30 villages with separate water sources in Mazandaran province was measured. Concerning the HMs concentration and toxicity, and exposure route through water drinking, carcinogenic and non-carcinogenic risks were assessed using a Monte-Carlo simulation-based method.
Results: The concentration values of arsenic, cadmium, chromium, nickel and lead in water were <1/0-4.26, < 0.05, <0.15-3.74, <0.3-10.89, and <0.8-4.68 µg/L, respectively. The hazard index (HI) values for non-carcinogenic risk due to the exposure to HMs through drinking of water in various age groups ranged from 3.04E-04 to 9.94E-04. Values of cumulative excess lifetime cancer risk (ELCR_T) for As and Cr were 9.72E-08 and 6.13E-08, respectively.
Conclusion: The results of this study showed that, fortunately, the concentration of metals in drinking water in the studied area was much lower than the national standards and the attributed health risk. Therefore, the drinking water sources in the studied villages had acceptable quality. However, due to the existence of rice paddies in some villages of Mazandaran province, continuous monitoring of pollution levels in the drinking water sources of these areas is essential.
 

Background and Objective: Increasing the productivity of surface water, the unsustainable development of agriculture in the boundaries of rivers, and human sewage have reduced the quality of these water resources. Therefore, investigating the amount of pollution and its sources is very necessary for regional planning. This study aimed to evaluate the water quality of the Golin River using WQI and Liou indexes.
Materials and Methods: Sampling of Golin river water was performed to check water quality based on (WQI) and (Liou) indices in Najjar village station for one year from April 2019 to March 2020.
Results: Water quality, according to the Liou index, during the research period in the sampling station in September and March, was in a good category and other months were slightly polluted. According to the results of the WQI index, water quality in September and March were in the excellent descriptive category, with values of 47.82 and 49.74, respectively, but in other months it was in a good category. In September and March, water quality improved compared to other months because of lower BOD5 due to reduced agricultural activities, and both indicators showed these quality changes well.
Conclusion: Due to the lack of stable conditions in water quality affected by seasonal changes and its departure from the category of high-quality water according to the results of the WQI index and also a little water pollution according to the Liou index, the direct use of Golin River water for drinking purposes is recommended and for this purpose, regular purification should be done and accurate and continuous evaluations of water quality in Golin River are necessary.
 

Background and Objective: Considering the significant number of injured people in spas, the main goal of this research is to provide a model for measuring and managing risk in spas.
Materials and Methods: To prepare the conceptual model of risk, four steps were taken, which include determining the general outline of the model, identifying the parameters, evaluating and scoring the parameters based on the questionnaire, using the hierarchical analysis method, and evaluating and determining the final risk of the pools. According to the allowed standard range of each parameter, five ranges for each parameter were obtained based on the obtained weights, health, safety and environmental risk classes. Finally, by summing up these parameters, the final score of the risk of using each pool is obtained. In order to evaluate the presented model, the risk value of hot mineral water pools in Ardabil province was obtained with the innovative method of this research.
Results: According to the results, according to the risk score, Gutursoi and Gamish-Goli spas have an unacceptable risk level, while Qainarjeh, Shabil, Barjelo and Sablan spas are at a high-risk level.
Conclusion: The presented model was validated with the evidence of forensic events. According to the results of the conceptual model of risk and the score obtained for each component and sub-components, appropriate solutions were presented, including the need to modify the current standards in each spa.

Background and Objective: One of the main ways of transmitting diseases is drinking water, so the safety of drinking water is an important issue for consumers, water suppliers, operators, and health officials. This study was conducted to identify and semi-quantitative evaluation and prioritization of risks in the drinking water supply system of Bostan Abad city.
Materials and Methods: In order to evaluate and document the key elements of WSP and identify the steps that need improvement, the quality assurance tool of the water safety plan (WSP-QA TOOL software) was used, and then based on the guide of the water safety plan from the WHO and the International Association Water safety, WSP team formed. Then the water supply system of Bostan Abad city from the farthest point of the basin to the last consumption point was inspected and described.
Results: The results showed that the highest number of risks are in the water supply sources, distribution network, and point of consumption, respectively. Also, the most vulnerable part of the system was identified as the disinfection unit and storage tanks due to biological and chemical contamination caused by equipment failure and improper preparation of chlorine solution.
Conclusion: In summary, it can be said that carrying out the necessary reforms can play an effective role in reducing the risk potential in times of crisis, which should be given serious attention by water industry officials.
 

Background and Objective: Occurrence of the pharmaceutical active residues (particularly antibiotics) threatens the health of the environment and human society. Therefore, this research aimed to investigate the impacts of the Amoxicillin (AMX) residues on resistance to environmental stress and biochemical compositions of the body in Penaeus vannamei.
Materials and Methods: Six-hundred specimens with a mean (±SD) weight and total length of 9.23±1.77 g and 9.28±0.73 cm were randomly experimented in four triplicate treatments, namely T₁(control): without AMX residues in a rearing environment, T₂: 100 μg/L AMX residues concentration in water, T₃: 300 μg/L and T₄: 500 μg/L for 60 days. At the end of the experimental trial, five specimens for biochemical body composition analyses were separately sampled. Ten shrimps from each treatment were also randomly selected and exposed to 50 ppt salinity stress for 48 hours, and then survival rates were computed.
Results: Body composition analyses showed that moisture and protein not differed among the treatments (p>0.05), while fat in T₂ (28.29±5.50) was significantly more than in others (p<0.05). The lowest values of ash were obtained in T₁ and T₄, and they differed with T₂ and T₃ (p<0.05). The highest survival rate of shrimps exposed to salinity stress (50 ppt in 48 h) was observed in T₂ and T₃, in contrast, the lowest value was recorded for T₄ (p<0.01).
Conclusion: Findings of the present research indicate that the occurrence of high doses of AMX residues pollution in the rearing water affects the stress resistance of P. vannamei which can be due to disruption of protein and fat metabolisms in the shrimp body.
 

Background and Objective: Heavy metals in water can pose risks to human health. Therefore, it is necessary to monitor and measure metals to ensure the health of consumers.
Materials and Methods: This study aimed to measure heavy metals such as arsenic, lead, cadmium, chromium, zinc, and mercury in water resources and urban water distribution networks in spring and summer of 2021 in Maragheh city. Accordingly, 25 samples were taken to investigate the presence of heavy metals. The presence of these metals in water sources was investigated using qualitative maps and finally, by evaluating the health risk caused by the presence of these metals, their effect on the health of consumers has been studied.
Results: Examining the concentration of metals in water resources upstream of the dam shows a relatively high concentration of metals, especially arsenic (13.2 µg/L). Despite this, the amount of arsenic after the water treatment plant and in the distribution network is reduced to an insignificant level. On the other hand, the results show that the amount of zinc metal in the network is higher than in the reservoir of the dam, and its concentration in the dam is equal to zero and in the network, it reaches the highest value of 578 µg/L. Finally, the health risk assessment shows that the calculated THI values for all samples vary between 0.01 and 0.99.
Conclusion: Based on the calculated health risk, there is no threat to the health of consumers regarding heavy metals in Maragheh drinking water. Also, these results double the necessity of additional studies regarding the leakage of zinc metal from the pipes and accessories of the city's drinking water distribution network in the future.
 

Background and Objective: This research tries to analyze the spatial distribution and trend of arsenic level changes in the underground water resources of the Sirjan basin, and also to evaluate and analyze the factors affecting the concentration of this element in these water resources.
Materials and Methods: Sampling of underground water sources in the study area was done by systematic-random method and arsenic concentration was done by ICP-MS method in the laboratory. Also, to evaluate the factors affecting the concentration of arsenic in the underground water resources of Sirjan bathe sin, the method of land systems analysis was used.
Results: The results of the research show that the amount of arsenic in all samples is higher than the Guidelines provided by the World Health Organization so the amount of this element in the underground water sources of the study area varies between 30 and 390 µg/L. Samples No. 9, 13, and 16, which are located in the deepest parts of the basin, have the highest amount of arsenic. For this reason, the durability of water in this part of the basin increases. This reduces the intensity of the current. As a result, according to the cumulative effect law, this process can lead to an increase in arsenic concentration.        
Conclusion: The evaluation of changes in the concentration of arsenic in the underground water resources of the study area indicates that the concentration of this element had a high increasing trend. According to the results, the location of the studied area in the center of hydrothermal and geothermal processes (copper mineralization belt in Iran), the cumulative effect, and the effect of pH on the absorption and desorption of arsenic are among the most important factors affecting the increase of arsenic in the underground water resources of Sirjan Basin.
 

Background and Objective: Nowadays, the use of biochar as a new and suitable adsorbent to remove inorganic pollutants from water sources has grown significantly. The present study was conducted to evaluate the effects of biochar physical modifications compared to unmodified biochar on nickel (Ni) removal efficiency in aqueous solutions.
Materials and Methods: After the production of cypress cones biochar (RB), biochar particles (<164 µm) were crushed into very small (<26 µm) dimensions (BMB) using a planetary ball mill and after evaluation their various properties by SLS, BET, FTIR and SEM techniques, their application (RB and BMB) in optimizing the Ni removal from aqueous solutions were evaluated using the response surface methodology (RSM: Box-Behnken design).
Results: Based on the results, the physical modification of biochar (BMB) decreased the particle size by 6.2 times, increased the specific surface area by 4.9 times, increased (containing oxygen) and decreased (aliphatic and OH stretching groups) of specific functional groups and finer surface morphology, compared to RB. The use of BMB in the aqueous solution caused an increase of 9.7% (on average) in the removal of Ni compared to the RB sample. The fitting of the data obtained from Ni removal in the Box-Benken model in both adsorbents shows the appropriate prediction of this model in the optimization of Ni removal from aqueous solutions.
Conclusion: According to the results of this research, the physical modification of biochar, as a simple, cheap, and environmentally friendly method, due to the increase in the efficiency of Ni pollutant removal, can be introduced as a suitable method in the activation of biochar, which further research is required based on the type of biochar and various pollutants.
 

Background and Objective: Water resources deficiency has caused the use of effluents to be considered as a source for re-use in the form of haloculture projects. An attempt has been made to investigate the possibility of using effluent produced by sugarcane production companies in the implementation of haloculture projects, from the viewpoint of the most used pesticides.
Materials and Methods: Ten water, four sediment, two plant, and two fish samples were analyzed using gas chromatography-mass spectrometry (GC-MS) and high-performance liquid chromatography (HPLC) to determine the concentration of pesticides. In order to assess the ecological risk, toxic unit (TU) and risk quotient (RQ) were calculated.
Results: Glyphosate and Ametryn in all liquid, solid, and biological samples had concentrations below the detection limit. 2.4.D, Metribuzin, and Atrazine had detectable concentrations in the samples. However, their concentrations are lower than the standard values. Metribuzin and Atrazine had high concentrations in the stems and leaves of reeds in the region, which may indicate the role of these plants in the remediation of water and sediment from these compounds.
Conclusion: Using effluent from Amirkabir and Mirzakouchak Khan agro-industrial complexes to implement the haloculture project does not pose a particular problem from the viewpoint of contamination with the studied pesticides. This is confirmed due to the small concentrations of the studied compounds in the liver and below the detection limit in the muscles. However, it is necessary to carry out more studies to evaluate the quality of effluent in terms of the other types of pollution.
 

Background and Objective: Microplastic pollution due to its small size can be used by a wide range of marine organisms and accumulate mainly in their digestive system, as they have been found in the tissues of aquatic animals, including fish. Due to the nutritional importance of fish for humans, it is very important to check their contamination. The main purpose of this research is to investigate the presence of microplastics in skipjack tuna (Katsuwonus pelamis) in the Oman Sea.
Materials and Methods: 17 pieces of skipjack tuna were used. After the biometry, dissection and isolation of the digestive system of the fish, the digestion and extraction of microplastics were done using KOH solution. Identification and counting were also done by a stereomicroscope equipped with a digital camera. FTIR spectrophotometric analyses were performed to investigate the polymers.
Results: The total frequency and average frequency of microplastics are 331 particles and 19.4±7.3 particles per individual, respectively. String (64.35%) and pieces (28.7%) were the dominant forms in the samples. The highest color spectrum was assigned to red (28.7%) and the lowest to violet (1.51%). The largest number of identified microplastics had a size of 0.5-1 mm (53%). Analysis of particles by ATR-FTIR method showed that nylon polymer and polycarbonate were the dominant polymer particles.
Conclusion: Microplastics are present in all samples. The abundance of microplastics in water, sediments and contaminated bait makes them easily available and swallowed by fish, which is most likely the main reason for the presence of microplastics in fish.
 

Background and Objective: Identifying the quality of non-conventional waters and exploring their optimal utilization are fundamental measures for maintaining public health. This study aims to investigate the effluent quality of the irrigation canals in Pakdasht farms.
Materials and Methods: In this cross-sectional descriptive study, 120 samples were collected from 6 irrigation canals in Pakdasht fields over a period of 5 months. The physicochemical and microbial characteristics of the canal effluents were determined based on the standard methods of water and wastewater tests. The concentration of heavy metals was measured using an ICP device. To determine the possibility of using the effluent of Pakdasht canals for agricultural purposes, the Environmental Protection Organization of Iran and FAO standards were used.
Results: The average concentrations of COD, BOD₅, TSS, TDS, NO₃^-, SO₄^-2, PO₄^-3 parameters were 259, 125, 105, 697, 4.5, 94.4, 13.5 mg/L. Additionally, the average number of total and fecal coliforms in the effluent of the canals exceeded the standard values set by IRNDOE and FAO. The mean pH was 6.97, the electrical conductivity (EC) was 1014 μm/cm, and the turbidity was 76.2 NTU. The detected concentrations of heavy metals were awithin the following ranges: Cr (0.025-0.045 mg/L), Cd (0.0006-0.001 mg/L), Pb (0.0006-0.001 mg/L), Co (0.038-0.059 mg/L), and Ni (0.05-0.06 mg/L), which were roughly lower than the suggested standards. However, both HEI and WWQI indices confirmed that the water was unsuitable for agricultural irrigation.
Conclusion: Based on the comparison of the results of the parameters measured in this study with the environmental and FAO standards, the effluent from the irrigation canals of Pakdasht city is deemed unsuitable for the irrigation of warm-season crops but suitable for fodder and industrial crops.
 

Background and Objective: There have been concerns about microbial contamination along the coastal cities in the north of the country, particularly in cities of Mazandaran province, which could pose health risks for swimmers and tourists. The present study aimed to quantitatively assess the risk of gastrointestinal diseases resulting from exposure to E. coli and enterococci bacteria during recreational activities on the beaches of Fereydunkanar.
Materials and Methods: In this cross-sectional descriptive study, 66 grab samples collected during the summer were analyzed to investigate microbial contamination in the recreational beach waters of Fereydunkanar.The Monte Carlo simulation method was used to calculate both daily and annual infection risks.
Results: The findings demonstrated that transmission of enterococci was more likely than that of E. coli in the swimming areas of these beaches. The average annual infection risk for E. coli was 0.41 for adults and 0.69 for children . Additionally, the annual risk of enterococci infection was 1 for adults and 0.99 children and, which exceeds the range advised by the WHO and EPA. These findings indicate that children have a higher infection risk compared to adults.
Conclusion: Unrestricted discharge of municipal and industrial wastewater effluents into sea and rivers can contribute to the presence of harmful microbes in beaches. By implementing effective environmental and recreational management strategies, it is possible to minimize the risk of public health hazards at recreational beaches while also preserving the natural beauty of these important public spaces.
 

Background and Objective: In recent decades, the issue of crop product safety has led to develop methods for analyzing pollutants in crops. In the present study, ultra-trace amounts of lead (II) ions were measured in lettuce and water samples collected from Shahmirzad, located in Semnan province, an area known for its lead-containing mineral mines.
Materials and Methods: After sampling and pre-preparation, the lead content in each sample was extracted using solid phase extraction with modified silica gel. The recovery percentage of lead was then determined using atomic absorption spectroscopy.
Results: Optimization of key parameters such as pH, adsorbent amount, analyte flow rate, and volume resulted in a recovery rate of 104%. The experiments also demonstrated a very low limit of detection (LOD) of 1.14 ng/mL, a concentration factor of 250, high analyte selectivity of the adsorbent in the presence of interfering ions, and a high adsorbent capacity of 2.93 μg/g.
Conclusion: The evaluation of experimental data indicates that the current study provides a highly selective method that can be applied to the extraction and recovery of various analytes from different sample types.