Iranian Journal of

Background and Objective: Natural organic matters (NOMs) are a mixture of chemically complex polyelectrolytes with varying molecular weights, produced mainly from the decomposition of plants and animal residues. Various purification methods are used for removal of NOMs from water. The objective of this study was to remove NOMs from aqueous solution using reformed continuous carbon nanotubes column. Materials and Methods: The removal of NOMs from aqueous solution using reformed continuous carbon nanotubes column was studied. Effect of several variables such as zero point of pH (pH_ZPC), pH, influent concentration of natural organic matters were studied and different isotherms were assessed. Results: Investigation of pH effect showed that the adsorbability of NOMs increased with decreasing of pH. The experiments indicated that carbon nanotubes (CNT) samples exhibit pH_ZPC around 6. Results from Freundlich, Langmuir, and BET isotherm experiments revealed that the correlation coefficient R² in Freundlich model was higher than that of Langmuir. In addition, experiments of continuous flow in different initial concentrations of NOMs showed that the adsorption capacities of CNT were 53.46, 30.40, and 24.75 mg/g for NOMs initial concentrations of 10, 5, and 3 mg/L, respectively. Conclusion: The present study shows that CNTs have high potential for adsorption of NOMs from aqueous solution

Background and Objectives: Remaining of crude oil in storage tanks usually results in accumulating oily sludge at the bottom of the tank, which should be treated and disposed of in a suitable manner. The efficiency of in-vessel composting process in removing total petroleum hydrocarbons (TPH) from bottom sludge of crude oil storage tanks was investigated in the present study.

Material and methods: The sludge was mixed with immature compost at the ratios of 1:0 (as control), 1:2, 1:4, 1:6, 1:8, and 1:10 (as dry basis) with the initial C:N:P and moisture content of 100:5:1 and 55% respectively for a period of 10 weeks. The moisture adjustment and mixing process were done 3 times a day during the composting period. Sampling and analysis of TPH and pH were done every week and every two days, respectively.

Results: TPH removal in the 1:2, 1:4, 1:6, 1:8, and 1:10 composting reactors was 66.59, 73.19, 74.81, 80.20, and 79.91%, respectively. Thus, initial adjustment of sludge to immature compost ratios plays a great role in reduction of TPH. The results of the control reactors indicated that the main mechanism of TPH removal in the composting reactors was biological process.

Conclusions: In-vessel composting by addition of immature compost as amendment is a viable choice for bioremediation of the bottom sludge of crude oil storage tanks.

Background and Objective: Considering the environmental problems raised from current plastic packaging, edible and biodegradable films could be developed and also be effective in controlling the chemical and microbial properties of food especially if their effect be strengthened by adding natural antioxidant and antimicrobial agents like herbal essential oils. This study aimed at assessing the effect of packaging with chitosan film containing garlic essential oil on the chemical changes of chicken fillet during storage at refrigeration temperature.

Materials and Methods: Different levels of garlic essential oil (0, 0.5, 1 and 2%) were used in chitosan film preparation. Through casting method and using glycerol as plasticizer and tween 80 as emulsifier, different films were prepared after homogenization and molding. Chemical tests were conducted in days 0, 2, 4, 7, 10, and 14 on chicken fillets covered with different films and stored at 4 °C. Statistical analysis was performed using SPSS software.

Results: Samples covered with different films showed lower values for pH, total volatile nitrogen (TVN), Thiobarbituric acid-reactive substances (TBARs), and peroxide index (P.V) compared with controls during the study (p ≤ 0.05). Generally, a dose-dependent trend was observed by essential oil addition.

Conclusion: Chicken packaging with chitosan film especially by adding various levels of garlic essential oil could had a preventive effect on major chemical spoilage factors. Considering the relatively similar preventive effect of 1 and 2 % essential oil levels and also economic aspects, optimum dose for essential oil could be 1 % in the film.

Background and Objectives: In this study, contribution of exhaust emission and CO distribution was estimated in enclosed residential complex parking.

Materials and Methods: This was a descriptive - analytical study consisted of two stages. In the first stage, the emission contribution of vehicles was determined. In order to determine the contribution of exhaust gas emissions, through gas species, only four species CO, O₂, CO₂, and N₂ were measured. Concentration of CO, O₂, and CO₂ was estimated using data obtained from the vehicle emissions monitoring system. The amount of N₂ was estimated from sum ratio of all species, which equals to 1. Then, using computational methods, the amount of the emission contribution from vehicles. In the second phase, to measure the distribution of CO pollutant, gas sampling and collecting was performed using sampling bags made of inert materials with a volume of 10 l at six points. Sampling was conducted in accordance with the requirements of OSHA ID 210. The Obtained data were analyzed using SPSS Ver.16 software and Pearson statistical test (P > 0.05 means there was no significant difference).

Results: Maximum contribution was estimated for Pride with amount of 44.4 g/s and minimum contribution was estimated for Tiba with amount of 0.3 g/s. The minimum and maximum distribution value of CO concentration was achieved 3.6 and 69.48 ppm respectively. It was found that no significant relationship was observed between the values of exhaust emissions and CO distribution. However, the distribution of concentration was associated with locations and the number of openings, the number and type of vehicle, time of operation of the vehicle, the vehicle performance, and environmental factors.

Conclusion: Measuring vehicles CO emission indicated  that the concentration was beyond the permissible level recommended by the World Health Organization at some. Moreover, it was indicated that natural air conditioning is an effective alternative for improving the air quality in built environments and suitable quality in built environments is achievable through reasonable architectural design, without need to spend too much expense.

Background and Objective: Arsenic is one of the most toxic pollutants in groundwater and surface water. Arsenic could have lots of adverse impacts on human health. Therefore, access to new technologies is required to achieve the arsenic standard.

Materials and Methods: The present study was conducted at laboratory scale in non-continuous batches. The adsorbent of zero-valent iron nanoparticles -Chitosan was produced through reducing ferric iron by sodium borohydride (NaBH₄) in the presence of chitosan as a stabilizer. At first, the effect of various parameters such as contact time (5-120 min), pH (3-10), adsorbent dose (0.3-3.5 g/L) and initial concentration of arsenate (2-10 mg/L) were investigated on process efficiency. Then optimum conditions in terms of contact time, pH, adsorbent dose and initial concentration of arsenate were determined by RSM method. Freundlich and Langmuir isotherm model equilibrium constant, pseudo-first and second order kinetic constants were calculated. The residual arsenate was measured y using ICP-AES.

Results: The optimum values based on RSM for pH, absorbent dose, contact time, and initial concentration of arsenate were 7.16, 3.04 g/L, 91.48 min, and 9.71 mg/L respectively. Langmuir isotherm with R²= 0.9904 for Arsenate was the best graph for the experimental data. According to Langmuir isotherm model, the maximum amount of arsenate adsorption was 135.14mg/g. . The investigation of arsenate adsorption kinetics showed that arsenate adsorption follows the pseudo-second kinetics model.

Conclusion: This research showed that the adsorption process is depended on pH. With increasing pH, the ability of amine groups in chitosan are decreased to protonation, caused to decrease the efficiency of arsenate removal at high pH.

Background and objective: Compost is beneficial for conditioning the structure and nutrient content of soil. Toxic metals are the most important contaminants that can enter the food chain through the compost products and affect human health. The aim of this study was to assess the arsenic, mercury, cadmium, and lead levels in six brands of vermicompost produced from the organic solid wastes in Tehran and to compare the amounts with the international and national standard levels.

Materials and Methods: This was a descriptive - analytical study in which samples of six brands of vermicompost products were randomly selected from the distribution centers in Tehran, and from each brand four samples were prepared (24 samples). Then the samples were extracted using the TCLP (Toxicity Characteristic Leaching Procedure) method and after filtration the metal concentrations were measured by Inductively Coupled Plasma (ICP). All data were analyzed using Excel software.

Results: The means and standard deviations of the toxic metals concentrations (arsenic, mercury, cadmium, and lead) in the collected samples of each brand were reported in terms of mg/kg. The maximum concentrations of these toxic metals were 7.45, 0.15, 0.19, and 79.95 mg/kg, respectively.

Conclusion: The results indicated that the levels of toxic metals in the vermicompost samples derived from the municipal solid waste in Tehran were lower than the permissible limits of the national and international standards.

Background and Objectives: The continuous increase in solid waste generation worldwide due to population growth and industrialization, calls for management strategies that integrate concerns for environmental sustainability. By quantifying environmental impacts of systems, Life Cycle Assessment (LCA) is a tool which can contribute to answering that call. The aim of this study was to evaluate environmental pollutants resulting from various treatment options including anaerobic digestion, incineration, and landfill of Municipal Solid Waste (MSW) generated daily in Tehran.

Materials and Methods: First, the physical properties of the waste and consumption of inputs in the study area were determined from September to October, 2014- 2015. Then the different steps of LCA in relation to each of the subsystems were followed (with SimaPro software). Finally, the results based on the CML Baseline 2000 were presented and analyzed.

Results: It was found that when the higher rate of separation and processing in any subsystems increases, the emission of environmental pollutants decreases, so that the global warming potential, acidification, eutrophication, and abiotic depletion as the most important impact categories in the subsystems of anaerobic digestion were obtained as -125935 kg CO₂/day, -449 kg SO₂/day, -1690 kg PO₄^3-/day and -0.43 kg Sb/day, respectively and in incineration were obtained as -264872 kg CO₂/day, -974 kg SO₂/day, -3471 kg PO₄^3-/day and -0.76 kg Sb/day, respectively, while in the landfill subsystem, they were estimated to be 74478 kg CO₂/day, 362 kg SO₂/day, 118 kg PO₄^3-/day, and 0.13 kg Sb/day, respectively.

Conclusion: According to the constituent processes of each of the subsystems and the results of the evaluation of exhaust emissions subsystems, it can be concluded that in an integrated system of waste management, the energy-generating systems such as anaerobic digestion and incineration should be as the first priority and the traditional subsystems such as landfill should be as the last priority.

Background and Objective: Exposure to chemicals such as heavy metals can be occurred through the route of drinking water consumption. Chromium is an important pollutant because of its role in the appearance of carcinogenic and non-carcinogenic health effects in humans. In this study, we studied the carcinogenic risk and non-carcinogenic hazard of chromium due to the consumption of bottled drinking water distributed throughout Iran.

Materials and Methods: The Hazard Quotient (HQ) and Excess Lifetime Cancer Risk (ELCR) indices were calculated. Monte-Carlo simulation technique was adopted for simulating  uncertainty in the estimation of HQ and ELCR based on the input variables namely the concentration of pollutant, per capita water consumption, body weight, reference dose, biological availability, and source contribution factors. 

Results: The average concentration of chromium in bottled waters determined was 4.79 ± 2.32 µg/L. The amounts of HQ and ELCR  for the age groups of  lower than  2, 2 to 6, 6 to 16 and over 16 years old were 0.000354, 0.00292, 0.00236, 0.00147 and 4.04×10^-11, 5.99×10^-10, 8.61×10^-10 and 2.34×10^-9, respectively.

Conclusion: In regard to the concentration of chromium in bottled waters in Iran, the incidence probability and the possibility of carcinogenic and non-carcinogenic effects by this pollutant due to the consumption of bottled water are considerably low and there is no health concern for any age groups.

Background and Objective: The performance of in-vessel composting process, as one of the most effective methods of oily sludge treatment, depends on factors such as nutrients and temperature. Therefore, it is crucial to investigate the trend of changes of these factors. The aim of the present study was to investigate the trend of changes of organic carbon, nitrogen, phosphorus, and temperature during the composting of bottom sludge of crude oil storage tanks.

Materials and Methods: The sludge was mixed with the immature compost at the various ratios of sludge to compost including 1:2, 1:4, 1:6, 1:8, and 1:10 with the initial C/N/P of 100/5/1 and then was composted for a period of 10 weeks. The process of mixing and moisture adjustment of the mixtures was done 3 times a day during the composting period. Sampling and analysis were performed every week for organic carbon, nitrogen, and phosphorus and every day for temperature.

Results: The research indicated that the concentrations of organic carbon, nitrogen, and phosphorus were decreased sharply during the first weeks of the process and then they were decreased gently. At the final stage of the composting, the ratios of C/N and C/P increased from 20:1 and 100:1 to 26:1 and 166:1, respectively. In addition, the temperature of the reactors was kept in the mesophilic range during the process period.

Conclusion: The similar trend of decrease of organic carbon, nitrogen, and phosphorus in the composting reactors is an indication of decreasing the activity of the microorganisms involved in petroleum hydrocarbons degradation.  

Background and Objective: Being low cost of building and operation, anaerobic baffled reactor is considered superior to aerobic methods of wastewater treatment, especially for small communities. However, it needs to be studded for upgrade and overcome of its limitations. The purpose of this study was to evaluate the performance of FABR and RABR reactors for the municipal wastewater treatment at laboratory scale and in field conditions to determine their optimum conditions in reaching effluent discharge standards.

Materials and Methods: This study was conducted in Khoy wastewater treatment plant. FABR was operated for 267 days with hydraulic retention time of 18-48 h and RABR was operated for 90 days with media bad rotation of 10-50 rpm. The reactors were fed in line from the wastewater canal. Using composite sampling, 224 samples were taken from the inflow and outflow of the reactors and each sample was analyzed for parameters of COD, BOD, TSS, VSS, TKN, and TP.

Results: The reactor startup took about 107 days. FABR removal efficiency was 93-80, 21-10, and 30-21% for COD, TKN, and PO₄ respectively at HRT of 48-18 h. FABR reached effluent disposal standard of TSS, COD, and BOD in all conditions and optimum HRT of 36 h. RABR reached to these standards at HRT 24 h and 50 rpm. However, none of them could meet the nutrient effluent standards.

Conclusion: FABR is an appropriate system for municipal wastewater treatment but for reaching N and P effluent standard, it should be combined with aerobic post-treatment. Moreover, in order to reuse the reactor's nutrient-rich effluent for irrigation; it can be reused as subsurface irrigation.

Background and Objective: Water corrosion and scaling are known as destructive phenomenon of drinking water quality and water facilities. In this study, the groundwater tendency to corrosion or scaling in source water, water storage reservoirs and distribution system were studied. Simultaneous use of some qualitative and a quantitative index along with statistical analyses to assess the water scaling or corrosion tendency were investigated.

Materials and Methods: The data analysis of groundwater, water storage reservoirs and water distribution system in rural area of Kurdistan province were analyzed and the amount of Langelier (LI), Ryznar (RY), Pockorius (PSI) and Larson–Skold (LS) and CCPP indices were determined. Corrosion and scaling threshold for qualitative indices were determined based on CCPP index. The mean of indices was compared with the thresholds using independent t-test. ANOVA was used to assess the difference between the indices in different sources of water.

Results: The balance range for LI, RY and PSI found to be -0.1-0.05, 7-9 and 7.1-8.5. The mean CCPP for groundwater, reservoirs and networks were 9.27 ± 1.29, 9.13 ± 1.25, 11.25 ± 1.23, respectively. All three sources of water have some tendencies toward scaling; however, a significant balance status was confirmed statistically. According to Larson–Skold index, sulfate and chloride anions did not play a role in scaling process.

Conclusion: The use of qualitative indices with CCPP index can provide more accurate estimation of water tendency toward scaling or corrosion. The assessment of qualitative indices along with CCPP is recommended in drinking water corrosion monitoring studies.

Background and Objective: Polycyclic aromatic hydrocarbons (PAHs) are a group of organic pollutants that are mostly generated during the incomplete combustion. The main objective of this study was to characterize potential sources of PAHs in Tehran.

Materials and Methods:, Samples of PM₁₀ were collected at 10 monitoring stations belonging to Tehran Air Quality Control Company (AQCC) and transferred to laboratory for analysis. Besides, a SKC Flite 2 Air Sampling Pump (SKC, USA) equipped with a sampling head and PM₁₀ size-selective inlet was used at four stations to compare the results obtained by collecting AQCC monitors (AQCCMs) tapes with the standard sampling procedures for assessing the interchangeability of two field sampling methods. The principal component analysis (PCA) and diagnostic ratios were applied to identify emission sources and source contribution.

Results: The average diagnostic ratios of phenanthrene (Phe)/ (Phe+anthracene (Ant)), benzo(a)anthracene (BaA)/ (BaA+chrysene (Chry)), fluorantene(Flu)/ (Flu+pyrene (Py)), and indeno(1,2,3cd) pyrene (IcP)/(IcP+benzo(ghi)perylene (BghiP)) in samples were 0.79, 0.52, 0.43 and 0.38, respectively. These ratios showed that the combustion, especially fossil fuels and motor vehicles, was the main sources of PAHs emission in Tehran. The results of  PCA analysis also indicated that 49, 29 and 22% of PAHs sources in Tehran atmosphere were attributed to gasoline-driven vehicles, diesel vehicles and other sources, respectively.

Conclusion: According to the results, the combustion, especially fossil fuel and motor vehicle, was the main sources of PAHs emission in Tehran.

Background and Objective: Optimum number of air quality monitoring stations in Mashhad is an essential task for management of the urban environment. However, real monitoring and accurate information on the status of air quality require proper spatial distribution of air quality monitoring stations in the city of Mashhad. The aim of the present study was to determine optimum site locations for air quality monitoring, including Downtown Pedestrain Exposure Station, Downtown Background Exposure Station, and Residential Population Exposure Station by three Multiple-Criteria Decision-Making (MCDM) techniques.

Materials and Methods: In the precent study, sites for new air quality monitoring stations t in Mashhad were determined based on a proposed protocol in the United States. Accordingly, the criteria effective for site selection such as population density, distance from existing stations, vicinity to vegitation, vehicle density and other factors were used by applying Analytic Hierarchy Process (AHP), Fuzzy set, and Probability Density Function (PDF).

Results: Location similarity of the sites proposed by decision making methods was evaluated to know its reliability. The compactness of distribution of the proposed sites were compared by applying spatial statistic methods auch as Average Nearest Neighbor (ANN) and Standard. The results from ANN indicated that fuzzy set mapped the suggested sites was fully scattered within the entire city of Mashhad and was statistically significant at 99% confidence level. The PDF method also offered the same spatial pattern as fuzzy set. Overall results of this study indicated spatial optimization of suggested sites location for fuzzy set and PDF.

Conclusion: The overall results of the decision-making methods used in this study indicated that it is necessary to increase number of air quality monitoring stations at Northwest of Mashhad due to the urban growth in the city. The results also showd the possibility of using Probability Density Function (PDF) as a method of decision-making in GIS for locating and ranking of new air quality monitoring stations.

Background and Objective: Bottled water consumption is rapidly increasing in recent years for various reasons.The main aim of this study was to survey the geological origin of Iranian bottled water and determine compliance or lack of compliance with the experimental data obtained through sampling 71 brands of drinking bottled water and mineral water.

Materials and Methods: In this study the coordinates of access points as a georef of the chosen points were launched on the "Iran geological map" and "Iran mineral and warm water map." The compliance of laboratory data and water types with the geological data were evaluated and compared with the important ionic ratios of the extracted water through using awh software.

Results: In examining 71 brands of the bottled water, 28% of the brands did not agree with the laboratory results, reflected by observing higher levels of bicarbonate in 50% of the bottled waters than those of the geological data.. Additionally, 70% of water types were calcic bicarbonate. In the bottled waters from North Alborz range with coastal Time deposits around the Caspian Sea, there was a source of brine or sea water that was about 55% of this amount.

Conclusion: Water pass through different geological structures and the dissolution phenomenon might be an important factor for the observed disagreement. Because chemical treatment and use of additives on mineral waters are not allowed it prompts further studies to determine the cause and origin of this issue through sampling from the factory and water source.