Showing 8 results for Aqueous Solutions
M.t Ghaneian, M.h Ehrampoush, Gh Ghanizadeh, M Dehvary, M Abootoraby, T Jasemizad,
Volume 3, Issue 2 (7-2010)
Abstract
BackgroundandObjectives: Dyes are organic compoundswith complex structures,which due to toxicity, carcinogenicity and nonbiodegredabity, this type of pollutants is one of the most important pollutants of the environment. The goal of this researchwas to study the feasibility of the application of solar irradiation in presence of potassium persulfate (K2S2O8) for the removal of Reactive blue19 (RB19) from synthetic wastewater.
Materials and Methods:This research wascarri edoutin laboratory scalewith using of 200ml volume of batchphotoreactor.The effectsofoperatingparameters suchas concentrationofK2S2O8,pH,photoexposure time and preliminary concentrations of dye on decolorization have been evaluated.Different concentrations of pollutant inwastewaterwere prepared by solution of variousmasses of RB19 on tapwater. The reactors were exposedwith natural solar irradiation as aUVAsource from11 amto 14 pm.Themaximumabsorbtion wave length of this dye (!max) was determined by spectrophotometer (Unico, 2100). The measurement of dye concentrations was determined with using of standard curve and its best line equation
Results:Analysis of absorbtion spectra showed that the !max of RB19 is 592 nm. The average intensity of the UVA irradiated from solar system was 54.6 µW/Cm2. The results of decolorization process showed that 38.2%of this dye can be removed within 3 hr in the presence of potassium persulfate and decreasing of pH leads to the elevation of dye removal efficiency. Based on these findings, the efficiency of dye removal with 3h photoexposure time and pH ranges of 4,6 and 8 were found to be 98.2 88.5 and 78.5%, respectively.Also, the results showed that increasing of K2S2O8 dosage leads to elevation of dye removal efficiency in 3h photoexposure time and K2S2O8 dosages within 1-5mmol/L, with the removal efficiency of 75,86,92,95 and 98.5%, respectively.Analysis of data indicates that the kinetic of the removal of RB19 with this process is a first order reaction which its rate constant is 0.01min-1.
Conclusion: Due to the operation problems presented in heterogeneous photocatalitical processes such as catalysts separation and high costs of operation and maintenance of these processes caused by manmade sources of irradiations homogeneous photocatalitical process with using of potassium persulfate associated with natural solar irradiation can be used as a suitable process for the removal of dyes from textile industries wastewaters.
R Fouladi Fard, A.a Ebrahimi,
Volume 3, Issue 4 (1-2011)
Abstract
Background and Objective: Nickel (II) and cadmium (II) are important in environmental pollutant. Biosorption of heavy metals can be an effective process for the removal and recovery of heavy metal ions from aqueous solutions because of the decrease in sludge problems, economical issues, high efficiency and compatibility with the environment.
Materials and Methods: power of wasted activated sludge have been contact with nickel (II) and cadmium (II) solutions in 0.25 and 0.75 milli molar invarious pHs and mixing pace, at 24-26 0C temperature on batch reactor system .After two hours (continuously 5-420 min in kinetic study) samples were analyzed with atomic absorption spectrophotometer.
Results:The kinetic study results show that equilibrium adsorption time for nickel (II) and cadmium
(II) reached within 2 hr, but the profile curve of cadmium (II) biosorption was smoother than nickel (II) biosorption. Both metals adsorption followed the Langmuir model and the maximum adsorption capacity (qmax) for nickel (II) and cadmium (II) was 0.195 and 0.37 milli mole per gram respectively. The increase in pH resulted in adsorption increase for both metals. For cadmium (II) at 0.25 and 0.75 mMinitial concentration there was no adsorption at pH 2 where as nickel (0.25 mM) adsorption was observed at the same pH. The optimum mixing rate for both metals was 200 rpm and this effect was more obviously in greater concentration.
Conclusion: Like othe biosorbents ,wasted activated sludge showed greater capacity for cadmium(II) biosorption than nickel (II). Cadmium (II) in modeling and biosorption characteristics study had more conformity than nickel (II).
Saeed Parastar, Simin Nasseri, Amir Hossein Mahvi, Mitra Gholami, Amir Hossein Javadi, Saeedeh Hemmati,
Volume 5, Issue 3 (10-2012)
Abstract
Background and Objectives: Pollution of water resources to nitrate is an
environmental problem in many parts of the world. This problem possibly causes
diseases such as methemoglobinemia, lymphatic system cancer and Leukemia.
Hence, nitrate control and removal from water resources is necessary.
Considering that application of nanomaterials in treatment of environmental pollutants
has become an interesting method, in this research use of Ag-doped TiO2 nanoparticles synthesized through photodeposition produced under UV irradiation
was studied for removal of nitrate from aqueous solutions.
Materials and Methods: Three nitrate concentrations of 20, 50, and 100 mg/L were considered. In order
to determine the effect of Ag-doped TiO2 nanoparticles on nitrate removal, dosages of 0.1, 0.4, 0.8 and 1.2 g/L nanoparticles were
used pH range of 5-9 was also considered. The effect of Ag-doped TiO2 nanoparticles both in darkness and under UV irradiation was studied. Moreover,
the presence of chloride and sulfate anions on the system removal efficiency
was investigated.
Results: The optimum
performance of nitrate removal (95.5%) was obtained using nitrate concentration
of 100 mg/L, in acidic pH and 0.8 g/L Ag-TiO2. Increase of
nanoparticle dosage up to 0.8 g/L, increased the removal efficiency, but for
1.2 g/L dosage of nanoparticles, the removal efficiency decreased. Maximum
reduction performance without nanoparticles, under UV irradiation and under
darkness conditions were 32% and 23.3% , respectively. In addition, we found
that presence of sulfate and chloride anions in aqueous solution reduced
efficiency of nitrate removal.
Conclusion: Results of
this study showed that Ag-doped TiO2 nanoparticles may be
efficiently used for nitrate removal from aqueous solutions.
Amir Sheikh Mohammadi, Mahdieh Sardar,
Volume 5, Issue 4 (2-2013)
Abstract
MicrosoftInternetExplorer4
Background
and Objectives: Antibiotics are
potential pollutants that represent an important environmental problem because
of their toxic effects on the food chain and aqueous streams. The objective of
this research was to study the adsorption of penicillin G on to chestnut shell
as an inexpensive adsorbent.
Materials and Methods: This study was performed at laboratory scale
and batch system. We studied the influence of process variables such as
adsorbent dose, initial PEN G concentration, pH of solution, contact time, and
breakthrough curves. In order to find out the possibility of reuse, desorption
study was also carried out. The surface characteristics of adsorbent were
investigated using Fourier Transform Infra-Red and Scanning electron
microscope. Equilibrium study data were modeled using Langmuir, Freundlich, and
D-R models. Moreover, kinetic studies
were done by three models of pseudo first order, pseudo second order, and
intra-particle diffusion.
Resuls: The maximum
PEN G removal achieved was 92%, at pH 3, adsorbent dose 0.1 g/l and contact
time 120 min. The Langmuir equation (R
2=0.99) provided the best fit
for the experimental data. It was also found that adsorption of PEN G by
chestnut shell followed pseudo- second order model (R
2= 0.992).
Conclusion: According to the results obtained, chestnut
shell appears to be a suitable, low cost and efficient adsorbent for removing
PEN G from waste streams.
Roohan Rakhshaee, Zahra Zamiraee, Somaieh Baghipour, Mohammad Panahandeh,
Volume 5, Issue 4 (2-2013)
Abstract
MicrosoftInternetExplorer4
Background and Objectives: Azolla Filiculoides as a non-living fern was used in a
batch system to remove "Basic Blue 3", which is a cationic dye and a
carcinogenic agent.
Materials and Methods: We used a batch system by applying certain concentrations of dye contaminant
and in the presence of a certain amount of adsorbent under optimum conditions.
The main groups presenting in the Azolla cell wall were evaluated by
acidification and alkalization of Azolla's media and then potentiometric
titration with standard basic and acidic solutions.
Results: It was
observed that the removal efficiency of dye using non-living Azolla in
accordance with the Langmuir isotherms was 82% for the initial dye
concentration of 200 mg/lit under reaction conditions consisting of contact
time 6 h, pH= 6, temperature 25 ˚C, and dose 5 g/lit. Q
max (maximum
uptake capacity) by the activated Azolla at three temperatures 5, 25 and 50 ˚C
was 0.732, 0.934, and 1.176 mmol/g respectively. ΔG (Gibbs free energy changes)
was obtained for these temperatures as -0.457, -0.762, and -1.185 kJ/mol
respectively.
Conclusion: Removal of
basic blue 3 using Azolla is an economically and effective method.
Behrooz Karimi, Mohamad Sadeg Rajaie, Mohamad Javad Ghanadzadeh, Masome Mashayekhi,
Volume 6, Issue 4 (3-2014)
Abstract
Backgrounds and Objectives: Nowadays, global concerns about nitrate in groundwater and its adverse impact on health have increased. This study aims to evaluate the efficiency of nitrate reduction from aqueous solution through modified Fenton process using Nano scale zero-valent iron. Material and Methods: This research was an experimental study and performed at laboratory scale. Nitrate reduction was conducted by advanced oxidation process of Fe°/FeІІ/FeШ/H2O2 at pH 2-10, contact time 10-90 min, nitrate concentrations of 50-300 mg/L, and the molar ratio of [H2O2]/[Fe] 0.5-5. The effect of adding H2O2, molar ratio of reagents, contact time, and pH on nitrate removal was examined and optimal conditions for each of these parameters were determined. Spectrophotometer Dr/5000 was used to measure nitrate in the effluent. Results: We found that the optimal parameters in our studywere pH 3, the molar ratio [H2O2]/[Fe°] of 0.5, and the contact time 15 min. By applying these conditions, nitrate removal efficiency at the retention time 15 min, initial nitrate concentration of 100 mg/L, iron concentration of 10 mg/L, and pH 4 for FeШ، FeІІ، Fe°، FeІІ/Fe°/H2O2 and FeШ/Fe°/H2O2 was 10.5, 27.6, 36.5, 62.3, and 74% respectively. Conclusion: According to the experimental results, it was determined that modified Fenton process using zero iron nano-particles can reduce nitrate under optimal conditions and this method can be used for the removal of similar compounds.
A.r Rahmani, F Nazemi, F Barjasteh Askari, H Almasi, N Shabanloo, A Shabanloo,
Volume 9, Issue 1 (6-2016)
Abstract
Background and Objectives: Phenol is a toxic and persistent substance in the environment. The aim of this study was to evaluate the performance of silica aerogel synthesized using sodium silicate in the adsorption of phenol from aqueous solutions.
Material and Method: Silica aerogel was prepared by Sol-Gel process. The influence of effective variables such contact time, initial pH of the solution, adsorbent dose, and initial phenol concentration on the adsorption efficiency was investigated. The characterization of prepared silica aerogel and confirmation of phenol adsorption was determined through SEM, XRD analysis and NMR, FTIR spectra respectively. The adsorption data was evaluated via Langmuir and Freundlich isotherms and pseudo-first and pseudo-second-order kinetics.
Results: This research found that the phenol adsorption efficiency increased by increasing pH from 3 to 11, so that after 60 min, the absorption efficiency at the 100 mg/L initial phenol concentration and 0.5 g adsorbent obtained 84 and 96.4 % at pH 3 and 11, respectively. The SEM image and XRD patternof synthesized silica aerogel confirmed the creation of porous and amorphous structure. After the phenol absorption, the NMR and FTIR spectra of silica aerogel, confirmed the creation of new bands because of phenol molecule at the adsorbent structure. The absorption of phenol was compatible with Freundlich isotherm and pseudo-second-order kinetic. The maximum absorption capacity (qm) obtained was 47.39 mg/g.
Conclusion: Silica aerogel as an adsorbent, due to special characteristics in the structure and usage, can be a promising treatment process for adsorption of toxic and persistent substances.
Mahboub Saffari,
Volume 16, Issue 3 (12-2023)
Abstract
Background and Objective: Nowadays, the use of biochar as a new and suitable adsorbent to remove inorganic pollutants from water sources has grown significantly. The present study was conducted to evaluate the effects of biochar physical modifications compared to unmodified biochar on nickel (Ni) removal efficiency in aqueous solutions.
Materials and Methods: After the production of cypress cones biochar (RB), biochar particles (<164 µm) were crushed into very small (<26 µm) dimensions (BMB) using a planetary ball mill and after evaluation their various properties by SLS, BET, FTIR and SEM techniques, their application (RB and BMB) in optimizing the Ni removal from aqueous solutions were evaluated using the response surface methodology (RSM: Box-Behnken design).
Results: Based on the results, the physical modification of biochar (BMB) decreased the particle size by 6.2 times, increased the specific surface area by 4.9 times, increased (containing oxygen) and decreased (aliphatic and OH stretching groups) of specific functional groups and finer surface morphology, compared to RB. The use of BMB in the aqueous solution caused an increase of 9.7% (on average) in the removal of Ni compared to the RB sample. The fitting of the data obtained from Ni removal in the Box-Benken model in both adsorbents shows the appropriate prediction of this model in the optimization of Ni removal from aqueous solutions.
Conclusion: According to the results of this research, the physical modification of biochar, as a simple, cheap, and environmentally friendly method, due to the increase in the efficiency of Ni pollutant removal, can be introduced as a suitable method in the activation of biochar, which further research is required based on the type of biochar and various pollutants.
