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Showing 2 results for Cerium Dioxide

Nahid Rashtchi, Soheil Sobhanardakani, Mehrdad Cheraghi, Amirreza Goodarzi, Bahareh Lorestani,
Volume 15, Issue 2 (8-2022)
Abstract

Background and Objective: Amoxicillin (AMX) is one of the commonly used commercial antibiotics due to its high resistance to bacteria and its large spectrum against a wide variety of microorganisms, which it´s existence in the wastewater from pharmaceutical industries and hospital effluents causes unpleasant odor, skin disorder, and microbial resistance among pathogen organisms, and it can lead to the death of microorganisms which are effective in wastewater treatment. Therefore, this study was conducted to investigate of removal efficacy of AMX from aqueous solutions using GO@Fe3O4@CeO2.
Materials and Methods: In this descriptive study, GO@Fe3O4@CeO2 was synthesized and then used as a photocatalyst for the removal of AMX from aqueous solution. GO@Fe3O4@CeO2 was characterized using X-Ray Diffraction (XRD), Scanning Electronic Microscopy (SEM), SEM-EDX elemental analysis, Fourier transform infrared spectroscopy (FTIR), and vibrating sample magnetometry (VSM) methods. Additionally, the influence of variables including pH (3-11), amount of photocatalyst (0.006-0.04 g), contact time (0-150 min), and temperature (25-55 °C) was assessed on the efficacy of AMX removal. 
Results: The results indicated that removal efficiency increased up to 90 min contact time, 0.02 g of photocatalyst, and at the temperature of 25 °C. The optimum pH for AMX removal was 10.
Conclusion: GO@Fe3O4@CeO2 could be an effective and available photocatalyst for the removal of AMX from industrial wastewater under UV light.

Seyed Khabat Naynava, Bahareh Lorestani, Mehrdad Cheraghi, Soheil Sobhanardakani, Behzad Shahmoradi,
Volume 17, Issue 3 (12-2024)
Abstract

Background and Objective: Fenitrothion is a phosphorus-based pesticide that enters water resources through various sources,including industrial wastewater and agricultural effluent. its non-biodegradability, which results from the formation of strong chemical complexes, advanced oxidation methods are required to remove it from environmental matrices.  This study aimed to evaluate the performance of a magnetic graphene oxide nanocomposite functionalized with cerium dioxide in the removal fenitrothion from aqueous solution.
Materials and Methods: In this applied research, GO@Fe3O4@CeO2 was synthesized and subsequently used as a photocatalyst for the removal of Fenitrothion from aqueous solutions. Characterization of GO@Fe3O4@CeO2 was conducted using X-Ray Diffraction (XRD), Scanning Electronic Microscopy (SEM), SEM-EDX elemental analysis, Fourier transform infrared spectroscopy (FT-IR), and vibrating sample magnetometry (VSM) methods. The effects of various parameters, including pH (2-9), photocatalyst dosage (10-40 mg), and contact time (0-90 min), were assessed to determine their influence on fenitrothion removal efficiency. 
Results: The results demonstrated that the removal efficiency increased up to 60 min contact time, 20 mg of photocatalyst. The optimal pH for fenitrothion removal was found to be 4. Additionally, kinetic analysis of the photocatalytic removal process indicated that it followed a pseudo first-order (PFO) model.
Conclusion: The GO@Fe3O4@CeO2 nanocomposite proved to be an effective and accessible photocatalyst for the removal of fenitrothion from industrial wastewater under UV light.
 


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