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Effect of Rapid Sand Filter on Copper and Zinc Metal Removal in Different Presence of Phosphate Concentration
N Daneshi, H Banejad, R Pirtaj Hamedani, H Farajee,
Volume 3, Issue 3 (10-2010)
Abstract

Backgrounds and Objectives: Due to copper and zinc elements toxicity, a greatly attention to removal of those in order to reduce environmental pollution exist. This experiment was conducted to investigate the study of the effect of gravity single layer rapid sand filter on heavy metals (zinc and copper) removal efficiency in aquatic condition in different phosphate concentration.
Materials and Methods: this study applied a gravity single layer rapid sand filter with silica sand media. Experiments conducted for all of the states of Cooper and Zinc concentration in 25, 75, 125 and 175 ppm at different phosphate concentration present by varied discharge. Each state of Solutions pumped on top of the bed and discharge adjusted. Samples taken fromeffluent then acidified immediately with nitric acid. Metals concentration perused by atomic emission spectrometer with ICP source. Collected data analyzed by SPSS software.
Results: Founds from this study shown that maximum removal efficiency for copper and zinc was 98.89%and 78.60%respectively effect of discharge,metal concentration and phosphate concentration factors in removal efficiency of zinc and cooper, discharge and phosphate concentration bilateral effect on cooper removal efficiency, phosphate concentration andmetal concentration bilateral on zinc removal efficiency, are significant in 1%. In addition, phosphate concentration and discharge bilateral effect, metal concentration and discharge bilateral effect are significant on zinc removal efficiency in 5%. Finally, bilateral effects of discharge and metal concentration also metal concentration and phosphate concentration have not significant effect on cooper removal efficiency.
Conclusion: Gravity single layer of rapid sandy filter with silica sand media in order to cooper removal in low concentration can be used successfully. This method in high concentration of cooper and also different concentration of zinc had not successful result but in this condition, may be use

 

 

of a series of filter with more depth


Removal of Cyanide from Aquatic Solution by Using of  Iron and Copper Powder: Equilibrium and Kinetic Study
M Shirzad Siboni, M.r Samarghandi, M Farrokhi, H Piri Dogahe, M Zarrabi,
Volume 4, Issue 3 (10-2011)
Abstract

Background and Objectives: Industrial wastewater included the cyanide is one of the important sources of environmental pollution which founded in Industrial wastewater which are harmful for human health and environment. Therefore, the purpose of this research that was fundamental designed is investigation of Removal of cyanide from aquatic solution by using of iron and copper powder in experimental scale.
Material and Methods: At first, pilot was designed. Then, acquired pH optimum equal to 2,7 for copper and iron by variation pH= (2,4,6,8,12) and constant other parameters. The effect of initial cyanide concentration (40,60,80 mg/l), initial iron and copper dosage (0.08-1 g/100CC) and contact time (15-12 min) studied at the constant of optimum pH. 
Results: The result showed removal efficiency Increased from 46.6% to 90.56% and 31% to 93.78% for copper and iron by increasing of contact time from 15to 120 minute in constant conditions, respectively. Also result showed Removal efficiency decreased and increased by increasing initial cyanide concentration and initial iron and copper dosage. The results showed equilibrium data were explained acceptably by Langmuir isotherms and kinetic parameters were obtained by application of Langmuir&Hinshelwood equation.
Conclusion: The results showed that removal of cyanide can be quick and effective done by iron and copper in experimental scale.


Performance Comparison of Fenton and Fenton  Modified with Copper in Raw Wastewater Disinfection  for reuse in Agriculture
Ramin Nabizadeh Nodehi, Hassan Aslani, Mahmood Alomohammadi, Reza Nemati, Kazem Naddafi, Maryam Ghany,
Volume 5, Issue 2 (10-2012)
Abstract
MicrosoftInternetExplorer4 Background and Objectives: Irrigation of agricultural crops using wastewater will increase, in some cases, their growth by 40 to 60 percent. However, this has a high risks for human health because of the presence of higher number of pathogenic organisms. The main purpose of this study was to investigate the feasibility use of Fenton and modified Fenton with copper for the disinfection of raw wastewater.
Materials and Methods: After primarily laboratory physicochemical and biological analysis, the disinfection process was performed in three different phases in each process. First, the disinfectants were injected separately, then we performed disinfection using Fe++ and cu++ ions combined with hydrogen peroxide in order to determine synergistic effect of each catalyst. Direct method was used for fecal coliforms counting. 
Results: Hydrogen peroxide maximum efficiency for inactivation of fecal coliforms was only 0.66log inactivation. Fenton and modified Fenton with copper ions showed a remarkable effect on the bacterial inactivation so that Fenton and modified Fenton with 1 and 2 mg/l of Cu++ inactivated coliforms by 4.73, 3.28, and 4.88 log respectively.
Conclusion: Application of HP alone for the disinfection of raw wastewater is not practicable due to low observed efficiency. However, its combination with ions such as Fe++ and Cu++ increases HP performance in disinfection and has a notable synergistic effect on HP  disinfection power, where, in the presence of each catalyst, hydrogen peroxide can reduce the fecal coliforms of raw wastewater to meet the Iranian Environmental Protection Agency Standards.


Efficiency of the electrokinetic process in copper recovery from the waste of the mine
Mohammad Javad Zoqi, Mohammad Amin Rasooli, Behnoosh Khataei, Mohammad Reza Doosti,
Volume 16, Issue 2 (9-2023)
Abstract
Background and Objective: Mining is one of the important economic activities all over the world. It causes the release of various emissions, especially heavy metals in the soil, due to the weak exploitation and improper disposal of mineral wastes. Different techniques are used for soil remediation and heavy metal extraction; including the electrokinetic method (so effective in fine-grained soils). In this research, the electrokinetic process was used to extract copper from the waste of the mine in Birjand.
Materials and Methods: In this research, a 24 cm long PVC reactor was used. The retention time was 2, 4, and 6 days and the voltage gradient was 1 V/cm. Graphite electrodes and electrolyte solutions of nitric acid and citric acid were investigated for copper extraction. The electrode polarity was alternately changed in order to pH control and improve the extraction process.
Results: According to the results, the highest removal efficiency (54%) was obtained after 6 days using 0.1 M citric acid and distilled water in the anode and cathode reservoir, respectively. Further, by 24-hour polarity reversing, the copper removal efficiency increased to about 60%.
Conclusion: The use of citric acid in anode was more effective than nitric acid, leading to more copper removal. In addition, by periodically polarity change and keeping the soil pH in the neutral range, further dissolution of the metal and reducing its sedimentation in the soil occurred. As a result, the rate of its transfer outside the treatment area and removal efficiency increased.
 

Assessment of the potential environmental effects of newly deposited mine tailings from the Sungun Copper mine
Safieh Hassanzad, Hossein Pirkharrati, Masoumeh Ahangari, Farrokh Asadzadeh,
Volume 17, Issue 1 (6-2024)
Abstract
Background and Objective: One of the significant challenges in mining areas is the pollution of the environment by heavy metals. Therefore, it is crucial to assess the pollution risk associated with mining wastes and take action to mitigate their environmental impact. The current study assessed the risk potential of recently deposited tailings in the Songun copper mining area.
Materials and Methods: Based on the conditions of tailings, 26 samples were randomly selected from the recently deposited mine wastes. Twenty-two thin and thin polished sections were prepared for lithology and mineralogy studies. Inductively-Coupled Plasma Mass Spectrometry (ICP-MS) was employed to analyze all 26 samples, while X-ray diffraction method (XRD) was used to analyze a subset of 10 samples.
Results: Sulfide minerals, as the main source of environmental pollution, remain intact and unaffected in the tailings. However, the majority of potentially toxic elements (PTEs) exhibit higher concentrations in the waste composition than the standard levels, resulting in a total ecological risk index of 49.93. Geochemical indicators highlight significant pollution levels for elements such as lead (Pb), arsenic (As), and copper (Cu). The values of the non-carcinogenic risk index for children (except As and Fe) and adults are lower than 1, indicating a non-significant non-carcinogenic health risk. However, the carcinogenicity index also indicates a significant carcinogenic risk in the case of long exposure to wastes, particularly for children.
Conclusion: Therefore, wastes pose a significant environmental risk potential, and due to this risk, proper management of their storage is necessary to prevent the release of PTEs into the environment.

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