Iranian Journal of

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Background and Objectives: Industrial wastewater included the dyes one of the important sources of environmental pollution, that founded in loom wastewater which are harmful for human health and environment. Therefore, the purpose of this research was investigated removal of RB5 dye from aquatic solution by using of adsorption onto synthesized magnetic sodium alginate beads.
Material and Methods: At first, synthesized magnetic sodium alginate beads. Then, acquired beads optimum dosage equal to 18 g/100CC, with constant other parameters. The effect of pH, contact time and initial RB5 dye concentration was studied at the constant of beads (18 g/100CC).
Results: Results showed that removal efficiency was decreased by increasing of initial RB5 dye concentration. Also the results showed the removal efficiency was increased by increasing of adsorbent dose and contact time. The results showed data were explained acceptably by Langmuir isotherms and pseudo-second-order kinetics models respectively.
Conclusion: The results showed that removal of RB5 dye from aqueous solution by using of magnetic sodium alginate beads can be done cheaper and effective.

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MicrosoftInternetExplorer4 Background and Objectives: Phenols in trace quantities are usually present in the treated effluent of many wastewater-treatment plants. Phenol compounds even at low concentration can cause toxicity, health and significant taste and odor problem in drinking waters. This research focuses on understanding the sorption process and developing a cost-effective technology for the treatment of water contaminated with phenolic compounds, which are discharged into the aquatic environment from a variety of sources. In order to remove phenolic compounds from water, a new natural sorbent, rice husk ash, was developed.
Materials and Methods: Removal of phenol, 2-chlorophenol and 4-chlorophenol were characterized by spectrophotometric technique at wavelengths of 269.5, 274 and 280 nm, respectively, under batch equilibrium conditions and via changing the parameters of contact time, initial pH, and initial concentration of adsorbates and dosages of sorbent. Finally, the results were analyzed by the kinetic and isotherm models.
Results: in this study, the equilibrium time was found to be 240 min for full equilibration of adsorbates. Removal percent of 2-chlorophenol was lower than two others. The maximum removal of phenol, 2-CP and 4-CP was observed at an initial pH of 5. The percentage removal of these phenolic compounds increased with increasing adsorbent dose and decreasing initial concentration. In kinetics studies, correlation coefficient and ARE factor showed that the sorption of phenol (R2=0.9999), 2-chlorophenol (R₂=0.9992) and 4-chlorophenol (R₂=1) fitted by pseudo second order model. Isotherm studies also revealed that, Langmuirmodel for phenol (R₂=0.9499), Freundlich model for 2-chlorophenol (R₂=0.9659) and 4-chlorophenol (R₂=0.9542) were the best choices to describe the sorption behaviors.
Conclusion: Sorption process is highly dependent on the pH and it affects adsorbent surface characteristics, the degree of ionization and removal efficiency. At high pH hydroxide ions (OH-) compete for adsorption sites with phenol molecules. The sorption was done rapidly and a plateau  was reached indicating the sorption sites occuupied till  they were saturated. Since the increasing sorbent dose would improve sorption site, its increasing enhances phenolic compounds removal.

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Background and Objectives: Dyes are one of the main environmental pollutants in the industrial effluents including textile industries, which are harmful for human health and environment. The purpose of this research was to investigate removal efficiency of Reactive Black 5 (RB5) dye using adsorption onto strongly basic anion exchange resin as an appropriate adsorbent. Materials and Methods: After preparing materials and equipment required, removal efficiency of Reactive Black 5 (RB5) dye using adsorption onto strongly basic anion exchange resin was investigated with respect to the variation of pH, contact time, adsorbent dosage, and initial RB5 dye concentration in batch system. Then results were analyzed using Excel software. Results: Our results showed that removal efficiency was decreased by increasing pH and initial RB5 dye concentration. Moreover, we found that the removal efficiency was increased by increasing adsorbent dosage and contact time. The kinetics and equilibriums data were explained acceptably by Langmuir isotherms and pseudo-second-order kinetics models respectively. Conclusion: Overall, our findings revealed that removal of RB5 dye from aqueous solution using adsorption onto strongly basic anion exchange resin can be considered as an effective and quick method.

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Background and Objective: 2,4 dinitrophenol is observed in sewage produced from chemical and petrochemical industries. Contamination of drinking water with these pollutants causes toxicity, health problems and change in taste and odor. The present study was developed to evaluate the efficiency of removal 2,4-DNP through dried sludge adsorbent and modified calcium chloride sludge adsorbent.