Showing 13 results for Pesticide
M Khodadadi, M.t Samadi, A.r Rahmani, R Maleki, A Allahresani, R Shahidi,
Volume 2, Issue 4 (3-2010)
Abstract
Backgrounds and Objectives: Water contamination by pesticides is considered as an environmentalproblem today. In terms of agricultural development and diversity of plant pests, the use of pesticides has been increasing. Hamedan province has a suitable agricultural condition, it has enjoyed significant development in this respect. Among all the cities of Hamedan province, Hamedan city has the highest rank in tiller crops. Therefore, yearly use of pesticides is increasing in this area which could be a serious threat to water resources of the city. The aim of this survey was determinaton of Organophosphorous and Carbamat pesticides residue in drinking water resources of Hamadan in 2007.
Materials and Methods: In this survey, 126 water samples were collected from 7 drinking water resources of Hamedan during 12 consecutive months in 2007. for determination of these pesticides,two methods (solid- phase extraction and Liquid-Liquid extraction) were adopted .and samples were analyzed by means of HPLC and GC/MS applying standard methods.
Results: Final results showed that the most concentration of Chlorpyrifos and Carbaryl pesticides were found to be about 3.85 ppb (part per billion) and 1.8 ppb in spring and June respectively the maximum concentration of Diazinon was about 36.5ppb in October (autumn).The minimum concentration of the three pesticides was detected in winter. According to the statistical test Two - Way ANOWA there were significant differences among pesticides concentrations in the water samples in different seasons (p<0.05) . However, there wasn't a significant difference in pesticides concentrations in surface and ground water samples(p>0.05).
Conclusion: Different studies have shown that pesticides residue concentration in water samples have a relationship with the amount of pesticides used in an area, physical and chemical refractory properties of pesticides and environmental conditions. Thus, using resistant pollutants such as pesticides will be a serious threat to health of water consumers if they are not properly controlled.
M Khodadadi, M.t Samadi, A.r Rahmani,
Volume 4, Issue 3 (10-2011)
Abstract
Background and Objectives: Water pollution by pesticides has adverse effects on the environment and human health, as well .In recent years, advanced oxidation processes, have been gone through to a very high degree for pesticides removal. Poly-Aluminum chloride (PAC) used for water treatment, can be effective on pesticides removal. The aim of this research was to study the use of UV/O3 and PAC in the removal of pesticides from drinking water.
Materials and Methods: In this descriptive- analytical survey, specific concentrations of pesticides (1,5,10,15,20 ppm)namely Diazinon, Chlorpyrifos, Carbaril were prepared through addition to deionized water. Dichloromethane was used for samples&apos extraction, samples extracted with Liquid- Liquid & Solid-phase extraction , finally entered bath reactor at pH (6,7,9) .The samples then exposed to UV/O3at contact time of (0.5,1,1.5 and 2 hours) . In the PAC pilot , the effects of various concentrations of pesticides, and PAC - ranging (12/24 and 36 ppm) were investigated for the efficacy of pesticides removal. All samples analyzed by GC/MS/MS and HPLC.
Results: It was found that in UV/O3 reactor, with the rise of pH, decrease in pesticides concentration, and rise of contact time, the efficiency of removal increased too. In the PAC pilot, increase in PAC concentration and decrease in pesticides concentration , both increased the efficiency. Besides, both of the methods showed high efficiencies in the removal of both pesticides,i-e. halogenated Organophosphorus (Chlorpyrifos) , non- halogenated Organophosphorus (Diazinon) at the degree of over (%80 ) In case of carbamate pesticides (e.g. Carbaril) efficiency was over (>%90). One-Way Anova & Two -Way Anova were used to analyze the obtained data.
Conclusion: According these results these two methods are suggested for the removal of pesticides from aqueous solutions.
Ar Khajeamiri, M Zare Jeddi, R Ahmadkhaniha, N Rastkari,
Volume 9, Issue 3 (12-2016)
Abstract
Background and Objective: Organochlorine pesticides are among the endocrine disrupting chemicals believed to produce a wide variety of adverse health outcomes such as cancers. Generally, fatty foods of animal origin are the major sources of human exposure to lipophilic contaminants such as DDTs and their metabolites. The objectives of the present study were to evaluate exposure of general population to DDTs via dietary milk consumption in Iran, and to assess the respective potential risks to health of people in terms of carcinogenic and none-carcinogenic effects.
Materials and Methods: The DDT residue levels were determined by GC/MS analysis in 60 milk samples of full fat pasteurized commercial types (3% fat). The assessment of carcinogenic and non-carcinogenic risks was calculated through international standard methods.
Results: In all of the milk samples, DDT and its metabolites were detected in the range of 0.0015 to 0.28 µg/L with the mean of 0.05±0.03, 0.15±0.08, 0.09±0.05, 0.05±0.02 µg/L for o, p-DDE, p,p-DDE, p,p-DDT, p,p-DDD, respectively. The calculated estimated daily intake (0.00006-0.0002 mg/kg/day) for all categories and all compounds were lower than the Reference doses (RfDs). Consequently, the hazard quotients calculated in these groups for DDTs were less than 1. Hazard index obtained for all compounds in full fat pasteurized milk based on maximum DDT residue concentrations was higher than unity confirming health risk. From the carcinogenic point of view, there is no risk and it was within the acceptable threshold of EPA.
Conclusion: The results of the present study showed that the general population are exposing to DDT and its metabolites constantly. Therefore, it is recommended to biomonitoring and measuring these chemicals in all age groups especially in children.
Ghh Abdollahzadeh, M Sharif Sharifzadeh, Z Qadami Amraei,
Volume 9, Issue 4 (3-2017)
Abstract
Background and Objective: Chemical pesticides are considered a vital component of farming and play a substantial role in maintaining high agricultural productivity. Concerns regarding the health and environmental effects of the pesticides have been increased in recent years. Therefore, this research aimed to assess farmers’ awareness about the positive and negative impacts of pesticides and their health risk on human.
Materials and Methods: A survey study was carried out between two groups of farmers including chemical pesticide users (n= 126) and biological pesticide users (n = 98). The users were randomly selected from 20 villages. The studied villages were selected from two sub-districts by cluster sampling method. An expert-verified questionnaire that its design and contents were assessed by local professionals was used in this research. The reliability of the questionnaire was confirmed based on the calculated Cronbach Alpha Coefficient for two constructs of awareness: positive (0.75) and negative (0.83) impacts of pesticides.
Results: Results indicated that the farmers using biological control were well aware of the harmful impacts of pesticide and hence they used less pesticides than the chemical pesticide users. Although the two groups of the farmers highlighted the health impacts of chemical pesticides such as human and animal health threat, and pollution of surface and underground water, the users of biological control methods had more concerns in this regards. Most of the respondents stated that the pesticides caused serious health problems such as exhaustion, sweating, cough and headache, dizziness, skin inflammation and irritation, nausea and vomiting.
Conclusion: Even though the farmers were well aware of the impacts of pesticides use, they have less often used personal protective equipment. In order to promote farmers’ awareness of pesticide impacts, more efforts are needed to strengthen training programs and facilitate access to extension services.
P Baratpour, G Moussavi, A Alahabadi, E Fathi, S Shekoohiyan,
Volume 10, Issue 2 (9-2017)
Abstract
Background and Objective: With industrial development and population growth, the emerging contaminants enter into the natural water resources. Therefore, adsorption potential of Ammonium Chloride-induced activated carbon (NAC) to remove metolachlor pesticide from contaminated water was investigated in this study.
Materials and Methods: The effects of operational conditions including solution pH, NAC concentration, metolachlor initial concentration and contact time on the removal of metolachlor by Ammonium Chloride-induced activated carbon (NAC) and standard activated carbon (SAC) were studied.
Results: Over 92.4% of 50 mg/L metolachlor was adsorbed using 0.3 g NAC/L within 5 min, and by increasing the reaction time to 60 min the removal efficiency reached to 100%. Under similar experimental conditions, standard activated carbon (SAC) could only adsorb 20% of metolachlor within 5 min and increase of contact time to 40 min caused the improvement of metolachlor adsorption onto SAC to 48%. The adsorption onto SAC was not influenced by the contact time over 40 min. Kinetic analysis showed that experimental adsorption data for both NAC and SAC were best fitted to the pseudo-second-order model. The maximum adsorption capacities of metolachlor onto NAC and SAC calculated by the Langmuir model were 344.8 and 238.1 mg/g, respectively.
Conclusion: Generally, these results showed that developed NAC was an efficient adsorbent with high removal efficiency for eliminating the halogenated pesticides from the contaminated water streams.
N Naqshband, M Askari Hesni,
Volume 10, Issue 2 (9-2017)
Abstract
Background and Objective: Glyphosate is a non-selective, systemic herbicide that can control most plants, but it has harmful effects on organisms, especially aquatic animals. Static bioassays were made to determine acute toxicity of glyphosate and its effects on haematological parameters and behavior changes of common carp (Cyprinus carpio).
Materials and Methods: Common carp were exposed to different concentrations of glyphosate (5, 10, 20, 30 and 40 mg/L) and a control group for 96 h. After that, blood and plasma factors were measured in blood samples. Mortality rate and fish behavioral were recorded during the experiments. LC50, LOEC, NOEC and MATC were calculated by Probit software according to mortality rate in any treatment.
Results: In the early period of the experiment, fish in toxic media were jumping in water and showed high movements. Then after, the behavior such as breathing in surface, loss of balance, weakness and finally death were observed in the different treatments. LC50 value and 95% confidence limit of glyphosate in 24, 48, 72 and 96 h were 36.09, 30.46, 21.78 and 20.05 mg/L for common carp, respectively. The LOEC, NOEC and MATC were calculated as 6.66, 4.73 and 2.005 mg/L. The Significant changes that were observed in blood factors included RBC, WBC, Hct, Hb and plasma factors such as total protein, glucose, cortisol and other factors when the pesticide concentration was increased (p<0.05).
Conclusion: Results showed that glyphosate had a high effect on common carp and it its physiology and immune system. Haematological parameters may be used as an environmental health diagnostic test and stress indicator for agriculture pesticides in aquatic ecosystems.
A Bondori, A Bagheri, M Sookhtanlou, O Jamshidi, A Norozi,
Volume 12, Issue 4 (2-2020)
Abstract
Background and Objective: Farmers in agricultural activities deal with various forms of chemical pesticides and thus their knowledge level can have a positive or negative impact on the food health of a community and the environment. Understanding their knowledge about the consequences of poisoning will provide an effective extension for promoting environmentally friendly methods in farms and maintaining food security. Hence, the aim of this study was to assess the farmers' knowledge of Moghan plain about the consequences of chemical pesticides use for community health, the environment and food security in 2017.
Materials and Methods: The method of this study is descriptive and survey. The statistical population consisted of all farmers (water cultivation) in the Moghan plain. The sample size of 400 was determined by multi-stage sampling method and using Kerjesi and Morgan table (1970). The study tool was a questionnaire whose validity was confirmed by a panel of experts and its reliability was confirmed by Cronbach's alpha coefficient.
Results: The findings showed that the majority of the farmers had relatively poor knowledge about the consequences of using chemical pesticides. The results of structural equation modeling (using Lisrel software) showed that the use of information resources, in total, predicted 24% of variance of farmers' knowledge about the consequences of chemical pesticides.
Conclusion: Given that more favorable safety behavior and cultivation of more healthy crops are based on the farmers' knowledge about the use and consequences of chemical pesticides, hence, the attention of authorities and planners for conducting various workshops in line with farmers' perceptions about the use of knowledge and the consequences chemical pesticides are needed.
Asghar Bagheri, Naier Emami,
Volume 13, Issue 3 (11-2020)
Abstract
Background and Objective: Pesticides are the major components of production in modern agriculture, however, as their widely usage, the hazards associated with their wastes have become of increasing concern. The aim of this study is to investigate orchard farmers’ attitudes toward proper disposal of pesticide wastes.
Materials and Methods: The statistical population of the study includes all orchard farmers in Meshkinshahr County (N=32,300). A total sample size of 300 farmers was selected and the data were collected. The research instrument was a questionnaire which was validated by a panel of university staff. A pilot study was conducted with 30 farmers outside the sample villages and Cronbach's alpha showed high reliability of the instrument.
Results: Due to the pesticides use, significant amounts of wastes are produced annually. Farmers do not properly dispose pesticide wastes. They leave the wastes on the farm, dump it in canals or river flow, or burn it. Farmers were not well informed about triple rinsing of containers before disposal. Most farmers used masks, hats, and gloves, 53% used boots and 7.7% used goggles, though none of them used coverall during pesticides’ handling. Respondents took negative to moderate attitudes towards proper wastes disposal. Age, education, and participation in extension programs were the most important determinants of the attitudes.
Conclusion: Considering the relatively negative attitude and improper waste disposal, it is necessary to establish centers for waste collection, to inform and encourage farmers to dispose of waste properly. Relevant organizations, such as health and the environment should plan for pesticide waste management.
Mogheiseh Sherafati, Gholamhossein Abdollahzadeh, Mohammad Sharif Sharifzadeh, Mohammad Reza Mahboobi,
Volume 13, Issue 3 (11-2020)
Abstract
Background and Objective: pesticides are essential to protect plants from pests and diseases. Extensive and unsafe use of pesticides by farmers pose various risks to human health and the environment. Therefore, the present study evaluates farmers' knowledge, attitudes, and behaviors regarding pesticides use and the health problems associated with their use.
Materials and Methods: In this human-research survey the target population consisted of 6170 farmers and fruit growers in Galogah County, Mazandaran province, were included. Multi-stage cluster sampling was used to select samples within 2 sub-districts and 13 villages, and the information was collected through 379 questionnaires. Statistical tests such as Mann-Whitney U, Kruskal-Wallis H, Spearman Correlation and Linear Regression were used to analyze the obtained data.
Results: The respondents have no sufficient knowledge regarding the safe use of pesticides. Respondents' attitudes toward the impacts of pesticide use were positive. The safety measures were less considered by majority of respondents. Moreover, the results revealed that personal protective equipment (mask, gloves and, goggles) and safe disposal of pesticide residues are not fully taken into consideration. The dizziness, skin problems, headache and vomiting were the most common symptoms of pesticide-related illnesses. The findings of regression analysis showed that wide range of knowledge and proper attitudes about the safe use of pesticides are beneficial and can act as the promoting factor in farmers' safety behavior regarding pesticides use.
Conclusion: In conclusion, providing pesticide users with sufficient knowledge, safety information and effective personal equipment such as wearing masks, goggles and gloves should be given highest priorities.
Naiema Vakili Saatloo, Tooraj Mehdizadeh, Javad Aliakbarlu, Rahele Tahmasebi,
Volume 14, Issue 2 (9-2021)
Abstract
Background and Objective: Milk is one of the most important components of human food. In recent decades, the continued use of pesticides has led to contamination of soil, water, air and milk and caused public concern in the community. Long-term exposure to pesticide residuals in the food chain can be harmful. Therefore, there is a need to control environmental conditions in order to improve its healthy and sustainable food processing practices.
Materials and Methods: In this study, 30 samples of raw milk were randomly collected in October 2020, from milk collection centers in Urmia and the residual pesticides were determined using gas chromatography–mass spectrometry (GC-MS).
Results: Organochlorine pesticides were detected in some raw milk samples. The highest concentrations of Lindane (γ-HCH) were detected with the values ranging from 0.3 to 0.6 mg/kg in 5 milk samples. Atrazine was detected in 15 samples with the values ranging from 0.8 to 1.33 mg/kg and alachlor was found in 13 samples with the varied range of 0.35 to o.5 mg/kg. Organochlorine pesticide concentrations were higher than maximum residue level (MRL) in all contaminated milk samples according to the values mentioned by the European Union.
Conclusion: This study showed that atrazine, lindane and alachlor were higher than MRL according to European Commission (EC). However, other organochlorine pesticides such as Heptachlor, Aldrin and hexachlorocyclohexane (HCH) isomers (α, β and γ) were not detected.
Alireza Rahimi, Nabi Shariatifar, Ali Heshmati,
Volume 14, Issue 3 (12-2021)
Abstract
Background and Objective: The Pesticides used in agriculture have caused great concern due to their adverse effects on human health. In this study, the effect of rinsing, crushing, filtering, clarifying with bentonite and pasteurization on the reduction of diazinon, ethion and phosalone during Asari grape juice was investigated.
Materials and Methods: Vineyard was sprayed during three growth stages before flowering, sour grape (ghooreh) and during grape ripening with phosalone, diazinon, ethion and in doses of 525, 600, 750 g of active substance per hectare, respectively. Twenty-four hours after the last spraying step, the grape sample was harvested and exposed to the process of rinsing (20-30 s), crushing, filtering, clarifying and pasteurizing. Then, the pesticides residue concentration was determined after each step by GC-MS/MS.
Results: The initial concentrations of diazinon, ethion and phosalone in unprocessed grape samples were 0.640, 0.716 and 0.550 mg/kg, respectively. The reduction values of diazinon during the juicing processes of rinsing, crushing, filtering, clarifying with bentonite and pasteurization, in comparison with the concentration of unprocessed grapes, were 25.72, 41.96, 74.54, 90.21 and 100% (not found), respectively; while these values were 9.78, 28.50, 69.45, 89.38 and 96.74% for ethion and 17.32, 28.47, 46.40, 80.25, 93.28% for phosalone, respectively. All processes significantly reduced insecticides residue.
Conclusion: Findings showed that the processes of grape juice production could significantly decrease the diazinon, ethion and phosalone residues.
Fateme Rezaee, Meisam Rastegari Mehr, Ata Shakeri,
Volume 16, Issue 3 (12-2023)
Abstract
Background and Objective: Water resources deficiency has caused the use of effluents to be considered as a source for re-use in the form of haloculture projects. An attempt has been made to investigate the possibility of using effluent produced by sugarcane production companies in the implementation of haloculture projects, from the viewpoint of the most used pesticides.
Materials and Methods: Ten water, four sediment, two plant, and two fish samples were analyzed using gas chromatography-mass spectrometry (GC-MS) and high-performance liquid chromatography (HPLC) to determine the concentration of pesticides. In order to assess the ecological risk, toxic unit (TU) and risk quotient (RQ) were calculated.
Results: Glyphosate and Ametryn in all liquid, solid, and biological samples had concentrations below the detection limit. 2.4.D, Metribuzin, and Atrazine had detectable concentrations in the samples. However, their concentrations are lower than the standard values. Metribuzin and Atrazine had high concentrations in the stems and leaves of reeds in the region, which may indicate the role of these plants in the remediation of water and sediment from these compounds.
Conclusion: Using effluent from Amirkabir and Mirzakouchak Khan agro-industrial complexes to implement the haloculture project does not pose a particular problem from the viewpoint of contamination with the studied pesticides. This is confirmed due to the small concentrations of the studied compounds in the liver and below the detection limit in the muscles. However, it is necessary to carry out more studies to evaluate the quality of effluent in terms of the other types of pollution.
Mohammad Mosaferi, Jafar Yahyazadeh, Yusef Mohammadian, Farzaneh Moshtaghi,
Volume 17, Issue 2 (9-2024)
Abstract
Background and Objective: The use of pesticides poses serious risks to the health of living organisms. Knowing the type and amount of pesticide use can provide a good information base for managing potential risks from pesticide consumption. This study was carried out with the main objective of determining the types and amounts of pesticides used on agricultural land in East Azarbaijan Province in 2021.
Materials and Methods: Information about the pesticides have been gathered and analyzed by referring to the Agricultural Jihad Organization and other relevant authorities. Calculations related to the amount of pesticides used per unit area were made using the total area of agricultural lands in the province.
Results: Considering the frequency, 403 kinds of pesticides are used in the following order: Herbicides > Insecticides > Fungicides > Acaricides > Others > Disinfectants. Consdidering total consumption of 2873730 kg pesticides, the order based on the amount is: Insecticides > Herbicide > Fungicides > Miscellaneous > Acaricides and Disinfectants based on the amount. The total ratio of pesticides used to pesticides distributed through the official (government) channel is 2.51. The minimum, maximum, and mean consumption values in counties are 0.4, 21.4, and 4.21 ± 5.33 kg/ha, respectively, and for province is 2.38 kg/ha. There is a correlation between the amount of pesticide applied and the number of farmers and traders.
Conclusion: The consumption of pesticides in the province is higher than the world average. Appropriate management of pesticides is required from the viewpoints of environment and health protection.
