Iranian Journal of

Background and Objectives: Phenol is one of priority pollutants produced through leather, paint, resin, and pharmaceutical industries and it can contaminate groundwater after entering to the environment. Hence, it is necessary to use a suitable method for its removal. The aim of this study was synthesize and efficiency evaluation of magnetic nanocomposite of activated carbon powder-zero valent iron/silver (PAC-Fe^o/Ag) in the removal of phenol from aqueous solution. Material & Methods: Reduction method was used for converting bivalent iron to zero valent iron and co-precipitation method for depositing of iron on activated carbon. For coating silver on nano zero valent iron, rapid mixing at high temperature was used. The adsorbent was characterized using SEM, TEM, and XRD techniques. Then, the impact of pH, contact time, agitation speed, temperature, adsorbent, and initial phenol concentration were evaluated and optimized by one factor at the time method. Reaction kinetics and isotherms were also determined. Results: It was found that PAC-Fe^o/Ag has cubic and intertwined structure and has a diameter in the range from 40 to 100 nm. The optimum conditions for phenol removal by PAC-Fe^o/Ag were as pH=3, 90 min contact time, 200 rpm agitating speed and adsorbent concentration equal to 1 g/l. Isotherm and kinetic equations showed that the experimental data of phenol adsorption onto PAC-Fe^o/Ag are correlated to the Langmuir (R²>0.969) and pseudo-second order (R²<0.965) models, respectively. Conclusion: Under optimum conditions, modified adsorbent by zero valent iron and silver with maximum efficiency of 97% has quickly and effectively ability in removal of phenol and it can be easily separated from the solution sample by magnet because of its magnetic properties.

Background and Objective: Collection and disposal of waste has an important role in public health. Isolation and separation procedures at the origin is considered as one of the most important and least costly methods of isolation and separation of waste. This study was aimed to culture and educate those involved in recycling and waste reduction in the Kalaeh City using two educational methods. .

Materials and Methods:  This semi-experimental study was conducted in Kalaleh City. In the social and cultural context,   Kalaleh was divided into six regions. Using cluster sampling, regions were selected randomly. In each area, 120 samples were used. The first group was face-to-face trained and the second group received training through the training package. Waste collection period was 60 days. After this time, the questionnaires were again filled up  and the impact of teaching methods were investigated.

Results: Face-to-face training resulted in increasing waste separation from 70.8 (before training) to 95%. Whereas, this figure in the group receiving training package increased from 57.5 (before training) to 86.7%. Waste recycling rate was between 0.6 to 1 Kg per person per week. These wastes included paper, glass, plastic, and metal containers. On average, the waste recycled in face-to-face training group and training package group was  91 and 83 Kg per week.

Conclusion: Knowledge, attitude and cooperation in waste separation increased after training in both groups. However, in the face-to-face training group, the knowledge and participation in waste separation was more compared with training package group. Continuous training and organizing waste separators could be helpful to re-use waste. It causes less pollution of the environment, reduce the transmission of diseases associated with non-systematic disposal of solid waste, reduce costs and increase awareness about the problems and issues of solid waste, and reduce the solid waste volume.