Showing 8 results for Uv
Ar Mesdaghinia, F Vaezi, E Dehghanifard, Ah Mahvi, M Alimohammadi,
Volume 1, Issue 1 (10-2008)
Abstract
Background and Objectives: Measurement of light intensity is a recommended practice for insuring the delivery of required germicidal dose in disinfection operations by UV lamps. Use of sensitive to light chemicals which is the base of actionometeric methods could be considered as a suitable manner for estimating the intensity of UV lamp in circumstances that special radiometers are not available.
Materials and Methods: lodide-iodate mixture was used as an actinometer for this study. The light intensities of a UV lamp (LP 25W) were first determined by a special UVC radiometer at certain distances from the lamp. Then the test of determining the suitable period of time for irradiation of actinometer was accomplished. Finally، the color changes of iodide - iodate solutions at the predetermined distances were evaluated at the wavelength of 352 nm. The latter analysis can be done by a common (visible) spectrophotometer.
Results: Results indicated that use of this actinometer is more suitable at the distances of 35 to 60 cm from the center of the lamp bulb، since iodode-iodate solution has a detectable color change at this range of distance in one minute irradiation which may be considered as a reasonable time for actionmeteric operations.
Conclusion: Although all kinds of actinometers should not be regarded as precise as special radiometers and there would be need to use pure chemicals for actinometeric determination of light intensity، it can be claimed that the recommended procedure in this study which is the newest actinometeric method can be used in acceptable evaluation of UV intensity with least difficulty in providing necessary instruments.
H Masombaigi, A Rezaee, A Nasiri,
Volume 2, Issue 3 (11-2009)
Abstract
Backgrounds and Objectives: Textile industrial wastewaters are one of the important sources of environmental contaminants. In the recent years, use of advanced oxidation processes, by producing highly active and reactive components such as hydroxyl radicals has been proposed. The aim of this research is photocatalytic degradation of methylene blue dye using the ZnO-nanoparticle with UVA irradiation.
Materials and Methods: photocatalytic degradation of methylene blue color using the ZnO- nanoparticles excited with UVA irradiation. In this research, photocatalytic degradation of methylene blue dye was study using different concentration of ZnO-nanoparticles under UVA irradiation in a batch reactor.
Results: The results of this research show that removal of methylene blue dye has direct correlation with UVA intensity. The best results of dye degradation were reported in concentration of 150 mg/L ZnO nano-particles and the radiation intensity of 240 µW/cm2. Rate of dye removal was decrease with increasing of color concentration. Subsequent of color degradation, the initial COD were decresed by %60.
Conclusion: The photocatalytic degradation process using ZnO nano-particles under UVA irradiation could be remove the methylene blue dye and 60% of COD.
H. Hashemi, M.m. Amin, B. Bina, H. Movahedian Attar, H. Farrokhzadeh,
Volume 3, Issue 1 (4-2010)
Abstract
Backgrounds and Objectives:Today, due to health, environmental and economical problems, of chlorine application, UV radiation is better option than chlorine for disinfection of effluent. The aim of this study was disinfection of secondary effluent with UV radiation.
Materials and Methods: Two types of UV disinfection system including low pressure (LP) and medium pressure (MP) was used to disinfection of Isfahan North Wastewater Treatment Plant (INWWTP) effluent without pretreatment. Single and combined lamps were operated to evaluate the removal of total and fecal coliforms (TC and FC), and fecal streptococcus (FS). TSS, iron, hardness, UV absorption and transmittance were analyzed in order to observe the fouling of the quartz sleeves.
Results: After using LP lamp with dose of 161 mws/cm2, TC and FC content was declined to standard level (1000 TC, and 400 FC/100ml). In addition, disinfection with MP lamp was led to FS content of 400 MPN/100 mL. Combination of LP and MP, with dose of 460 mws/cm2 could be met the environmental requirements of TC & FC, and the FS count was reached to 400 MPN/100 mL with dose of 237 mws/cm2. Maximum photo-reactivation percentage of coliforms after LP and MP lamps were appeared 15 and 3 percent respectively, while it was not observed for FS.
Conclusion: High fluctuation in secondary effluent quality of INWWTP mainly TSS concentration was caused to decline of the UVT value. Therefore, disinfection of effluent by LP, MP and even combined both systems are not applicable in conventional UV dose. Hence, using advanced process unit before UV disinfection system is necessary for removal of TSS.
M.h Dehghani, S Nasseri, M Ghaderpoori, A.h Mahvi, R Nabizadeh Nodehi,
Volume 3, Issue 4 (1-2011)
Abstract
Backgrounds and Objective: Surfactants are one of the largest pollutants which exist in urban and industrial wastewaters. Large quantities of surfactants have entered to the environment since last decade due to increased use of synthetic detergent in industrial and home consumptions.In this study, the efficiency of UV/H2O2 process in removal of linear alkylbenzane sulfonate (LAS) from aqueous solutions was investigated.
Materials and Methods: In this study methylene blue active substane(MBAS)method and spectrometery were used to determine anion and residual surfactant respectively. In this study important variables were H2O2 concentration, initial concentration of surfactant, pH and duration of UV radiation. The effect of UV/H2O2 process on the degradation of LAS was analyzed statistically by using Multiple Linear Regression test.
Results: The resulted showed that after 20 minute, ultraviolet radiation solely removed 38.44 percent of Anionic detergent, Hydrogen peroxide showed no significant removal of detergent solution in the time course study. The efficiency of UV/H2O2 process in 10, 20 and 30 minute were to 86.2, 90 and 96.5 %, respectively.
Conclusion: The results showed that the efficiency of ultraviolet radiation and hydrogen peroxide process in anionic detergent was not significant thoogh it was considerable in combination process (UV/H2O2).
Mohammad Reza Mehrasbi, Sorur Safa, Amir Hossein Mahvi, Ali Assadi, Hamed Mohammadi,
Volume 5, Issue 3 (10-2012)
Abstract
Backgrounds and Objectives: The base structure of total petroleum hydrocarbons (TPH)
is made of hydrogen and carbon. Widespread use, improper disposal and
accidental spills of this compounds lead to long term remaining of
contaminations such as organic solvents and poly aromatic hydrocarbons (PAHs)
in the soil and groundwater resources, resulting in critical environmental
issues. In this study, an oil-contaminated soil was washed using Tween 80
surfactant and the application of photo-Fenton process (UV/Fe2+/H2O2)
for treatment of the produced wastewater was evaluated.
Materials and Methods: Tween 80 is a yellow liquid with high viscosity and soluble in water. In order
to determine of the photo-Fenton process efficiency, we studied effective
variables including Fe concentration, pH, H2O2 concentration, and irradiation time. The UV irradiation source was a
medium-pressure mercury vapor lamp (400 w) vertically immersed in the solution
within 2L volume glass cylindrical reactor.
Results: The results
showed that efficiency of COD removal depends on the initial Fe concentration, pH,
H2O2 concentration and irradiation time.
Under optimum conditions, (Fe: 0.1mM, H2O2:
0.43 mM, pH: 3 and UV light irradiation time: 2 hours) the removal efficiency
of COD was 67.3%. pH plays a crucial role in the photo-Fenton process such that
the removal efficiency increased with decreasing of pH.
Conclusion: According
to the results of this study, under acidic condition, this process is an
efficient method for COD removal from the wastewater studied.
Leila Moradi Pasand, Bita Ayati,
Volume 6, Issue 3 (12-2013)
Abstract
Background and Aim: In this study, the removal of dye blue reactive-171 by combination of advanced oxidation processes UV/H2O2 and SBAR has been investigated. Methods: The efficiency of chemical and biological system was first investigated separately. In chemical system, the kind, power, initial dye concentration and hydrogen parasitize and in biological system, hydraulic detention time, aeration rate, initial dye concentration and the percent removal of dye and COD were investigated. In order to investigate the hybrid system, after determination of the optimum conditions and the capabilities of each system, the removed chemical system effluent from residual hydroxide peroxide, was entered into the biological reactor. Results: In the chemicals process, 100 ppm dye using 150 Watt-UV-C lamp and 0.1 mM hydrogen peroxide at pH= 9 was completely removed in 25 minutes. COD removal was 86.7 percent at the end of the experiment (135 min). Biological system with adsorption mechanism has shown 44 percent dye removal with initial COD of 50 mg/L that indicated the system inability in biodegradation and breaking down of the dye molecule. In comparison to separate chemical and biological processes, hybrid system has shown better dye removal efficiency. The results indicated that in addition to the complete dye removal achievement, 81% of COD in the first hybrid system and 52% of COD in the second hybrid system was removed, respectively. Conclusion: According to the results, because of complexity of dye structure, biological system was not able to remove the dye as efficient as hybrid system of advanced oxidation processes UV/H2O2 with SBAR.
Amir Hossein Mahvi, Noushin Rastkari, Ramin Nabizadeh Nodehi, Shahrokh Nazmara, Simin Nasseri, Mahboobeh Ghoochani,
Volume 6, Issue 3 (12-2013)
Abstract
Background and Objectives:Chlorination is the most common method of water disinfection. Chlorine reaction with natural organic compounds nor removed completely during treatment process would result in forming disinfection byproducts. Followed by trihalomethanes, Haloaceticacides are the second main byproducts of chlorination in water. The research works conducted in Iran have assessed trihalomethanes. Hence, this is the first time we are reporting haloacetic acids in Iran.
Materials and Methodology: We collected samples from surface water resources and treated water in Tehran for six consecutive months (first half, 2010). We measured temperature, pH, UV adsorption at 254 nm and TOC in each surface water sample and analyzed pH, residual chlorine, and haloacetic acids in the treated water samples.
Results: We found that TOC in surface water resources is 3.6-4.42 and 1.78-2.71 mg/l in spring and summer respectively. Moreover, haloacetic acids concentration was found to be 41.7-55.56 and 34.83-43.73 μg/l in spring and summer respectively.
Conclusion: Our results revealed that concentration of NOM, TOC, and HAAs was more in spring than summer. In addition, concentration of HAAs was depended up on NOM and TOC. Considering maximum permeable concentration of HAAs (60 μg/l) by EPA, it can be claimed that concentration of HAAs was less than the maximum permissible level in all of the samples. However, the immanency of the monitored values to the standard values can be a warning for concerned authorities in water industry.
Seyed Khabat Naynava, Bahareh Lorestani, Mehrdad Cheraghi, Soheil Sobhanardakani, Behzad Shahmoradi,
Volume 17, Issue 3 (12-2024)
Abstract
Background and Objective: Fenitrothion is a phosphorus-based pesticide that enters water resources through various sources,including industrial wastewater and agricultural effluent. its non-biodegradability, which results from the formation of strong chemical complexes, advanced oxidation methods are required to remove it from environmental matrices. This study aimed to evaluate the performance of a magnetic graphene oxide nanocomposite functionalized with cerium dioxide in the removal fenitrothion from aqueous solution.
Materials and Methods: In this applied research, GO@Fe3O4@CeO2 was synthesized and subsequently used as a photocatalyst for the removal of Fenitrothion from aqueous solutions. Characterization of GO@Fe3O4@CeO2 was conducted using X-Ray Diffraction (XRD), Scanning Electronic Microscopy (SEM), SEM-EDX elemental analysis, Fourier transform infrared spectroscopy (FT-IR), and vibrating sample magnetometry (VSM) methods. The effects of various parameters, including pH (2-9), photocatalyst dosage (10-40 mg), and contact time (0-90 min), were assessed to determine their influence on fenitrothion removal efficiency.
Results: The results demonstrated that the removal efficiency increased up to 60 min contact time, 20 mg of photocatalyst. The optimal pH for fenitrothion removal was found to be 4. Additionally, kinetic analysis of the photocatalytic removal process indicated that it followed a pseudo first-order (PFO) model.
Conclusion: The GO@Fe3O4@CeO2 nanocomposite proved to be an effective and accessible photocatalyst for the removal of fenitrothion from industrial wastewater under UV light.
