Iranian Journal of

Background and Objectives: Heavy metals processing industry has always been a major cause of concern which affects soils, surface waters, ground waters and river sediments contaminations. Thus, the Zanjan Zinc and Lead Smelting Plant has been considered as a potential source of contamination.
Mterials and Methods: This cross-sectional study has been conducted in February 2008 in the site region .The concentrations of Lead, Zinc and Cadmium have been assessed. The samples have been taken from 17 wells and atomic absorption spectrophotometeric method has been used to assess the samples. In order to find out and locate the exact situation of the wells under study, Global Positioning System instrument has been used. The correlation between the concentration of each metal and the distance of studied well from the plant has been assessed too.
Results: The findings of this study showed that lead and cadmium concentrations were 53% and 59% respectively out of the guideline values of World Health Organization.
Conclusion: The concentration of Zinc was lower than both national and international values in all samples. As the heavy metal concentration is very important for human health status, the other fields of study like heavy metal air pollution effects and related diseases and conditions should be studied and assessed.

Background and Objectives: Bottled water is a main beverage at many developed and developing countries. It can be polluted with chemical agents. One of these agents is nitrate which affects the safety of bottled and mineral water and cause healthy effects on consumer health. Today&aposs consumption of bottled water get a grate develop, thus infer of the quality of this matter is compulsive for each consumer.
Materials and Methods: A descriptive-analytical and cross- sectional study was done with the aim of determination of nitrate in bottled water available in market of Tehran City in 2007. In this study, 18 samples of six various manufacturers of product were examined.
Results: Results showed that the mean of nitrate is 9.02 mg/L and all samples have nitrate bellow 50 mg/L and they are at the standard level. Also, the results of the examinations have good correspondence with the concentration of nitrate on bottled water labels and according to statistic meaningful relation, was considered.
Conclusion: The nitrate content of these bottled water available in market of Tehran city is located at the level of national and global standards and it can not be a serious problem for health of consumer.

Background and Objectives: Natural organic matters (NOMs) are abundant in natural water resources and in many ways may affect the unit processes in water treatment. Although NOMs are considered harmless but they have been recognized as disinfection by-products (DBPs) precursors during the chlorination process. Formation of DBPs highly depends on the composition and concentration of NOMs. The objective of this study was to determine natural organic matter and its fractions concentrations in the surface water sources of Tehran.Materials and Methods: Water sampling was conducted monthly between May to July in three rivers of Lar, Jajrood and Karaj, as the main drinking water supplying sources in Tehran. Quantitative parameters of pH, EC, UV₂₅₄ and DOC were studied based on standard methods. The XAD-7 resin method was used for fractionation of NOMs.Results: Results showed that NOM concentrations in Lar, Jajrood and Karaj rivers were 8.53, 12.9 and 11.3 mg/L, respectively. The HPO (hydrophobic) fraction was predominant compared to the HPI (hydrophilic) fraction in water samples. The mean of total percent of HPO and HPI fractions were about 57% and 43%, respectively.Conclusion: Since the hydrophobic NOM fraction exhibits higher trihalomethane formation potential (THMFP) than hydrophilic part, Tehran water chlorination exhibits higher THMFP than haloacetic acid formation potential (HAAFP). The information obtained from this study may be further employed in the design of the control techniques and management strategies for the water treatment plant, especially for DBPs reduction.

Background and Objectives: In the production of some high-consumed food products like cake, biscuit, chocolate and spaghetti water is used in the preparing of primary material and in the kneading processes. At the present study microbiological and chemical quality of consumed water in food industries of East Azerbaijan Province were studied.
Materials and Methods: Eleven factories with different products were selected. Water samples were collected and analyzed regarding the microbiological contamination and chemical parameters, and heavy metals. In addition, condition of water quality in selected industry was surveyed during the summer.
Results: According to the results, monitoring of water quality in the studied industries is not suitable. The chemical characteristics of consumed water in those industries had major differences. Ni, Cr, Zn, Fe and Mn were present in all analyzed water but in lower concentration than national Maximum Contaminant Level (MCL). Pb was measured in higher concentration than MCL in spaghetti factory no. 2 and close to MCL in wiener and frankfurter and sugar industries. Cd was close to MCL in spaghetti factory no. 2 and wiener and frankfurter industries.
Conclusion: It was concluded that for the safety and health of food products the food industries should use the public water supply system as water source at least in food processing units or in the units of preparing of primary materials. Also for the preventing of chemical pollution of food products it is necessary, pay more attention to the subject of water quality control according to the special water standard of food industries, and using less volume of water in some food industry isn.t acceptable reason for neglecting of water quality monitoring and assessing. In addition it is required to analyze heavy metals in the final products of those industries.

Background and Objectives: A conventional treatment to stabilize the excess activated sludge is the aerobic digestion process but due to long aeration time, it requires large equipments as well as high investment cost. Because of high oxidation potential of ozone, sludge ozonation enhances stabilization rate and reduces sludge treatment equipment size and cost. Therefore, in this study, the combination of pretreatment with ozone and aerobic digestion processes were investigated.
Materials and Methods: The experimental set-up consisted of an ozone generator and ozonation reactor with the total volume of 2 L. Removal percentages of TSS, VS, total and soluble COD, HPC, fecal coliform and settable solids were measured in integrated process compared to the single ones.
Results: The results of this research indicated that the aerobic digestion of waste activated sludge during 10 days could reduce 38% of volatile solids and thus obtaining the EPA standard. Also, the results of combined ozonation and aerobic digestion revealed that the pre-ozonation at 0.25 g O3/g TS or 0.5 g O3/g TS with 6 or 3 days aeration, respectively, could achieve 38% reduction in VS and hence the requirement set by EPA. Therefore, integration of pre-ozonation with aerobic digestion can significantly reduce the digestion time to attain the standards.
Conclusion: The sludge pre-ozonation with low dose of ozone due to solids disintegration can enhance the efficiency of aerobic digestion in waste activated sludge stabilization, and consequently decrease size of equipments, air requirement, investment and probably operation cost.

Backgrounds and Objectives: Now a days modified activated sludge ways are used for standard removing nutrient substances from waste water that is named Enhanced biological phosphorus removal One of the most suitable ways is Anoxic-Oxic(A/O) process. The goal of this research is investigation and solving existing problems of Khoy power plant(P.P) waste water treatment plant(WWTP)and optimizing of phosphorus removal in it.
Materials and Methods: This research is done full scale in this treatment plant. The treatment plant was operating with extended aeration process, and some problems had, so in the first stage with in investigation of total efficiency, problems and their reasons determined. In the second stage after operational modifications existing problems was solved and real efficiency of treatment plant particularly for phosphorus(P) removal determined. In the third stage changes, system converted to A/O process and new system was tested with Changing parameters like food/microorganism(F/M), return sludge ratio(RAS)and sludge retention time(SRT)
Risults: In the first stage the most important problems were over concentration of BOD,TSS, and P in effluent of treatment plant and overgrows of alga observed in parts of treatment plant and effluent receiving conduit. The main reason of high concentration of P was considered releasing of sludge. In the second stage operating condition modification efficiency of P removal increased from 50to 62 percent. In the end of third stage value of P removal reached to %82 and the most suitable of anoxic contact time was determined 3to4 hours, SRT terry day and F/M ratio o.12,that the most effective change has been the decrease of SRT to three days.
Conclusion: Adjusting of operating factors like SRT,RAS, sludge processing way in WWTP can increase P removal in them with in total efficiency remaining, such as in this case it was %12. In waste water treatment particularly for P removal the A/O process is suitable so in this project its effect on P removal efficiency has been %20.

Background and Objectives: Phenolic compounds are presence in many industrial wastewaters, and have been classified as priority pollutants. Application of several conventional processes due to high cost and low efficiency has been limited. Thus, new methods such as enzymatic polymerization seem to be preferable and effective processes with high potential to substitute the conventional processes. This study was carried out to evaluate Raphanus sativus extract as a peroxides enzyme source for polymerization and removal of phenol from synthetic wastewater in the presence of hydrogen peroxide.
Materials and Methods: The study was performed in batch reactor at room temperature. Peroxidase enzyme was extracted from Raphanus sativus plant roots . Primary concentration of phenol in wastewater was 100 mgl-1. The concentration of phenol and enzymatic activity was been measuredby photometric assay.
Results: The results show that Raphanus sativus extract is a suitable source of peroxidase enzyme. Mean enzymatic activities in this extract was 3.107 Uml-1. Also, our results showed that elevation of extract volume lead to high efficiency of phenol removal, in which the increase in the extract volume from 5 to 50 ml, resulted in the efficiency of processes increased from 7.6 to 98.2 %. Also, sequencing addition of H2O2 and extract has improved the effects. The phenol removal efficiency of the reaction time after 3 h with single and three stages adding of reactants was 84.2 and 93.1% , respectively.
Conclusion:Enzymatic polymerization can be used as an appropriate process for the removal of phenolic compounds from wastewaters. To meet the optimized condition in process, the ratios of phenol/ enzyme and H2O2/ phenol and sequences of the adding of reactants should be considered.

Backgrounds and Objectives: in recent years, mobile bed biological reactors have been used progressively for municipal and industrial wastewaters treatment. Dissented experiment is a trial that significant changes will accrue for influent variables in the process, and generally used for identification of the effective factors and optimization of the process. The scope of this study was determination of the optimized conditions for the MBBR process by using of Taguchi method.
Materials and Methods: Reactor start up was done by using of the recycled activated sludge from Ahwaz wastewater treatment plant. After that and passing the acclimation period, with hydraulic residence time equal to 9 hours matched for 1000, 2000 and 3000 mg/l based on COD respectively, for optimization determination of the acclimated microbial growth, the variables change (pH, nitrogen source, chemical oxygen demand and salinity) were determined in 9 steps, and all of the results were analyzed by Qualitek -4 (w32b).
Results:In this study, organic load removal based on COD was 97% and best optimized condition for MBBR were (inf. COD=1000 mg/l, pH= 8, salinity = 5% and the Nitrogen source= NH4CL)
Conclusion: Based on our finding, we may conclude that Taguchi method is on of the appropriate procedure in determination the optimized condition for increasing removal efficiency of MBBR.

Backgrounds and Objectives:Safe drinking water providing is one of the main purposes in the community. Development and improvement of community is related to the public health. In this study !we studied the bacteriological quality of 116 villages under coverage of the water and wastewater companies in rural areas of Saqqez in.1386
Material and Methods:Drinking water of these rural areas have provided of deep, semi-depth- wells and spring water sources. Because in numerous rural areas both sources of drinking water and in some of them different sources of drinking water were used (old and new storage water source), in general, 359 samples were collected and transferred to the laboratory for testing to evaluate its quality. We also used linear Regression statistical analysis for collected data.
Results:results show that residual chlorine in drinking water in 33.88 percent of rural areas population were in range 0.2-1 mg/l. For 98.3 percent of the seqqez rural population, the turbidity was lower than the maximum permissible levels of drinking water standards of Iran (5 NTU). There was no any E.coli contamination in 88 percent of drinking water in saqqez rural areas.
Conclusion:Based on WHO guidelines concerning the microbial quality of water published in 2006! the average indicator for lack of E.coli in water of rural areas of seqqez was 88 percent and water is safe or good for drinking.

Backgrounds and Objectives: Dyes  are  organic  materials  with  complex structures, toxic,  carcinogenic, teratogenic,nonbiodegredable properties and!the most!important pollutants of textile industrial wastewaters. The goal of this study was to survey the feasibility application of bone char (BC) as a sorbent for the  of methylene blue (MB) from synthetic wastewater.The sub goals of the research!were to determine!the adsorption isotherm, !effects of primary concentration of dye, adsorbent!dose, contact!time, and pH for the adsorption of MB with BC.
Materials and Methods: BC was prepared under laboratory conditions by using of electrical furnace at 400°C for 2h. The prepared BC was crushed and pulverized by standard ASTM sieves with range of 10-16mesh(1.18-2mm).The  chemical composition  and  solid  structure  of BC was  analyzed using X-ray diffraction(XRD) and  scanning  electronic  microscopy (SEM). Measurement  of  the surface area was carried out by N2 gas via BET isotherm and Belsorb software. The concentration of dye was measured by photometric!method (663nm).
Results: Predominant!compositionof BC is calcium hydroxyl apatite (Ca5 (PO4)3OH with 14m2/g surface area. The results of this study showed that increasing of primary concentration of dye, adsorbent dose and pH (5 to12) would lead to increasing of adsorption/removal of MB dye.Equilibration of dye adsorption was reached at lapse of 2h andoptimum pH for adsorption of MB with BC found in the rage of 8.5-12.Adsorption of MB witht BC complies witht freundlich isotherm(R2:0.99).
Conclusion: Bone char is a cheap component that can be used as an adsorbent in water and wastewater treatment. Based on optimum pH of 8.5-12 found for the removal of MB and the fact that many of textile!industrial wastewaters have an alkaline pH, this adsorbent can be!used for the removal of dyes from these wastewaters.

Backgrounds and Objectives: Determination of Fluoride in drinking water has received increasing interest, duo to its beneifical and detrimental effects on health. The aim of this research is investigation of Effect of  activated alumina in fluoride concentration reduction in drinking water.
Materials and Methods: Expriment in batch system and with change effective parameters such as pH(5, 7,9), equilibration time (30, 60, 90, 120 minute), initial fluoride concentration(1.4, 2, 2.4 mg/l) and activated Alumina dosage (0.1, 0.2, 0.3 gr/l) was investigated. Also found data of this research were fited with Langmuir and Freundlich models, kinetic data with pseudo- first order, pseudo- second order and modifited pseudo- first order  models.
Results: The results showed that with increasing of pH of solution, removal efficiency was decreased and optimum pH was found to be in the range of 5 to 7. Also removal efficiency of fluoride was increased with increasing of adsorbent dosage and decreasing of initial concentration of fluoride. Adsorption isotherm data show that the fluoride sorption followed the Langmuir model (r²=0.98). Kinetics of sorption of fluoride onto Activated alumina was well described by pseudo- second order model.
Conclusion: The concentration of Activated Alumina had significant effect on the reduction of fluoride ions concentration in water.The higher fluoride removals were observed for batch experiments at pH=5 because no free fluoride ion is present in the solutions, and it could be casued by electrostatic interactions between the surface of alumina and the dominant fluoride species in solution The kinetic model can adequately describe the removal behaviors of fluoride ion by alumina adsorption in the batch system.

Backgrounds and Objectives: Swimming pools water if not disinfected properly can be one of the infection sources of different microorganisms such as staphylococcus. This study is to aware the authorities and users about the conditions existed in sheltered swimming pools in Sari and to believe the contamination of the water there, related to the existence of staphylococcus aureus.

Materials and Method: In this descriptive study 32 specimens collected randomly from 15 swimming pools in action during three months from 60 cm deep under specific conditions in sterile containers and taken to the laboratory of health college in 2 hrs and were analyzed for the contamination from staphylococcus aureus and some other parameters like temperature, pH, chlorine residual and opacity on the basis of microbiological and standard methods.

Result: Results showed an average temperature of 27.08 degree Celsius, PH=7.6, average chlorine residual 1 mil/l and opacity average was 77 NTU % and the highest contamination from staphylococcus aureus (29.3 %) in C and the lowest (10.19 %) was observed in D swimming pool. Furthermore this analysis showed that in 90% of specimens there was a direct relationship between the ratio of chlorine residual, times of swimming, water temperature and the number of staphylococcus.

Conclusion: Swimming pools water if not disinfected properly can be one of the infection sources of different microorganisms such as staphylococcus. Some suggestions inorder to optimization of the swimming pools condition presented in this paper.

Backgrounds and Objectives: A great part of organic compounds cause more pollution in natural  waters meet, are chemical dye material. Azo dyes have more usage in different industries. Azo dyes not only give undesirable dye to the water but also have mutation potential and carcinogenesis effects in human and cause the production of toxic substances in water environments.The purpose of this study is investigation of iron powder, hydrogen peroxide and iron powder-hydrogen peroxide processes in removal of acid yellow 36 dye from aqueous solutions.
Materials and Methods: This study was conducted in laboratory scale. At this experiment synthetic solution was made from acid yellow 36 dye, and the removal of acid yellow 36 dye was studied by iron powder, hydrogen peroxide and iron powder- hydrogen peroxide processes .Also effect of dye concentration, pH solution, hydrogen peroxide concentration, iron powder concentration and the time of contact on decolorization, were evaluated.
Results: The results showed that iron powder - hydrogen peroxide process, compared to two other  process has high decolorization power. Removal efficacy of iron powder-hydrogen peroxide process with H2O2 =23.33 ml / L, pH =3, iron powder 2000 mg/L and 60 minute ,was about 97.9%
Conclusion:In general this investigation showed that , this method (Iron powder-hydrogen peroxide process) has high efficiency for removal of Azo dyes. But application this method in the industry, should be economically evaluated.

Backgrounds and Objectives: Drinking water quality after treatment and before reaching  the consumer could be affected by distribution pipes, service lines and Home devices. The structure of water coolers, a home device that are widely used in warm months of the year, could potentially affect the quality of drinking water. The aim of this study was to assess the microbial and chemical quality of water from conventional water coolers.
Materials and Methods : Water samples were collected from 29 water cooler systems at the Isfahan  university of medical sciences. 29 control samples also obtained from the nearest drinking water taps. All samples were examined for total heterotrophic bacteria and physicochemical parameters including temperature, ph, turbidity and heavy metals.
Results: All samples from the water cooler systems complied with the EPA guidelines for total heterotrophic bacteria count. There were no significant differences between the levels of heavy metals in water samples from the water cooler systems and taps. There was only a significant difference between the level of Cu in the water samples from cooler systems and taps
Conclusion: The overall results of this study indicated that the use of water cooler systems from hygienic point of view could not cause any problems for consumers

Backgrounds and Objectives: Water contamination by pesticides is considered as an environmentalproblem today. In terms of agricultural development and diversity of plant pests, the use of pesticides has been increasing. Hamedan province has a suitable agricultural condition, it has enjoyed significant development in this respect. Among all the cities of Hamedan province, Hamedan city has the highest rank in tiller crops. Therefore, yearly use of pesticides is increasing in this area which could be a serious threat to water resources of the city. The aim of this survey was determinaton of Organophosphorous and Carbamat pesticides residue in drinking water resources of Hamadan in 2007.
Materials and Methods: In this survey, 126 water samples were collected from 7 drinking water resources of Hamedan during 12 consecutive months in 2007. for determination of these pesticides,two methods (solid- phase extraction and Liquid-Liquid extraction) were adopted .and samples were analyzed by means of HPLC and GC/MS applying standard methods.
Results: Final results showed that the most concentration of Chlorpyrifos and Carbaryl pesticides were found to be about 3.85 ppb (part per billion) and 1.8 ppb in spring and June respectively the maximum concentration of Diazinon was about 36.5ppb in October (autumn).The minimum concentration of the three pesticides was detected in winter. According to the statistical test Two - Way ANOWA there were significant differences among pesticides concentrations in the water samples in different seasons (p<0.05) . However, there wasn't a significant difference in pesticides concentrations in surface and ground water samples(p>0.05).
Conclusion: Different studies have shown that pesticides residue concentration in water samples have a relationship with the amount of pesticides used in an area, physical and chemical refractory properties of pesticides and environmental conditions. Thus, using resistant pollutants such as pesticides will be a serious threat to health of water consumers if they are not properly controlled.

Backgrounds and Objectives:Propylene glycol is applied in many industries as raw material and can be released to the environment through wastewater of such industries. The biological treatment of solutions containing high concentration of propylene glycol is difficult and some problems can be observed during this process. The main objective of this study was the investigation of electrochemical degradation of propylene glycol and the parameters influencing on improving removal efficiency.
Materials and Methods: In this study the degradation of propylene glycol was made by passing an electrical current though the synthetic wastewater containing propylene glycol. In order to investigate this process several types of electrode with applied voltage ranging between 5 to 50 V was used. Due to the effect of NaCl concentration on removal efficiency which was mentioned in the literature, the experiment was performed for different NaCl concentrations.
Results: In optimum condition, the maximum removal efficiency of propylene glycol (based onCOD) was obtained equal to 90%. The results showed that rising applied voltage, NaCl concentrationand retention time increase the removal efficiency. The optimum retention time was obtained equalto 50 min. The maximum removal was obtained when aluminum electrode was used. It can beattributed to the production of coagulant material such as Al+3 during this process.
Conclusion: The results revealed that this process can be useful for treating the industrial wastewatercontaining propylene glycol.

Backgound and Objectives: The aim of this study is to investigate water consumption, domestic wastewater generation and organic matter concentration, based on both, economical income and meteorological temperature.
Materials and Methods: The method of this study is descriptive and analytical. A checklist was used to collect data on economical income. Water consumption was obtained based on water bills. Wastewater generation and organic matter such as biochemical oxygen demand (BOD) per capita/ day were measured every four hours, during a day in three regions of Kermanshah city: Kasra, Ellaheiah and Taavon.
Results: Comparing water consumption in winter and summer showed significant difference in three regions, mentioned above. The water consumption was (398 ± 75, 291 ± 48 and 188 ± 50) for warm climate and (200 ± 25, 188 ± 35 and 140 ± 41) for three regions respectively in cold weather. In spite of an apparent difference in BOD in three regions, it was not significant statistically. Water consumption has strongly considerable relationship with economical income (r =0.988, P_value <0.001), while the generated wastewater in these regions were not different, statistically for warmclimate (220 ± 60, 204 ± 15 and 170 ±34), and in cold weather (170 ± 21, 158 ± 31 and 112 ±29), also the generated wastewater did not have considerable difference in cold climate. This study confirms that, the effects of these two parameters, i.e.monthly economical income and environmental temperature on water consumption, generated wastewater and biodegradable organic loading per capita/day is considerable. It was concluded that water consumption and wastewater generations were much more in warm climate than in cold weather.
Conclusion: Finally through this study the estimation of water consumption, wastewater generation and BOD concentration becomes possible, which is beneficial for establishment of water consumption.

Backgrounds and Objectives:Much attention has been recently paid on using waste materials as adsorbents for removal of contaminants from water and wastewater. A new low cost waste was examined for its capacity to adsorb RR198, an azo reactive model dye, from an aqueous solution.
Materials andMethods: The waste was dried, powdered and characterized before being used as an adsorbent. The effects of pH (3-10), adsorbent dose (0.2-3 g), dye concentration and contact time on the adsorption efficiency were investigated. Equilibrium study data were modeled using Langmuir and Freundlich models.
Results: The characterization analysis indicated that itwas composedmainly of ferric hydroxide. The powder had a BET and average pore size of 107 m2/g and 4.5 nm, respectively. The results showed that dye removal was highest at a solution pH of 7 to 8 and a powder dose of 2 g/L. The RR198 removal percentage decreased from 100& to 43& at 140 min contact time when the concentration of dye was increased from 25 mg/L to 100 mg/L, at optimum pH and dosage. The Langmuir equation provided the best fit for the experimental data. The maximum adsorption capacity was calculated to be 34.4 mg/g.
Conclusion: According to the obtained results, the water coagulation waste sludge appears to be a suitable low cost and effcient adsorbent for removing reactive azo dyes from waste streams.

Backgrounds and Objectives: One of environmental outcomes in industrial towns is developing environmental pollution such as production of industrial wastewaters. These industrial wastewaters should be appropriately treated before entering to receiving waters. However we can't solve environmental anxieties by establishing of wastewater treatment plants alone but permanent and regular assessment of these treatment plants performance is necessary for achieving environmental standards. Thus, this research has been done in order to investigation of activated sludge performance in wastewater treatment of Agghala industrial town in Golestan province.
Materials and Methods: This cross-sectional study implemented in sewage treatment plant laboratory of Agghala industrial town in Golestan within 12 months at 2007. Chemical Oxygen Demand (COD) parameter determined twice in week, But Biochemical Oxygen Demand (BOD) test accomplished weekly. pH measured by pH meter daily. Experiment of total suspended solids (TSS) and total dissolved solids (TDS) carried out every 10 days. All tests accomplished according to standard method for water and wastewater examination (2005). Then data analyzed using excel 2007.
Results: The average of BOD, COD and TSS in influent was 11196.17, 1854.58, 1232.25 mg/L respectively.Maximum influent organic loading rate was related to Shahrivar andMehr months. The total average of removal efficiency for BOD, COD and TSS was calculated 99.66, 98.2, and 97.6% respectively.
Conclusion:Quality of this treatment plant effluent was according to effluent disposal standards all over year. In sum, efficiency of this treatment plant (activated sludge system) was very good ininfluent pollutant removing. However occasionally effluent was not adapted with environmental standards but these deficiencies is solvable by accurate management and supervision on flow rate and influent organic loading rate easily.

Background and Objectives: Nowadays nitrate concentrations in surface water and especially in groundwater have increased in many locations in the world. Since nitrates cause many health and environmental concerns, increased nitrate concentrations in groundwater have led to rendered aquifers unusable as water sources. So, as the water demand is still increasing the throughout the world, decreasing the nitrate concentration in drinking water is imperative. Magnesium powder has been determined to be potentially useful for the removal of nitrate in the water environment. This research is aimed at subjecting the kinetics of nitrate chemical reduction by Mgo to an analysis of some factors affecting the chemical denitrification.
Materials and Methods: Nitrate concentrations determined in 220 nm using a spectrophotometer.To determine the performance of nitrate removal by Mg0 powder, double distilled water was used for preparation of reagents and simulation of contaminated water with nitrate.All experiments were triplicate and the averaged results were reported.
Results: Kinetics analysis from batch studies revealed that the denitrification reaction with Mgo powder appeared to be a first-order with respect to substrate and the observed reaction rate constant (kobs). The effects of mixing intensity on the denitrification rate suggest that the denitrification appears to be coupled with oxidative dissolution of magnesium through a largely mass transportlimited surface reaction. Also in the denitrification by Mgo determined that Mgo dose related with kobs ( R2>0/99 )S
Conclusion: In this research was determined that denitrification effectively by Mg0 powder can achieved in a wide range of concentrations under atmospheric conditions and without pH controlling within short reaction time. Denitrification rate was related to some parameters such as contact time, Mgo dosage, mixing rate and initial nitrate concentration.