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Isotherm and Kinetics of Arsenic (V) Adsorption fromAqueous Solution Using Modified Wheat Straw
A Maleki, A Eslami,
Volume 3, Issue 4 (1-2011)
Abstract

Backgrounds and Objectives:Water contamination with arsenic has been recognized as a serious problem and its epidemiological problems to human health have been reported. The objective of this study was to explore the possibility modified wheat straw using sodium bicarbonate for removing arsenic from aqueous solution.
Materials and Methods: Adsorption process was accomplished in a laboratory-scale batch with emphasis on the effect of various parameters such as pH, contact time, arsenic concentration and adsorbent dosage on adsorption efficiency. In order to understand the adsorption process, sorption kinetics and equilibrium isotherms were also determined.
Results: It was found that adsorption of the arsenic was influenced by several parameters such as arsenic initial concentration, adsorbent dosage and solution pH. Maximum absorption efficiency was achieved at pH 7. As expected the amount of arsenic adsorbed on wheat straw incresed as its concentration went up. Among the models tested, namely the Langmuir, Freundlich, and Dubinin Radushkevich isotherms, the adsorption equilibrium for arsenic was best described by the Langmuir and Freundlich models. It was also found that adsorption of arsenic by wheat straw followed pseudo second-order kinetics. Mean free energy of adsorption (15.8 kJ mol-1) indicates that adsorption of arsenic by wheat straw might follow a chemisorption mechanism. Desorption studies show that arsenic ions are strongly bounded with the adsorbent and exhibit low desorption.
Conclusion: It is concluded that that adsorption by modified wheat straw is an efficient and reliable method for arsenic removal from liquid solutions.

 


Determination of mycotoxin contamination in imported wheat to Mazandaran province by high performance liquid chromatography
R Farahmandfar, S Rashidaei Abandansari , E Maghsoudlou, M Asnaashari,
Volume 11, Issue 1 (6-2018)
Abstract
Background and Objective: Wheat is one of the most important cereals due to the supply of much of the flour used in bread making in most countries, such as Iran. Wheat contamination with mycotoxins is subject to different production and maintenance conditions. As a carcinogen and mutagen, monitoring the amount of mycotoxins in imported wheat and prevention of the entry of low quality wheat to the food chain are essential. Therefore, this study was conducted to determine the contamination of the wheat imported to Mazandaran province.
Materials and Methods: Samples of the wheat imported from Caspian Sea countries were evaluated for moisture content and mycotoxins contamination (ochratoxin A, zearalenone and deoxynivalenol). Mycotoxins contamination was determined by HPLC method via purifying with immunoaffinity column for ochratoxin A and zearalenone, and DONSPE column for deoxynivalenol.
Results: The results of this study showed that the average of ochratoxin A, zearalenone, and deoxynivalenol in the samples were 2.24, 133.50 and 181.66 ng/g, respectively.
Conclusion: All the samples were within the acceptable level for mycotoxin according to the permissible limits of Iran National Standard. Additionally, a direct relation between deoxynivalenol and moisture content of the samples (-0.092) was not observed and the correlation between moisture content and ochratoxin A and zearalenone was 0.104 and 0.168, respectively.

Aflatoxin B1 concentrations in corn flour and wheat flour supplied in Shahrekord province using ELISA method in 2022
Ebrahim Rahimi, Mohammad Amin Heidarzadi, Najmeh Vahad Dehkordi,
Volume 16, Issue 3 (12-2023)
Abstract
Background and Objective: Aflatoxins are secondary metabolites of fungi, which can have very dangerous consequences for human health in addition to spoiling food and changing organoleptic properties. Aflatoxin entering the body and targeting the liver as the main organ involved can cause liver and blood cancer. Hence, the aim of the present study is to measure aflatoxin B1 in corn flour and wheat flour supplied in Shahrekord using ELISA method in 2022.
Materials and Methods: In this study, 40 samples of flour, including 20 samples of corn flour and 20 samples of wheat flour, were randomly sampled from the supply centers and sent to the food hygiene laboratory to track and determine the amount of aflatoxin B1.
Results: The results showed that all samples of wheat flour and corn flour contained aflatoxin 1B. The average of aflatoxin B1 in wheat flour and corn flour was calculated as 2.58 ± 0.95 and 3.47 ± 2.07 (µg/kg) of the sample, respectively; Among the 20 examined samples of corn flour, the concentration of aflatoxin B1 ranged from 3.4 (µg/kg) to 1.9 (µg/kg) and in 20 samples of wheat flour (µg/kg) from 7.90 to (µg/kg) was 1.4; Therefore, the concentration of none of the samples was higher than the Iranian standard.
Conclusion: The occurrence of aflatoxin B1 in all the samples examined in the current study is lower than the risk range determined by the Iranian standard, so in this case, its aasociated high risk does not threaten the health of consumers.
 

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