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Ts. Jafarzadeh Kashi, M. Erfan ,
Volume 18, Issue 1 (30 2005)
Abstract

Statement of Problem: The quantity of remaining unreacted double bonds may be a significant factor pertaining to the mechanical, physical and chemical properties of restorative resins. Insufficient polymerisation within the hybrid layer may cause significant differences in the quality of this layer, and act as a reservoir for monomer release thus increasing cytotoxic potential.

Purpose: The aim of this study was to measure the degree of conversion of three generations of 3M dentin bonding agents and an experimental dentin bonding agent

Materials and Methods: The quantity was determined from the transmission IR-spectrum of the materials before and after polymerization. ScotchBond MP plus adhesive, SingleBond, Prompt L-Pop, and an experimental dentin bonding were used to measure degree of conversion. Six repetitions of each bonding were investigated. Time of light curing was 120s. Kruskal-Wallis and Mann-whitney test were used to compare groups with P<0.05 as the limit of significance.

Results: The results showed a significant difference between groups (P<0.01). A trend of increasing in Singlebond conversion obtained in comparison with ScotchBond MP plus adhesive, Prompt L-Pop and experimental dentin bonding. The degree of conversion was not statistically significant among the other dentin bondings. No significant difference was found between conversion of the experimental dentin bonding and ScotchBond MP plus adhesive (P=1.00) with P<0.05 as the limit of significance.

Conclusion: Dentin bonding technology continues to evolve toward simpler systems. However, Prompt L-Pop as a self-etching adhesive does not show the trend of increasing the degree of conversion. However, the performance of these simpler systems must be further investigated.


T. Jafarzadekashi, M. Erfan, M. Mirzaie, S. Kalbasi,
Volume 22, Issue 1 (11 2009)
Abstract

Background and Aim: Extent of polymerization (Ep) is the rate at which methacrylate C=C bonds are converted to aliphatic C-C bonds. The higher the Ep value, the better the polymerization of the polymer. If the polymer dose not polymerize sufficiently, it could have destructive effects e.g. releasing monomer, initiator, free radical or insufficient polymerization of hybrid layer. Therefore, measuring the Ep value is very important. Light-emitting diodes (LEDs) are becoming increasingly popular in dental practice as they have a long life expectancy. LEDs do not generate infrared wavelength, and have a constant light output. Therefore, comparison of LED and Quartz tungsten halogen (QTH) from the point of Ep is important. Differential Scanning Calorimetry (DSC) is a proper tool for determining the Ep value, monitoring the process of reaction and reaction kinetics. The aim of this study was to measure the Ep value of a dental bonding containing camphorquinone/amine photoinitiator which were cured by LED and QTH using DSC.

Materials and Methods: In this experimental study, 2.5 mg of bonding material were placed in DSC aluminum pans. Two different light cures, LED & QTH (Coltene Company Coltolux ®75 LED Curing Light), were used in this study. The light guide was positioned at a distance of 9mm from the base of the sample chamber. Each sample was photopolymerized for 30 seconds, and the DSC curves were obtained after 100 seconds from initiation of photopolimerization of each sample, at both 23oC and 37oC. The heat of photopolymerization (DH) was calculated from the area under the peak of the differential temperature curve. Five samples were used for each condition. The data was analyzed by two-way ANOVA.

Results: There was highly significant difference between two temperatures in the experimental bonding (pvalue<0.001). Representative DSC curves showed the same kinetic behavior for LED and QTH.

Conclusion: The results revealed that the Ep generated by high power density QTH was the same as that of produced by second generation of LED.


T. Jafarzadeh Kashi, M. Erfan, A. Nezadi Niasar,
Volume 22, Issue 3 (1 2009)
Abstract

Background and Aim: Evaluation of shear bond strength and microleakage of bonding agents is important as these properties play main roles in adhesion of composite to dental tissues. Microleakage results in bacterial penetration into dentin tubules and enamel surfaces and causes sensitivity and recurrent caries followed by destruction of composite filling. Insufficient shear bond strength results in early failure of filling in low masticatory forces. The main goal of this study was to compare the microleakage and shear bond strength of an experimental adhesive and Scotchbond multi-purpose (MP) adhesive system.
Materials and Methods: In this experimental study, sixty extracted caries free human molar teeth were randomly assigned into 4 groups of 15 each for shear bond strength. Variables were bonding agents, enamel and dentin. Twenty teeth assigned into 2 groups of 10 each were used for valuation of the microleakage. Microleakage and shear bond strength were performed according to ISO TR 11405. All data were analyzed with parametric and non-parametric tests according to their normality distribution. Also, Weibull distribution performed on data.
Results: Data obtained from both microleakage and shear bond strength tests showed no significant difference between the experimental bonding and Scotchbond MP bonding (P>0.05). Furthermore, there was no significant difference between the microleakage of occlusal and gingival parts of both bondings (P>0.05).
Conclusion: Experimental adhesive bonding showed acceptable results regarding microleakage and shear bond strength. It may be concluded that the experimental dentin bonding had a comparable performance quality with that of commercial system.


Tahereh Sadat Jafarzadeh Kashi, Mohammad Erfan, Akbar Fazel Najafabadi, Seied Mostafa Fatemi, Marjan Behroozibakhsh, Haleh Hali, Hosein Bagheri Gorgani,
Volume 25, Issue 2 (9 2012)
Abstract

Background and Aims: The aim of this study was to measure the degree of conversion (DC) of three types of composite resins (micro-hybrid, nano-hybrid and Ormocer) with different light curing units (LED LCU and QTH LCU) in two depths.

Materials and Methods: Three commercially available dental resin composites were used in this study: (Tetric Ceram, Ivoclar Vivadent, Liechtenstein-A2 shade), (Tetric Evoceram, Ivoclar Vivadent, Liechtenstein-A2 shade), (Ceram X, Dentsply, Germany-M2 shade). Specimens were divided into two groups, 5 specimens were photo-activated by QTH unit (Coltolux 75-Colten) and the other five specimens were cured by LED (Demi-Kerr). Then each specimen was sectioned at the top surface and at 2-mm depth. The DC was measured by FT-IR
(Bruker-tensor 27). The data were analyzed by 3-way ANOVA test.

Results: There was significant difference between tested composite resins (P<0.001). The results of top surfaces were significantly different from those observed at 2-mm depth (P<0.001). The type of curing unit affected the polymerization of Ceram X resin composite.

Conclusion: This study showed a significant difference in the degree of conversion in different thicknesses within three groups of resin composites.


Mehran Bahrami, Maryam Memarian, Farinaz Khodadad Kashi,
Volume 28, Issue 3 (10-2015)
Abstract

Background and Aims: Residual ridge resorption is an unpredictable, unavoidable and time-dependent process which occurs in denture-wearing patients especially those who use mandibular dentures. This process causes more problems in mandible because of its less support, tongue forces and more resorption. Inserting implants in many of these patients requires bone grafts. Overdentures are also more expensive. Denture adhesives are the last option to improve retention and masticatory function in denture-wearers with severe resorption of alveolar ridge. Nowadays only a few denture adhesives are used in Iran and there is not much information about their standard features including, pH, bond strength and washability. The objective of this study was to examine and compare the mentioned characteristics of four denture adhesives (Professional, Corega, Fittydent and Fixodent) and to introduce the most suitable denture adhesive for clinical use.

Materials and Methods: All the methodologies of ISO 10873:2010 were applied. To measure the pH value, 1±0.1g of each denture adhesive was diluted with 5g of propylene glycol and mixed with water. Using pH meter, pH of each group was measured separately for 4 times (n=4) and results were recorded. For the washability test, 4 dentures were fabricated (n=4) and each group of denture adhesives was placed on a denture according to manufacture instructions. For simulating mouth environment specimens were placed in water at 37±2 ̊C bath for 1 hour and then washed with a plastic brush. Specimens were examined for any residual adhesive and the results were recorded. For bond strength test, a sample holder was gently filled with denture adhesives and was attached to the holding arm of bond strength testing device (Santam, STM 20, Iran). Specimens were placed in 300ml water bath at 37±2 ̊C for 10 minutes, and then shaken to be dried and placed in the bond strength testing device. 10N force with 5mm/min rate was applied to the specimen. The force was maintained for 30s and then device arm was pulled back and the highest number was recorded with computer software (Santam Machine Controller v4.19, Iran). The test performed 8 times (n=8) for each adhesive and 8 results were recorded. Data were analyzed using ANOVA test for comparing the bond strength with a significant level fixed
at 0.05.

Results: Professional and Corega adhesives had more neutral pH than that of Fittydent and Fixodent which were more acidic. Washability test showed no remaining mass of any adhesive and there was not any statistically significant difference between groups (P>0.05). Fittydent and Corega adhesives showed higher bond strength than that of Professional and Fixodent and this difference was statistically significant (P<0.05).

Conclusion: Professional and Corega adhesives had less acidity. Thus they cause less harmful effects on the oral mucosa than that of Fittydent and Fixodent and should be indicated in patients with little-tolerant oral mucousa such as diabetous, iron-deficiency anemia and hypertention. All the groups had acceptable washability. Fittydent and Corega had higher bond strength than that of Professional and Fixodent. Therefore in complete-denture-wearers who require more retention as a result of severe ridge resorption, macrotruma, and maladaptiivity, Fittydent and Corega seems to be more acceptable.


Reza Masaeli, Tahereh Sadat Jafarzadeh Kashi, Farhad Shafiei,
Volume 28, Issue 3 (10-2015)
Abstract

Poly (lactic-co-glycolic acid) is a biodegradable polymer which has used in a different fields of medical applications. As PLGA is approved by FDA(food and drug administration) the range of this usage is increasing in comparison to the past. Particularly, PLGA are also developed for the dental field in the form of scaffolds, films, membranes, microparticles, or nanoparticles. PLGA scaffolds have been used to regenerate damaged tissues together with stem cell-based therapy. There is solid evidence thatthe development of PLGA microparticles and nanoparticles may be beneficial to a wide range of dental fields such as endodontic therapy, dental caries, dental surgery, dental implants, or periodontology. The aim of the current paper was to review the recent advances in PLGA materials and their potential uses in Dentistry via exploring related literature during 2004 till 2016 in Science Direct and PubMed.


Mehrsima Ghavami-Lahiji, Marjan Behroozibakhsh, Tahere Sadat Jafarzadeh Kashi,
Volume 30, Issue 4 (1-2018)
Abstract

FTIR spectroscopic imaging is a chemical imaging method that can be employed to a broad range of applications. This powerful technique is suitable for determining the functional groups and chemical structures of the samples. The advantage of infra-red spectroscopy is that it can be used for various modes of physical samples. The aim of the current paper was to review the recent advances and the potential uses of Fourier Transform Infra-red Spectroscopy in dentistry via exploring related literature during 1960 till 2017 in Science Direct and PubMed databases. One of the most popular applications of infrared spectroscopy is to calculate the degree of conversion in the resin based dental materials. It has also been used to investigate the chemical structure of the teeth and bones, synthesis calcium phosphate, the diagnosis of microorganisms, and pathological conditions. In this paper, we mentioned the principles of this technique and recommend this method as a simple and fast way to determine the structure of the materials and their alteration.


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