Showing 2 results for Khoshakhlagh
Amir Hossein Khoshakhlagh, Farideh Golbabaei, Mojtaba Beygzadeh, Seyed Jamaleddin Shahtaheri,
Volume 11, Issue 4 (12-2021)
Abstract
Introduction: Toluene is considered as a group of chemical contaminants, causing problems for people’s health. Due to the high rate of evaporation and rapid emission in the surrounding environment, it leads to the exposure of many employees and people at risk and, subsequently, its irreparable effects on their health in different jobs. Therefore, its removal is very important. In the present study, this contaminant was removed using the copper metal-organic framework (MOF) under different operating conditions.
Material and Methods: In this study, the copper MOF was synthesized using the one-pot and in situ method. Physical and morphological properties of the adsorbent were investigated using BET, XRD, FTIR and SEM techniques. The efficiency of the adsorbent in removing toluene from the air stream under the dynamic adsorption system was investigated by examining the effect of the variables of adsorbent mass, pollutant concentration and humidity. Isotherm, thermodynamics and kinetics equations were used to evaluate the data.
Results: The results of experiments determining the properties of the metal-organic framework showed the formation of pure Cu-BDC crystals with mean and particle size distribution of 1.95 nm. The specific surface area calculated by the BET method for the mentioned sample was 686 m2 g-1 and the total volume of structural pores was 0.335 g3 cm3. The presence of micropores increased the dynamic adsorption capacity of toluene. The findings follow the Langmuir isotherm model and the Pseudo-second order kinetic model. Based on the results of thermodynamic studies, entropy change (ΔS°) and enthalpy change (ΔH°) were equal to -0.44 kJ mol-1 K-1 and -15.67 kJ mol-1, respectively. Gibbs free energy change (ΔG°) was also calculated negatively, indicating that the adsorption process was spontaneous and exothermic. The regeneration of the adsorbent was 77% after three cycles.
Conclusion: According to the results of this study, the microporous copper MOF can be used as a result of cheapness, high access, high adsorption capacity and appropriate regeneration rate in different operating conditions for adsorption of toluene.
Saeid Yazdanirad, Farideh Golbabaei, Amir Hossein Khoshakhlagh, Vali Sarsangi, Mehdi Yaseri, Seyed Mahdi Mousavi,
Volume 12, Issue 1 (3-2022)
Abstract
Introduction: Prevention of heat-related diseases requires the participation of the workers. For this reason, the aim of this study was the development and validation of the tools for evaluating awareness and practice related to heat stress among the workers of warm workplaces.
Material and Methods: The various items and factors related to the awareness and practice of the workers were identified by the literature review. Then, several questions for evaluating these items were designed. In the next step, the reliability and validity of the questionnaires were appraised using calculating the content validity ratio (CVR) and content validity index (CVI), and Cronbach’s alpha coefficient, respectively. After that, these questionnaires were completed by 2338 employees of six industries in various regions of Iran. Finally, collected data were analyzed using SPSS software.
Results: In total, 77 questions, including 53 questions on awareness and 24 questions on practice in six groups of water and beverages, food, snacks and additives, heat exchange, thermal strain risk factors, clothing and heat protection equipment, and heat-related disorders and body reactions, were designed. The values of content validity index (CVI) of remained questions in the questionnaires of awareness and practice were equal to 0.954 and 0.824, respectively. The values of Cronbach’s alpha coefficients of these questionnaires were calculated by 0.755 and 0.716, respectively. The values of the chi-square divided by degrees of freedom (CMIN/DF) and root mean square error of approximation (RMSEA) in the construction of the awareness questionnaire were computed as 4.58 and 0.079, respectively. These values in the construction of the practice questionnaire were calculated by 2.33 and 0.084, respectively.
Conclusion: The results showed that the designed questionnaires had appropriate reliability and validity and could be used to evaluate the awareness and practice in warm workplaces.
