Journal of Health and Safety at Work

---

Introduction: Heat stress is one of the Hazardous physical agents in the workplace, which can cause impairment of cognitive performance. The current study aimed to evaluate the effect of different levels of heat stress on attention and reaction time in a laboratory condition.

Material and Method: This experimental study was done among 33 students included 17 males and 16 females. Mean age of the participants was 22.1(SD=2.3). Attention and reaction time parameters were evaluated using the continuous performance test and  reaction time measurement device respectivlely, after exposure to different heat levels (22°C and 37°C). Data were analyzed using ANOVA test and SPSS 20 software.  

Result: The results of tests attention and reaction time showed that the average of attention percentage was decreased and the average of reaction time increased by increasing the heat level, with a  statistical differences of  (P˂0.001) in both cases. Attention percent in terms of exposure to 22°C temperature was significantly higher than 37°C (P˂0.001). But, reaction time was significantly higher than with the exposure to 37°C temperature than 22°C (P˂0.001).

Conclusion: The results of this study showed that, heat by increasing reaction time and decreasing attention leading to an impairment  in the individual’s cognitive performances. Therefore, in jobs such as control rooms and various industries that need attention, concentration and quick reaction, it is necessary to consider and optimize the heat conditions in order to increase the level of attention and decrease of reaction time.

---

Introduction: Despite the ongoing efforts to reduce human errors in various systems, errors and unsafe behavior are the main cause of accidents in the workplace. Many studies have been conducted to identify and improve human error in recent years. The number of studies about the human error with the variety of topics has made it an overall overview difficult for researchers. Therefore, a systematic review of previous studies can be the best way to share useful findings and make a trend for the future research in the field of human error.

Material and Method: After a systematic search of valid databases, the analysis was focused on the title, publication year, journal title / Congress, city/region, the level of organization, job search, type of organization and the methods used. And articles were evaluated based encryption.

Result: Three groups of human error studies were identified. The first group studies in safety management, safety assessment, and safety planning have investigated the human error. The second group has examined the influence of individual characteristics such as behavior, cognition, and education on human error. The third group has focused on data arise from the previous accident to improve behavior and reduce human error. To make a better orientation for next studies two essential aspects included chronological analysis and thematic analysis was considered.

Conclusion: This study made an attempt to identify the gaps in the studies related to human error and afford some appropriate strategies.

---

Introduction: Electrospun nanofibers are suitable option to synthesize filtering mats for nanoparticles. This study was aimed to fabricate polyurethane nanofiber mats through electrospinning process and to investigate the effect of different parameters such as packing density, face velocity and particle type on the filtration efficiency and quality factor of electrospun polyurethane nanofiber mats.
 

Material and Method: The nanofiber mats were produced by electrospinning  process. Polyurethane granules were dissolved (15w/w%) in a solvent system consisting of dimethylformamide and tetrahydrofuran (3:2). Then, the filtration performance testing system was made at the Fluid Mechanics Department of Hanyang University of South Korea and the filtration efficiency and pressure drop of prepared nanofiber mats were studied.
 

Result: Findings showed that by increasing the duration of electrospinning, the basis weight, thickness, packing density, initial pressure drop and filtration efficiency of the mats increased, and the quality factor of the mats decreased due to the increase of the pressure drop. The increase in electrospinning duration from 15 to 45 minutes was led to the increase in pressure drop from 7 to 32 Pa and the average filtration efficiency was increased about 9-10% for KCl and DEHS test particles. The filtration efficiency and quality factor of the prepared polyurethane nanofiber mats were declined with the increase of filtration face velocity from 2 to 5 and 10 cm/s. The reduction in filtration efficiency was more obvious for particles smaller than 425 nm.
 

Conclusion: The results demonstrated that prepared polyurethan naofiber mats provide acceptable filtration performance. What is more, such nanofiber mats can have other potential benefits such as light basis weight, low thickness and simple production.

---

Introduction: Adverse effects of volatile organic compounds (VOCs) including general and specific effects like carcinogenic of benzene are well known. The aim of this study was to evaluate occupational exposure to BTEX compounds in the painting unit of an automotive industry and subsequently health risk assessment of exposure to these compounds.

Material and Method: This cross-sectional study was conducted in the paint unit of an automotive industry including painting cabin, pre-painting salon and painting salon sections. After analyzing samples, gathered from different sections, by GC-MS, BTEX compound were identified as the main contaminants. In the next step, NIOSH1501 and EPA methods were used to measure and analysis of BTEX and risk assessment, respectively.

Result: Findings showed that benzene concentration in painting cabin was higher than occupational exposure limits provided by the Environmental and Occupational Health Center of Iran. Life time cancer risk for benzene per 1000 has been reported10, 3.63 and 1.27in the painting cabin, pre-painting and salon sections, respectively. It was also for ethyl benzene 2.5m 1.8 and 38.0 in the mentioned sections, respectively. The non-cancer risk for benzene and xylene in the painting cabin and pre-painting sections were higher than recommended allowable level.

Conclusion: Regarding the high level of cancer risk values obtained for benzene and ethylbenzene in the studied units and also high values of non-cancer risk for benzene and xylene, it is recommended to conduct biological exposure assessmnet of the workers and improve existence control systems using modern engineering control systems.

---

Introduction: Heat stress is one of the hazardous agents in the steel industries which can threaten the health and safety of workers and lead to serious occupational diseases. The aim of the study was to assess the heat stress in the steel industries and compare PHS (Physiological Strain Index), WBGT (Wet-Bulb Globe Temperature), DI (Discomfort Index) and HSI (Heat Stress Index) indices for the estimation of heat stress and to determine the optimum index for steel industries.
 

Material and Method: This descriptive-analytic study was conducted among 220 workers engaged in two steel industries in Iran. Environmental and physiological parameters were measured according to ISO 7726 and ISO 9886 in three times of measurement, and finally the time-weight average of the heat stress indices were calculated. All data were analyzed using SPSS ver.  20.
 

Result: The time-weight average of WBGT (28.28 oC), DI (29.11 oC), HIS (65.7 %) indices were higher than the recommended limits. Physiological parameters (oral, tympanic and skin temperatures, systolic and diastolic pressures and heart rate) had the greatest value in the second time of measurement (afternoon). WBGT index comparing to the PHS, DI and HSI indices had highest correlation with oral, tympanic and skin temperatures and heartbeat (r=0.314 , 0.408 , 0.459 , 0.302, respectively; P < 0.05), while systolic and diastolic blood pressures showed no significant correlation with WBGT (P > 0.05). The WBGT index had the highest correlation with studied indices which was 0.945, 0.681 and 0.600 for DI, PHS and HSI, respectively.
 

Conclusion: This study assessed the optimal index with regard to the physiological parameters, and it was concluded that the WBGT index has the highest correlation with the most of physiological parameters, and therefore, WBGT index can be the most optimum index to heat stress assessment   in the studied steal industries.

---

Introduction: Being aware of the explosion, fire radius, and their damages, has an important role in accident prevention methods. Therefore, the aim of this study was modeling and evaluation of the consequences of propylene oxide spill in a petrochemical company.
 

Material and Method: The QRA method including seven steps was used in this study. In the present study, in order to examine and modeling of the propagation propylene oxide, first a familiarization with the process information of the unit was done then, a risk assessment was carried out adopting HAZOP technique to identify existing hazards. Consequence analysis in a process unit includes: selecting important scenarios, characterizing scenario, modeling the consequences of scenarios, analyzing the results and determining the percentage of mortality. PHAST software version 6.51 was used for modeling of outcomes and assessment propylene leak.
 

Result: urves of the firing zones of sudden release of propylene oxide showed that the influence puts are included up to radius of 0.15 meters in the scenario of leakage 5 mm, in scenarios with leaks 25 mm to a radius of 1.1 meters and in scenarios with leakage of 100 mm to a radius of 39 meters. The maximum intensity of flash fire in the initial point Scenario 5 mm was 4.2 kW/m2, in the scenario of radiation leakage was 25 mm at the distance to 5 meters from the fire intensity up to maximum of 9 kW/m2, and also in the scenario with 100 mm flash fire radiation leak at an earlier point fire was 14 kW/m2. The maximum intensity of thermal radiation at the distance to 5 meters up to 16.5 kW/m2, and maximum distance of 80 meters around the reservoir affected. The mortality rate of flash fire has exposed employees, was 50 percent.
 

Conclusion: Many accidents caused by leakage and explosion were due to corrosion, spoil tanks and equipment, and the majority of such accidents can be prevented by technical inspections and continuous audits.

---

Introduction: Indoor air environments contain a wide variety of microorganisms such as bacteria, fungi, and viruses in which some of them can affect the human health. Filtration is considered as one of the most common methods to remove microorganisms in these environments. The purpose of current study was to investigation the neat and photocatalytic HEPA filters performance at different face velocities and various intensity of UVC light source on the reduction of airborne microorganisms.

Material and Method: After installation of the neat and photocatalytic HEPA filters in a closed–loop chamber, suspension of Staphylococcus epidermidis and Bacillus subtilis bacteria with a concentration of 107 CFU / ml were sprayed into the closed–loop chamber by nebulizer. Sampling of penetrated microorganisms from filters were performed using the NIOSH 0800 method under ambient temperature 22±3oC, relative humidity 35±5%, and different air velocity (0.1 m/s and 0.3 m/s) and UVC different radiation intensity (1 mW/cm2, 1.8 mW/cm2 and no radiation (dark)) at 30 minutes time period. penetrated microorganisms density from filters was determined in term of CFU/m3.

Result: There were no significant differences in the penetration rates of microorganisms at the dark mode between the two neat and photocatalytic HEPA filters (p>0.05). The penetration rate of bacteria was significantly decreased in the neat and photocatalytic HEPA filters at UVC radiation mode with various intensities than dark mode (p<0.05). In addition, comparison of the filters in the illuminance modes of 1 mW/cm2 and 1.8 mW/cm2 were statistically significant (P <0.05). Also, UVC radiation with the 1.8mW/cm2 illuminance compared to the 1 mW/cm2 illuminance resulted in a greater reduction in the bacterial penetration from both types of filters, which is statistically significant(p<0.05). The bacteria penetration rate dramatically increased by increasing the face velocity from 0.1 m/s to 0.3 m/s under UVC radiation at an illuminance of 1mW/cm2, 1.8mW/cm2 and as well as in no radiation mode in both types of HEPA filters (P <0.05).

Conclusion: Photocatalytic HEPA filters and increasing UVC illuminance, especially at lower surface velocities, have a significant positive effect on reducing airborne microorganisms and increasing the efficiency of HEPA filters

---

Introduction: Workers in steel manufacturing companies are extensively exposed to the volatile organic compounds (VOCs). Considering the health effects of these compounds, the purpose of this study was to determine occupational exposure to the BTEX compounds and also evaluation of carcinogenic risk due to benzene and non- carcinogenic risk for BTEX compounds in a steel industry.

Material and Method: This cross-sectional study was conducted in the coke production unit of the steel making industry. After collecting personal samples from breathing zone of the workers and analyzing of the samples the levels of exposure to the BTEX were quantitatively determined using Gas chromatography equipped with Flame Ionization Detector (GC-FID), according to the NIOSH 1501 standard method. Then, cancer risk due to benzene and non-cancer risks from BTEX compounds were calculated using Monte-Carlo technique.

Result: The analysis of personal samples indicated that benzene concentration in energy and biochemistry and benzol refinement sections of the plant were higher than occupational exposure limits (OELs). Among the studied sections, benzol refinement as the most polluted section had the highest concentration of BTEX compounds. Non-cancer risk due to BTEX compounds in all studied sections was lower than one. Benzene cancer risk in energy and biochemistry, benzol refinement and experimental furnace sections was higher than maximum recommended value by EPA.

Conclusion: Due to the high concentration of benzene in energy and biochemistry and benzene refinement sections as well as the resultant carcinogenic risk, improvement of existing control systems and the use of modern engineering systems are necessary to control occupational exposure.

---

Introduction: Nowadays, millions of people are exposed to the dusts in their workplaces. Occupational exposure to dusts is considered as one of the most common and serious occupational hazards to workers’ health. The purpose of this literature review was to review the literature related to the occupational exposure to dusts in Iran published over the past 14 years.  
Material and Methods: In this review, published articles were obtained from Web of Science, PubMed, Google Scholar, Scopus, ScienceDirect, Islamic World Sciences Citation (ISC), Magiran, SID، Iran Medex, and Civilica search engine. The main keywords for search were Occupational Exposure, Lung, Dust, Total Dust, and Respirable Dust. The relevant articles published in Iran over the past 14 years were searched and extracted after checking their relevancy. All articles were classified based on the titles, years of publication, places of publication, type of industries, geographic distributions, sampling and analysis methods, fields of study, and the amounts of exposure.
Results: Findings showed that in spite of increases in the rate of published literature in recent years and by considering geographical variation and the large number of dust generating firms and industries, a relatively small number of studies was conducted and published in this field. Majority of the studies in this field considered the levels of dust exposure and respiratory effects of dust exposures.  In most studies the levels of occupational exposure to dusts (and crystalline silica dusts) were higher than the recommended limit values.
Conclusion: Although an increasing number of studies can be seen in recent years on occupational exposure to dusts and their effect, by considering the presence of large and small size industries with dust generating pollution  in Iran, the large number of exposed people, adverse-health  effects,  and  the need for control measures, few studies have been published in this field and further works need to be done in this area.

---

Introduction: Exposure to organic solvents cause adverse effects on various systems such as the central nervous system, behavioral and cognitive changes, sleep disorders, as well as changes in mood. This study was aimed to evaluate the effect of long term exposure to mixed organic solvents on positive and negative aspects of the mood of the workers of a painting industry.  
Material and Methods: In this cross-sectional study, based on the obtained results of Gas chromatography–mass spectrometry (GC-MS) analysis and neuro-behavioral effects of benzene, toluene, ethylbenzene and xylene (BTEX) compounds, these compounds were selected as the main organic solvents for the study and the amount of these compounds was quantitatively determined according to the National Institute for Occupational Safety and Health (NIOSH) 1501. Furthermore, the mood status of workers was evaluated by the validated Persian version of BRUMS (The Brunel Mood Scale) questionnaire and the obtained data were analyzed using SPSS software, version 24.
Results: The mean of exposure to mixed organic solvents in different sections of the exposed group was reported to be 0, 0.27, 0.76, and 2.6 ppm. By increasing exposure to mixed organic solvents from the first quartile to the fourth quartile, fatigue and calmness scores were increased with a strong correlation (r = 0.7). Also the fatigue and calmness scores in the groups having elevated exposure were significantly higher than the control group. Furthermore, the obtained scores for tension, depression and anger in the exposed group were significantly higher than control group (p- value <0.05). There was no significant relationship between demographic data such as age, work experience and smoking with different subscale of mood status.
Conclusion: Long term exposure to low level of BTEX compounds has made an adverse effect on positive and negative mood status in different aspects. Also, increasing the level of exposure to mixed organic solvents was positively correlated to the obtained scores for fatigue and calmness.

---

Introduction: Despite nanofibers have attracted great interests for filtering particulate matters from the air stream, fewer studies have been done on the feasibility of their use in the removal of gas pollutants, while the both pollutants are present in the most workplaces. Toluene is a toxic and mutagenic substance, and chronic exposure to its low levels can lead to a wide range of adverse health effects on people who exposed. The purpose of this study was to produce polymer /single-walled carbon nanotube hybrid nanofibers by electrospinning technique and doing plasma surface treatment and evaluating their removal efficiency of toluene from air stream.  
Material and Methods: The nanofiber layers were fabricated by electrospinning solution containing polyacrylonitrile polymer (PAN) and single-walled carbon nanotube (SWNT) with a 99: 1 ratio under following conditions: applied voltage 20 kV, distance between needle and collector: 10 cm, injection rate: 1 ml / h; needle diameter: 18 gauge and drum speed ranging from 1000 to 500 rpm. The surface of the manufactured nanofibers was treated by cold-plasma with a radio frequency power supply (13.56 MHz with a power of 20 watts), argon gas and operating pressure of 0.2 torr. Test conditions was prepared according to standard ISO 10121-1: 2014, which provides a method for testing the performance of gas-phase air filter for a variety of flat sheet media. In order to measure the concentration of toluene, the First check – handheld multi gas VOC detector equipped with a PID detector was used. The morphology characteristics of the fibers was performed using the analysis of scanning electron microscope images. Infrared spectroscopy-Fourier transform was used to identify organic compounds and functional groups in nanofibers.
Results: The results of the analysis of the images showed that the mean diameter of the fiber was 169.16 ± 7.19 nm and the mean coefficient of variation was 0.23. The uniform and bead nanofibers were obtained. The thickness, porosity and air permeability coefficient of test media was 0.15 mm, 43% and 5.75 Darcy, respectively. The mean removal efficiency of PAN / SWNT nanofiber treated with plasma was 98% and the mean pressure drop was 100 Pascal. The FTIR spectrum of the test filter media showed that the peaks appearing at certain wavelengths related to the vibration of C-H aliphatic groups of C-C and C=O bands related to PAN polymer and carbon nanotubes.
Conclusion: Removal of toluene was achieved through the fabrication of PAN/SWNT hybrid nanofibers treated with plasma. Uniform nanofibers were obtained and showed the proper removal efficiency and low pressure drop.

---

---

Introduction: Determining methods for assessing heat stress in different work environments is one of the major challenges for researchers in this field. The purpose of this study was to validate WBGT index and heat pressure assessment (HPA) by some physiological responses in Iranian South Oil Company.
Material and Methods: This descriptive-analytical study was carried out on 154 employees of Kharg, Asalouyeh and Mahshahr oil terminals recruited from three different working conditions including indoor, outdoor and rest environments in the summer. The amount of heat stress in the workplace was evaluated by WBGT index HPA method. To meet this purpose, the environmental parameters i.e., temperature, wet temperature, radiation temperature, relative humidity, water vapor pressure and air flow rate were determined. In addition to the direct reading method by the WBGT meter, ISO 7243 was used to calculate the WBGT index. In order to validate the heat stress indicators, physiological parameters of oral temperature, tympanic temperature and work metabolism were measured.
Results: The results of paired sample t-test showed a significant difference between WBGT index and HPA in indoor and outdoor environment (P<0.05). Moreover, there was a significant difference between the physiological indices of oral and tympanic temperatures and work metabolism in the indoor and outdoor environment (P<0.05). Furthermore, the correlation test was significant between WBGT index as an independent variable and HPA as a dependent variable (P<0.05)  and showed a high correlation (R2=0.914) between WBGT index with oral temperature and tympanic temperature . Also, the rate of work metabolism was significantly related with the aforementioned parameters (P<0.05) and was equal to R2=0.423, R2=0.335, R2=0.552, respectively. The correlations were also significant between HPA with Oral temperature, tympanic temperature and work metabolism (P<0.05)and were equal to R2=0.632, R2=0.605, R2=0.557, respectively. The results showed also that the correlation rate between the HPA with physiological parameters is stronger than that between physiological parameters with the WBGT index.
Conclusion: This study showed that WBGT and HPA methods are useful for assessing the heat stress of Iranian South Oil Company. Also, the HPA method is more reliable for assessing heat stress in these regions.

---

Introduction: In recent years tend to use of natural fibers has increased in making sound absorbers. Fiber-based natural materials have low density, low production costs, and are biodegradable.
Material and Methods: In this study, the effect of nanoclay and the behavior of the nanocomposite specimens containing tea waste, polypropylene, and nanoclay in the sound absorption coefficient are investigated. 
Results: The results showed the sound absorption coefficient increases by increasing the tea waste weight percent of the polypropylene. 60% increase in tea waste has a special role in the absorption of sound waves at a frequency of 1000 Hz and 2500 to 6300 Hz frequency range as the TW60 N5 sample has the sound absorption coefficient 0.94 and 0.84 in 1000 and 6300 Hz frequencies, respectively. Comparison of the sound absorption coefficient of composite and nanocomposite showed that sound absorptions increase by adding nanoclay to the 5%, at frequencies above 2000 Hz.
Conclusion: Tea waste-based sound absorbers can be used in noise control due to the high acoustic absorption and no harmful effects on human health.

---

Introduction: Studies show that in many cases, environmental hazardous agents such as heat, noise, as well as chemical pollutants cause adverse health effects through the mechanism of oxidative stress. This study has examined the effect of exposure to noise and whole-body vibration (WBV) on some parameters of oxidative stress (enzyme superoxide dismutase (SOD), total antioxidant capacity (TAC), and malondialdehyde (MDA)) of workers in a foundry industry.
Material and Methods: The workers were selected based on the calculations related to the sample size and taking into account the inclusion criteria as well as completing the informed consent form. The level of exposure to noise and WBV was measured according to ISO 9612 and ISO 2631, respectively. For each worker, the time-weighted average was calculated. The level of exposure of workers to the studied stressors was divided into three categories: low, medium, and high. The blood samples were taken from all participants between 7-9 am. Then, via ELISA method according to the protocol of the kit manufacturer, the samples were prepared and analyzed. Univariate analysis of variance was performed to determine the “effect size” of each physical stressors on the studied parameters.
Results: The mean levels of MDA, SOD, and TAC among participants were 22.48 (11.19) nmol / ml, 61.28 (10.97) U / ml, and 1.64 (0.90) mM, respectively. Among the exposure variables, noise had the largest effect on MDA level (B = 0.090), which was not statistically significant (P = 0.865). WBV had the largest effect on SOD level (B = -1.469) which was statistically significant (P = 0.016). None of the studied variables had a significant effect on the TAC level; however, among the exposure variables, the greatest effect was related to WBV (B = -0.077; P = 0.133).
Conclusion: The effect of noise on oxidative stress parameters was not statistically significant. The effect of whole-body vibration on oxidative stress parameters except SOD was not statistically significant. Noise and WBV had increasing effect on MDA and decreasing one on SOD and TAC levels.

---

Introduction: Due to uncertainties regarding the risks of engineered nanomaterials for human health and the environment, different organizations and researchers have developed various management frameworks and assessment tools to mitigate hazards during the procedures and applications of engineered nanomaterials. However, most of these techniques do not meet all the individual requirements. This study provides a review and introduction to the techniques developed for the management of safety, health, and environmental risks associated with engineered nanomaterials.
Material and Methods: In order to find pertinent documents on the safe handling of engineered nanomaterials, a search was conducted using the following keywords: “Engineered nanomaterials”, “Framework”, “Tool”, “Risk management”, “Occupational exposure”, “Environment”, “Risk assessment”, and “Nanotechnology”. The search was conducted on various databases, including Scopus, Web of Science, NIOSH, ECHA, and ISO. Among the search results, tools and frameworks that specifically focus on the safety, health, and environmental risk management or assessment of engineered nanomaterials were selected.
Results: Among the search results, 17 frameworks and 11 developments in the field of managing occupational, environmental, and toxicological risks associated with engineered nanomaterials were discussed. Various frameworks and tools for identifying, evaluating, and managing the potential risks of engineered nanomaterials vary in terms of their scope, goals, risk assessment approaches, and output, offering diverse applications.
Conclusion: Various tools and frameworks, each with unique properties, applications, and limitations, can assist organizations in achieving their goals related to safety, health, and environmental issues in the field of nanotechnology. Currently, there is no consensus on the optimal approach for assessing the risks of nanomaterials, underscoring the necessity for additional research, development, and collaboration in this field.
 

---

Introduction: Wearable thermal management systems and phase change materials (PCMs) have emerged as effective solutions for regulating body temperature and storing thermal energy. This study focuses on synthesizing and thermal optimizing a sodium sulfate decahydrate-based nanocomposite incorporating various nanoparticles to improve its performance for personal thermal regulation applications.
Material and Methods: The composite was prepared using sodium sulfate decahydrate as the base PCM. Potassium chloride (KCl) was added to adjust the melting point, borax (STD) served as a nucleating agent, and sodium polyacrylate (SPA) was included as a thickening agent to suppress phase separation. To evaluate the effect of nanoparticle additives, 0.05 wt.% of aluminum oxide (Al₂O₃), iron oxide (Fe₂O₃), graphene oxide (GO), and titanium dioxide (TiO₂) were separately incorporated into the base formulation. A field emission scanning electron microscope (FESEM) was used to analyze the surface morphology of the resulting nanocomposites. Differential scanning calorimetry (DSC) assessed thermal properties, including phase transition temperatures (melting and freezing points) and latent heat.
Results: Differential scanning calorimetry (DSC) analysis indicated that sample S-5-5 comprising sodium sulfate decahydrate with 3 wt.% KCl, 5 wt.% STD and SPA exhibited a melting temperature of 29.5 °C and a latent heat of 120 J/g. This composition remained stable without phase separation. The incorporation of nanoparticles raised the melting point of the base PCM by 0.6 to 1.72 °C. Aluminum oxide (Al₂O₃) and iron oxide (Fe₂O₃) reduced the latent heat of fusion, whereas GO and TiO₂ increased it.
Conclusion: These findings confirm that the thermal properties of sodium sulfate decahydrate-based PCMs can be tailored by including specific additives and nanoparticles. Hydrated salt nanocomposites demonstrate strong potential as PCMs for wearable body temperature regulation.

---

Introduction: Nanomaterials are widely applied across diverse scientific and industrial sectors; however, their emergence has introduced a new generation of occupational hazards for workers. Concurrent with discussions on the adverse effects of nanomaterials on human health, researchers have sought to develop methods for assessing occupational risks associated with these materials. Accordingly, this study aims to propose a general framework for the development of such methods.
Material and Methods: This is a critical analysis study designed to evaluate existing methods for assessing occupational risks related to nanomaterials and ultimately propose a modified framework for refining these methods. By examining current approaches and identifying their strengths and weaknesses, the authors have proposed an improved framework for occupational risk assessment of nanomaterials.
Results: The proposed framework is based on two key dimensions: “Severity/Hazard” and “Probability/Exposure.” The first dimension determines the potential risk level arising from exposure to nanomaterials, with the most critical factors being the intrinsic properties and toxicology of the nanomaterial itself, parent materials, and similar substances. The second dimension describes the likelihood and nature of exposure to nanomaterials during work activities, with the most influential factors being worker, job tasks, and workplace environment characteristics.
Conclusion: The lack of sufficient data and numerous uncertainties regarding bio-nano interactions make quantitative risk assessment (the traditional occupational health approach) difficult, less reliable, and in some cases unfeasible for nanomaterials—given current knowledge. Qualitative and semi-quantitative approaches, such as Control Banding, despite demonstrating positive aspects, have faced significant criticism. The framework-based method proposed herein appears capable of partially overcoming these challenges.

---

Introduction: With the advancement of industries and increased use of metalworking fluids, controlling pollutants generated by machining operations has become increasingly challenging. This study aimed to address these challenges by designing an air filtration system designed specifically for this purpose.
Material and Methods: A local exhaust ventilation system was developed based on the VS-80-12 ACGIH standard, tailored to the working conditions and air sampling of the environment. The filtration system includes an aluminum pre-filter, an E11 class filter, and a nanofiber filter incorporating a metal-organic framework. The performance of the system was evaluated by measuring the numerical concentration of particles and the mass concentration of oil mist at both the inlet and outlet. The results were then compared to those obtained from an E1 class filter.
Results: The results obtained from XRD and FTIR analyses showed that ZIF-8 had high crystallinity and was successfully incorporated into the structure of the fibrous media filter containing metal-organic framework. The evaluation revealed that the filtration system effectively removed pollutant particles at their source. Notably, the initial efficiency for larger particles reached 100%, while the average removal efficiency for particles smaller than 2.5 microns was 99%.  
Conclusion: In conclusion, the combination of nanofiber filters with a metal-organic framework and aluminum pre-filters presents an effective solution for controlling particulate pollutants from machining operations. However, further research is necessary to comprehensively assess the system’s performance, particularly regarding dust loading capacity. Future studies should also explore the effects of various factors, such as airflow rate and the type of metalworking fluid, on the system’s efficacy.

---

Introduction: Students play a key role in shaping the future of any society and spend a significant amount of time in educational environments. Creating an optimal learning environment requires close attention to factors affecting student well-being, particularly thermal comfort and indoor air quality. This study aims to systematically review the existing literature on thermal comfort and ventilation systems in schools.
Material and Methods: This systematic review was conducted based on the Cochrane methodology, involving a comprehensive search of three major databases — Scopus, Web of Science, and PubMed — for articles published between 2020 and 2024. The inclusion criteria encompassed peer-reviewed, conference, and review articles published in English that included the keywords “thermal comfort,” “ventilation,” and “school” in their title, abstract, or keywords. Studies focusing on preschools, universities, or other non-primary/secondary educational settings, as well as those conducted during the COVID-19 pandemic, were excluded.
Results: A total of 42 articles were selected after a rigorous screening process. The highest number of publications was reported in 2023. Key findings included: Most studies focused on elementary and secondary schools. The majority of research was conducted during the summer season, which may limit generalizability across seasons. There was considerable variation in CO₂ levels, with some exceeding recommended standards. In simulation studies, DesignBuilder and EnergyPlus were the most frequently used software tools. Additionally, results showed that: Indoor air quality and thermal comfort are significantly influenced by the type of ventilation system. Schools using natural ventilation often experienced higher CO₂ concentrations and lower thermal comfort than recommended. Implementation of Demand-Controlled Ventilation (DCV) has shown promise in improving indoor air quality and reducing pollutant levels.
Conclusion: This paper can contribute to the improvement of educational space design, enhancement of student learning, and promotion of indoor environmental health. It also provides insights into the latest methods for measuring and simulating thermal comfort and indoor air quality. For more practical outcomes, long-term studies with larger sample sizes across different seasons and times of day are needed. Combining computer simulations with real-world measurements can support cost-effective and optimized design of educational spaces. Future research should focus on standardizing temperature, humidity, CO₂ levels, and selecting the most appropriate ventilation strategies for classrooms.