Showing 2 results for H2s
Hojatolla Kakaei, Mojtaba Beygzadeh, Farideh Golbabaei, Mohammad Reza Ganjali, Mehdi Jahangiri, Sayed Jamaleddin Shahtaheri,
Volume 9, Issue 4 (12-2019)
Abstract
Introduction: Hydrogen sulfide is one of the most important impurities in natural gas. Due to the fact that this gas is hazardous, toxic, corrosive and volatile, therefore, the removal of hydrogen sulfide has been studied using several methods. One of the most known procedures is the adsorption process. In the present study, activated carbon and activated carbon-based composite scaffolds (MOF-5) were used as a cartridge mask to remove hydrogen sulfide from respiratory air.
Methods and Materials: First, activated carbon (AC) was converted to powder form by ball mill, and AC / MOF-5 composite with 10%, 25%, and 40% MOF-5 to AC was synthesized from the MOF-5 metal-organic scaffold. Then, the rates of adsorption and breakthrough time using a designed setup were tested in two ranges of temperatures, humidities and concentrations. XRD, SEM and BET were used to determine the properties of composite absorbents. The Aeroqual S500 Direct-reading sensor with 0.01 ppm accuracy was used to measure the exact amount of hydrogen sulfide gas.
Results: The AC/MOF-5 composite showed higher adsorption and breakthrough time compare to the other adsorbents. The Specific surface area (BET), average pore diameter, and total pore volume of the adsorbent were 814 m2 /g, 1.6795 nm, and 0.342 cm3 /g, respectively. The isotherm diagram showed that, according to IUPAC, most of the pore size of this adsorbent was classified in the micro-porous group. The maximum adsorption (mg/gS) and breakthrough time (min) were related to AC/MOF-5(40 Wt. %) adsorbent with 60.41 mg/gS (SD = 1.08) and 56.26 min (SD =2.38) at a temperature of 15 ° C, a concentration of 9.88 ppm (SD = 0.70), a moisture content of 51.06% (SD = 0.15) and a pressure drop of 51.34 mm water. By adding more than 25% MOF-5 metal-metal scaffold to activated carbon, the amount of adsorption, breakthrough time and pressure drop were increased.
Conclusion: AC / MOF-5 composite adsorbent due to its porous structure, high specific surface area, and most importantly, having Zn-O-C groups increased the adsorption rate as well as the pollutant Breakthrough time. However, it showed a relatively higher pressure drop than commercial activated carbon (AC).
Towhid Delshad, Farhad Shahraki, Mohammad Reza Sardashti Birjandi, Bahareh Bidar,
Volume 15, Issue 4 (12-2025)
Abstract
Introduction: Industrial units, such as oil refineries, face significant hazards due to the release of toxic and flammable gases. Hydrogen sulfide (H₂S), due to its high toxicity and environmental impact, is among the most dangerous pollutants. This study aimed to model and assess the consequences of H₂S release in the Sulfur Recovery Unit (SRU) of Abadan Refinery using PHAST software to support safety planning and risk reduction strategies.
Material and Methods: Consequence modeling was conducted using PHAST version 8.4. Process data, including temperature, pressure, flow rate, and feed composition, along with meteorological conditions (average temperature, relative humidity, and wind speed based on Pasquill stability classification), were used to define probable scenarios. Scenarios included partial pipeline rupture, variable leak flow, short pipe release, and catastrophic reactor tank rupture. Key damage criteria, including thermal radiation threshold, explosion overpressure, and toxic dose, were used to determine hazard zones.
Results: Thermal radiation up to 71.027 kW/m² can cause instant death within a 70-meter radius, while overpressure exceeding 0.206 bar can destroy equipment and structures up to 35 meters in summer conditions. The H₂S cloud can spread up to 120 meters downwind, causing immediate fatalities among exposed personnel. These findings identify high-risk zones in and around the SRU, emphasizing the need to relocate shelters, install gas monitoring systems, and provide protective equipment. Results are limited to the defined scenarios and PHAST assumptions.
Conclusion: Due to the lack of risk assessment studies in early phases and during operation, identifying safe points and high-risk zones, along with prioritizing risk reduction, is essential to ensure workplace and public safety. Comprehensive risk assessment, including probability analysis (using software such as SAFETI) and application of advanced models (CFD and AI-based methods), is recommended for future research.
