Showing 9 results for Nanoparticles
M. Osanloo, H. Shirkhanloo, O. Qorban Dadrass,
Volume 4, Issue 1 (5-2014)
Abstract
Introduction: Mercury is one of the toxic metals that damages the nervous system and kidneys. Therefore, monitoring of mercury vapors in the environments is essential.
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Material and Method: A new adsorbent was made from silver nanoparticles on a bed of quartz. The nano-adsorbent was capable for sampling of the trace amounts of mercury vapor from air. In this study, the required mercury vapor was generate by hydride generation atomic absorption spectrometry and the necessary analysis was performed by cold vapor atomic absorption spectrometry.
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Results: Mercury vapors in the Stationary phase, were concentrated as much as 2300 times (Atomic absorption detection limit was 1.15 microgram per liter of air). Thus by this stationary phase, the trace amounts of mercury vapors can be detected up to 0.5 nano gram per liter of air. The detected value of the presented method is 200 times lower than the occupational safety and health administration (OSHA) standards for mercury vapors. Heater accessory at the temperature of 245 °C was used for thermal desorption of mercury from nano silver adsorbent. Optimal time of desorption was obtained 150 seconds and the Repeatability of the method was 58 times. The mercury vapors absorbed on nano silver adsorbent could be maintained at 80 days at the room temperature (25 °C).
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Conclusion: The presented adsorbent is very useful for sampling of the trace amounts of mercury vapors from air. Moreover, it can be regenerated easily is suitable or sampling at 25 to 70 °C. Due to oxidation of silver and reduction in uptake of nanoparticles, oven temperature of 245 °C is used for the recovery of metallic silver. Low amount of adsorbent, high absorbency, high repeatability for sampling, low cost and high accuracy are of the advantages of the presented method.
M. Rashidi , M. Saffari, H. Shirkhanloo, M.r. Avadi,
Volume 5, Issue 4 (12-2015)
Abstract
Introduction: During recent years, carcinogenic effects of X-ray have been proven. Todays, lead is used in many equipment such as coats, thyroid shield, and gloves for body protection against X-ray. However, these equipments have several disadvantegous including toxicity, heaviness, and inflexibility. Hence, newer methods like protective semisolid products (cream, ointment) for topical application are being replaced. Therefore, the feasibility of using an ointment containing bismuth oxide nanoparticles (Bi2O3) as a X-ray adsorbent was evaluated in this study.
Methods and Materials: First, synthesis of Bi2O3 and then formulating it in the form of ointment was investigated. In this study, X-ray device and dosimeter was employed to check the X-ray absorption in different thickness of bismuth oxide nanoparticles ointment.
Results: In dosimetry test, the protective effect of the ointment containing Bi2O3 nanoparticles was evaluated significantly (P<0.05) better than control group and equal sheet lead group. Dosimetry tests showed that the bismuth oxide nanoparticles ointment and cream absorb 56% of the radiation whereas this value is 41% for lead. K absorption edge for bismuth is higher than other metals and its nanoparticles have more absorbent surface to volume ratio (S/V).
Conclusion: It seems that due to higher atomic number and lower toxicity, Bi2O3 nanoparticles have better efficiency in X-ray absorbtion, comparing to the lead. Cream and ointment of bismuth oxide nanoparticles can be used as X-ray absorbant for different professions such as physicians, dentists, radiology experts, and operating room staff and consequently increase health and safety of these employees.
Majid Habibi Mohraz, Farideh Golbabaei, Il Je Yu, Asghar Sedigh Zadeh, Mohammad Ali Mansournia, Somayeh Farhang Dehghan,
Volume 8, Issue 1 (4-2018)
Abstract
Introduction: Electrospun nanofibers are suitable option to synthesize filtering mats for nanoparticles. This study was aimed to fabricate polyurethane nanofiber mats through electrospinning process and to investigate the effect of different parameters such as packing density, face velocity and particle type on the filtration efficiency and quality factor of electrospun polyurethane nanofiber mats.
Material and Method: The nanofiber mats were produced by electrospinning process. Polyurethane granules were dissolved (15w/w%) in a solvent system consisting of dimethylformamide and tetrahydrofuran (3:2). Then, the filtration performance testing system was made at the Fluid Mechanics Department of Hanyang University of South Korea and the filtration efficiency and pressure drop of prepared nanofiber mats were studied.
Result: Findings showed that by increasing the duration of electrospinning, the basis weight, thickness, packing density, initial pressure drop and filtration efficiency of the mats increased, and the quality factor of the mats decreased due to the increase of the pressure drop. The increase in electrospinning duration from 15 to 45 minutes was led to the increase in pressure drop from 7 to 32 Pa and the average filtration efficiency was increased about 9-10% for KCl and DEHS test particles. The filtration efficiency and quality factor of the prepared polyurethane nanofiber mats were declined with the increase of filtration face velocity from 2 to 5 and 10 cm/s. The reduction in filtration efficiency was more obvious for particles smaller than 425 nm.
Conclusion: The results demonstrated that prepared polyurethan naofiber mats provide acceptable filtration performance. What is more, such nanofiber mats can have other potential benefits such as light basis weight, low thickness and simple production.
Hasan Iravani, Mohammad Javad Jafari, Rezvan Zendehdel, Soheila Khodakarim, Athena Rafieepour,
Volume 10, Issue 1 (3-2020)
Abstract
Introduction: Hydrogen sulfide (H2S) is a toxic gas that has adverse effects on human health and equipment. One of the methods for eliminating of H2S gas is the use of adsorbent substrate. In this study, the effect of adding iron oxides including ferric (Fe2O3) and magnetite (Fe3O4) nanoparticles to ZSM-5 zeolite substrate was investigated on the efficiency of H2S elimination from the air stream.
Methods: In this study, Fe2O3 and Fe3O4 nanoparticles were impregnated in ZSM-5 zeolite in two weight ratios of 3% and 5%. The structural properties of the substrate were studied using XRD, BET and SEM. Then, the efficiency of substrate in removing H2S from air was studied while H2S gas was injected in to a pilot setup, in concentrations of 30, 60, 90 and 120 ppm at three bed temperatures of 100, 200 and 300 o C.
Results: The accuracy of combination and the morphology of inoculated zeolite was confirmed using XRD and SEM. The BET test also showed that the loading of iron oxide nanoparticles on the substrate educed the substrate surface area. The results revealed that increasing the percentage of nanoparticles and increasing the temperature from 100 ° C to 300 ° C increase the time of breakthrough point. The maximum adsorption capacity was obtained equal to 44.449 (mgH2S/g zeolite) for ZSM-5/Fe3O4-5% substrate at 120 ppm concentration.
Conclusion: Iron oxide nanoparticles inoculated in ZSM-5 zeolite substrate increase the capability of eliminating of H2S gas at high temperatures and therefore can be used as a suitable method for the elimination of similar pollutants.
Marziye Pirani, Mohammad Raza Monazzam, Seyed Qasem Pourjandaghi,
Volume 11, Issue 1 (3-2021)
Abstract
Introduction: Reducing noise pollution has become an essential issue due to the increase in public concern and also social demands for a better lifestyle. Using sound absorption materials is a preferred method to reduce the noise pollution. Undesirable properties of pure polyurethane such as poor absorption of mechanical energy in narrow frequency ranges can be improved by providing polymeric nanocomposites. The main purpose of this study is to synthesize the polyurethane nanocomposite foams in order to improve its acoustic properties.
Material and Methods: At the first steage, pure polyurethane foam was synthesized using the pre-polymer method. Afterwards, nanocomposite foams were synthesized with different mass fractions of Nano silica. The cellular morphology of prepared nanocomposite foams was investigated by scanning electron microscopy (SEM (.Utilizing a two-microphone impedance tube, sound absorption coefficient (α) was calculated in the frequency ranges of 100 Hz to 1600 Hz in order to investigate the acoustic properties of the new absorbant.
Results: According to the microscopic investigations, morphology of the cells changed after adding silica nanoparticles. Also, the cell sizes were observed to be decreased by increasing the amount of silica nanoparticles. Furthermore, the acoustic analysis of nanocomposite foams indicated that the sound absorption increased by enhancing the load of silica nanoparticles.
Conclusion: In the current study, the effect of silica nanoparticles additive amount on acoustic properties of the polyurethane-based nanocomposite was investigated. Our findings depicted that the polyurethane-based nanocomposites were able to promote the sound absorption coefficient.
Hosseinali Rangkooy, Maryam Mosavi Ghahfarokhi, Behzad Fouladi Dehaghi,
Volume 11, Issue 4 (12-2021)
Abstract
Introduction: Ethylbenzene is a volatile organic compound used in many industries, including oil and gas, oil colored and insecticides. Due to the toxic effects of this chemical substance, control and elimination of this vapor is necessary. Photocatalytic degradation is a possible method to remove organic compounds from air. This study was performed to determine the efficiency of photocatalytic removal of ethylbenzene vapor using ZnO nanoparticles immobilized on modified natural zeolite.
Material and Methods: Natural zeolite was first modified with hydrochloric acid and then with diphenyl dichlorosilane. Next, zinc oxide nanoparticles were stabilized on the zeolites. Dynamic air flow and different concentrations of ethyl benzene (25, 50, 100 and 200 ppm) were produced and the removal efficiency of ethylbenzene vapor was investigated using UV/MZe/ZnO. The temperature and relative humidity were set at 25±2°c and 35%. The surface and volume of the pores of the bed were determined by the BET method and surface structure was determined by Scanning Electron Microscope (SEM) and X-Ray Diffraction (XRD).
Results: Evaluations for BET showed the specific surface areas decreased by increasing the amount of ZnO. XRD analysis and SEM images showed that zeolite structure was stabled and nanoparticles was successfully stabilized on Ze. The results showed that the highest removal efficiency (50.8%) by the process of UV/MZe/ZnO at concentration 25 ppm.
Conclusion: The result of this study showed that the Ze/ZnO catalyst may be an applicable and hopeful method to removal of ethylbenzene from air flow under UV irradiation
Esmaeil Karami, Zahra Goodarzi, Reza Chahardoli, Mahmoud Ghazi Khansari, Mehrafarin Kiani, Seyed Jamaleddin Shahtaheri,
Volume 12, Issue 2 (6-2022)
Abstract
Introduction: Although aluminum oxide nanoparticles (Al2O3-NPs) are the most widely used nanomaterials, limited studies have been reported on their toxicology. Therefore, the present study aimed to investigate the potential toxicity of aluminum oxide (alumina) nanoparticles and the protective role of aqueous extract of wormwood plant on nanomaterial-induced disorders in the lung of rats.
Material and Methods: Here, 36 male Wistar rats were randomly divided into six groups. Next, the rats were first exposed to 200 mg/kg of the aqueous extract of wormwood plant (by gavage) for 15 days and then received a dose of 30 mg/kg of aluminum oxide nanoparticles as an intraperitoneal injection for 14 days. Furthermore, various features of clinical signs, body weight, biochemical parameters, gene expression changes, lung weight ratio, histopathological observations, and metal content in lung tissue were evaluated during the experiment. Eventually, the ANOVA (Analysis of Variance) and Tukey’s range test were employed to analyze and compare the mean of the data.
Results: The results revealed that aluminum oxide nanoparticles at a concentration of 30 mg/kg body weight led to changes in antioxidant enzyme activities, e.g., T-SOD, CAT, GPx, and TAC, lipid peroxidation, and iNOS for exposed rats. Also, the above biochemical disorders were associated with altered expression of oxidative stress-related genes (HO-1, MT-1) and histological changes in the lung tissue. On the other hand, simultaneous intake of aqueous extract of wormwood plant and aluminum oxide nanoparticles in rats significantly improved the studied parameters (p <0.05).
Conclusion: Our findings showed that the γ-Al2O3 NPs were more toxic than α-Al2O3 NPs, which can be attributed to changes related to their size and shape characteristics. Also, it was observed that the wormwood plant could play a protective role against aluminum oxide nanoparticles-induced pulmonary toxicity in rats.
Gholamreza Moradi, Sana Mohammadi, Abdolrasoul Safaiyan, Saeid Ahmadi, Mehrnia Lak,
Volume 14, Issue 1 (3-2024)
Abstract
Introduction: Disturbing noise can cause physical and mental illnesses among workers; for this reason, it is necessary to restrain it, especially in workplaces. Using sound-absorbing materials with suitable acoustic properties has been a growing trend in mitigating noise. This study aimed to improve the acoustic properties of polyurethane foam (PUF) as a sound absorber.
Material and Methods: In the present study, PUF was synthesized with different percentages of clay nanoparticles (0 -1.2 wt.%), and then the Sound Absorption Coefficient (SAC) of the synthesized PUF was measured by the acoustic impedance tube in the frequency range of 63 to 6400 Hz according to the ISIRI 9803 standard without an air gap behind the sample. The morphology of the foam was also investigated by Scanning Electron Microscope (SEM).
Results: The results showed that the addition of clay nanoparticles to PUF improved the sound absorption behavior of the samples, and the best sound absorption behavior was for PUF with 1.2% weight of nanoparticles at low frequencies (500-2600 Hz). This increase in the absorption coefficient can be due to the increase in the number and smaller size of the pores with the increase in the amount of nanoparticles in PUF.
Conclusion: This study illustrates that the incorporation of clay nanoparticles into PUF at varying percentages results in an enhanced absorption coefficient. The presence of clay nanoparticles leads to a reduction in cell size and an increase in the number of pores, consequently enhancing surface friction. The absorption coefficient was observed to increase with the growing concentration of clay nanoparticles in PUF.
Mahdi Mohammadiyan, Nafiseh Nasirzadeh, Akbar Ahmadi Asour, Sepideh Keyvani, Fatemeh Fasih-Ramandi, Farideh Golbabaei,
Volume 14, Issue 2 (6-2024)
Abstract
Introduction: In recent years, exposure to nanomaterials has been known as a challenge among occupational health experts. In this line, personal protective equipment has been considered as a solution to reduce the worker’s exposure. Since respiratory and skin tracts represent the most common workplace exposure routes, knowledge of the efficiency of respiratory and skin protection equipment is particularly important. So, the aim of this study is the assessment of the efficiency of respiratory and skin protection equipment toward controlling nanoparticles in the workplace with a scoping review approach.
Material and Methods: This study was conducted in 2022 with a scoping review approach. Arksey and O’Malley’s five-step framework was chosen as the research method. The search strategy was followed in the databases necessary to access the research data, including PubMed, Google Scholar, Science Direct, Web of Science, and Scopus. Also, EndNote X9® and Microsoft Excel software were used to collect and analyze studies, respectively.
Results: In the first step, 1014 articles were identified. Finally, 38 articles were included in the study to examine quantitative and qualitative information about the efficiency of respiratory and skin protective equipment. Twenty-five articles were related to breathing masks, and six studies were about protective gloves, and seven other articles were devoted to protective clothing. According to the studies of breathing masks, the mean total penetration of nanoparticles was estimated at 2.27%. Also, based on the studies of protective clothing, the maximum penetration of nanoparticles was 30nm for protective clothing made of polypropylene and polyethylene with different layers.
Conclusion: Although the efficiency of existing personal protective equipment showed a good result for controlling nanoparticles, the size of nanoparticles is one of the essential parameters in determining the efficiency of the equipment, which should be considered the workplaces. So, it is recommended that more studies be considered to improve their efficiency, and standard tests should be developed to evaluate them.
