Elnaz Rahimi, Azam Biabani, Maryam Ghaljahi, Farideh Golbabaei,
Volume 14, Issue 3 (10-2024)
Abstract
Introduction: Workers who work in warm situations need clothes with better thermal regulation. Nowadays, improving the thermal regulation properties of cotton fabric by treating it with phase change materials (PCMs) has been considered. The type of fabric plays an important role in providing thermal comfort. Cotton fabric is the most popular raw material in the textile industry due to its distinctive features. Therefore, this systematic review aims to investigate the effects of PCM nanoencapsulation in commonly used cotton fabrics, including morphology, thermal properties, thermal stability, tensile strength, abrasion resistance, leakage, water absorption, washing ability, and breathability of the fabric, related challenges, and future research trends.
Material and Methods: This research was conducted with the papers obtained from the systematic search in Science Direct, Web of Sciences, Scopus, and PubMed databases. Keywords “nanoencapsulated phase change materials”, “nanoenhanced phase change materials”, “cotton”, “cotton fabric”, and “cotton textiles” were used.
Results: Of the 1251 studies identified through search databases, 13 were selected according to the entry criteria. The results revealed that in all the studies, PCM nanocapsules were successfully synthesized and inserted into the cotton fabric, improving the fabric’s thermal properties. Most studies used in situ polymerization and mini-emulsion polymerization for nanoencapsulation. The pad-dry-cure method was also widely used for applying nanocapsules to cotton fabric.
Conclusion: This systematic review showed that synthesized nanocapsules of phase change materials and applied them to cotton fabric can improve the thermoregulating properties of the fabric. It is suggested to expand the research to design thermoregulating clothes made from treated fabrics and investigate their cooling performance.
Elnaz Rahimi, Saba Kalantary, Aziz Babapoor, Habibollah Dehghan, Anoshirvan Kazemnejad, Mohammadreza Monazzam Esmaeelpour,
Volume 15, Issue 2 (7-2025)
Abstract
Introduction: Wearable thermal management systems and phase change materials (PCMs) have emerged as effective solutions for regulating body temperature and storing thermal energy. This study focuses on synthesizing and thermal optimizing a sodium sulfate decahydrate-based nanocomposite incorporating various nanoparticles to improve its performance for personal thermal regulation applications.
Material and Methods: The composite was prepared using sodium sulfate decahydrate as the base PCM. Potassium chloride (KCl) was added to adjust the melting point, borax (STD) served as a nucleating agent, and sodium polyacrylate (SPA) was included as a thickening agent to suppress phase separation. To evaluate the effect of nanoparticle additives, 0.05 wt.% of aluminum oxide (Al₂O₃), iron oxide (Fe₂O₃), graphene oxide (GO), and titanium dioxide (TiO₂) were separately incorporated into the base formulation. A field emission scanning electron microscope (FESEM) was used to analyze the surface morphology of the resulting nanocomposites. Differential scanning calorimetry (DSC) assessed thermal properties, including phase transition temperatures (melting and freezing points) and latent heat.
Results: Differential scanning calorimetry (DSC) analysis indicated that sample S-5-5 comprising sodium sulfate decahydrate with 3 wt.% KCl, 5 wt.% STD and SPA exhibited a melting temperature of 29.5 °C and a latent heat of 120 J/g. This composition remained stable without phase separation. The incorporation of nanoparticles raised the melting point of the base PCM by 0.6 to 1.72 °C. Aluminum oxide (Al₂O₃) and iron oxide (Fe₂O₃) reduced the latent heat of fusion, whereas GO and TiO₂ increased it.
Conclusion: These findings confirm that the thermal properties of sodium sulfate decahydrate-based PCMs can be tailored by including specific additives and nanoparticles. Hydrated salt nanocomposites demonstrate strong potential as PCMs for wearable body temperature regulation.
