Journal of Health and Safety at Work

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Introduction: In real Conditions, pollution emission are mostly released as mixed components rather than a single pure emission of the chemicals. In this study, a miniature stirred tank bioreactor was optimized for treatment of waste gas containing BTX (benzene, toluene and xylene).

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Material and Method: The sludge of an oil refinery was sampled based on the assumption that it contains BTX-degrading microorganisms and used as microbial consortium. Also, silicone oil was added to improve removal efficiency. The operational parameters of the bioreactor were optimized during the study.

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Result: The removal efficiency and elimination capacity of benzene, toluene and xylene vapors simultaneously in the presence of 10% silicone oil as an organic phase showed increasing trend up to the concentrations of 1730 mg/m3, 1710 mg/m3 and 1380 mg/m3, respectively. In these concentrations the removal efficiency and elimination capacity of benzene were 100% and 59 g/m3/h, toluene 100% and 58 g/m3/h and xylene 91% and 42 g/m3/h, respectively. The total removal efficiency and elimination capacity for BTX were 91 to 100% and 159 g/m3/h, respectively.

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Conclusion: It was shown that presence of 10% silicone oil increased 44.5% in total removal efficiency of BTX. The microbiological experiments on the bioreactor media showed that three spices of Pseudomonas putida, Chryseobacterium and Ralstonia pickettii can be found, when BTX ware treated. This work revealed that two phase partition bioreactors (TPPBs) can be successful method for the treatment of streams contaminated with BTX.

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Introduction: Rapid population growth and industrialization have increased chemical pollutants. Some studies show that employee exposure to formaldehyde in industrial places, hospitals, and laboratory settings is more than the allowed limits. Therefore, it is necessary to implement a proper control system to reduce this exposure. This study aimed to synthesize Ag3PO4/TiO2 nanocomposite, determine its morphological and structural characteristics, and test the degradation efficiency of this photocatalyst on formaldehyde.
Material and Methods: Ag3PO4/TiO2 composites were synthesized via an in-situ precipitation method. The physicochemical, morphological, and optical properties of the synthesized sample were investigated by employing the BET method, X-ray diffraction (XRD), UV–visible absorption spectroscopy, and scanning electron microscopy (SEM). The photocatalyst degradation efficiency test was performed on gaseous formaldehyde in a 3.2-liter photoreactor under visible light radiation.
Results: The UV–Vis absorption spectrum of the Ag3PO4/TiO2 sample noticeably shifted to the visible light region compared to that of the TiO2. The bandgap energy of the nanocomposite was 2.3 eV. The SEM image demonstrated that the average particle size of the nanocomposite was about 102 nm. The result of the degradation efficiency tests revealed that 63% of the formaldehyde was removed under visible light irradiation after 90 minutes by the Ag3PO4/TiO2 photocatalyst.
Conclusion: The adopted synthesis method adopted was highly efficient and appropriate for the synthesis of Ag3PO4/TiO2 nanocomposite according to the analyses. The Ag3PO4/TiO2 photocatalyst performed well under visible light radiation and could be used in pollution control systems.