Journal of Health and Safety at Work

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Introduction: Human and environment exposed to harmful factors, as the result of industrial pollutants. Volatile organic compounds (VOCs) play important role in photochemical reactions in troposphere layer of atmosphere and results in production of ozone and photochemical oxidants.

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Material and Method: In this study, a miniature stirred tank bioreactor was designed for treatment of waste gas containing xylene. In the next step, the bioreactor incubated with microbial consortiums with ratio of 1 to 3. The performance of bioreactor in treatment of xylene vapors in presence of 10% silicone oil, as an organic phase was assessed in concentrations ranging from 551 mg/m3 to 3330 mg/m3 for 432 hours.

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Result: The results of xylene biodegradation showed that removal efficiency up to the concentrations of 2756 mg/m3 was 82 percent. Moreover, adding 10% silicone oil increased removal efficiency of BTX by 85.7% in comparison with context without organic phase. The microbiological experiments on the bioreactor media showed that three spices of Pseudomonas putida, Chryseobacterium and Ralstonia pickettii were found, in the presence of xylene.

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Conclusion: Overall, the results of the present research revealed that application of two phase stirred tank bioreactors (TPPBs) for xylene from contaminated treatment of streams was successful.

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Introduction: Volatile organic compounds such as xylene, which are the main constituents of the oil and petrochemical industries, have serious impacts on health and can cause adverse effects on the environment. It is clear that release of these compounds into the environment should be controlled. The two-phases partitioning stirred tank bio-reactor is one of the newest methods for treating these compounds which have few side-effects besides of having appropriate efficiency since itdestroyscontaminant completely and transform it tosafer compounds.

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Material and Method: In this study, a two phase partitioning stirred tank bio-reactor, in lab scale, was used for treating the gas stream containing xylene vapors. The aqueous phase containing the bacteria Pseudomonas putida and nutrients inserted into the bioreactor with 3:1 ratio and system performance was evaluated for 432 hours in the concentration range of 1000 mg/m3 to 3500 mg/m3

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Result: Empirical findings of this study showed that the maximum, minimum and average of removal of xylene vapors by stirred two phase bioreactor containing a pure strain of Pseudomonas putida were 94.00, 54.00 and 84.94 percent, respectively.Furthermore, maximum, minimum and average of elimination capacity of xylene were obtained 93.00,24.00 and 62.02 g/m3/h, respectively

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Conclusion: Overall, the results of the present research revealed that the application of two phase stirred tank bioreactors (TPPBs) containing pure strains of Pseudomonas putida was successful for treatment of air streams with xylene.

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Introduction: Volatile organic compounds such as xylene are one of the main air pollutants. Adsorption method are of the most common methods used in the control of volatile organic compounds. The aim of this study was to investigate the xylene removal from air through nano activated carbon adsorbent in comparison with NIOSH approved carbon adsorbent.
 

Material and Method: Xylene adsorption tests on nano activated carbon and activated carbon in static mode (batch) were done in glass vials with volume of 10 ml. Gas chromatography with FID detector was used for analysis. Various variables including contact time, amount of adsorbent, concentration of xylene, and temperature were studied.
 

Results: Absorption capacity of xylene at ambient temperature (25° C) in static mode and duration of 10 minutes for activated carbon and nano activated carbon was obtained 349.8 and 435 mg/g, respectively. Results of Scanning Electron Microscope (SEM) images of nano activated carbon showed particle size pf less than 100 nm. Furthermore, Transmission Electron Microscope (TEM) pictures showed particle size of 30 nm. XRD images also showed cube structure of nano activated carbon adsorbent.
 

Conclusion: The results showed that adsorption capacity at constant humidity increased by raising in temperature and contact time. What is more, nano activated carbon absorbent showed greater absorption capacity for xylene removal compared to activated carbon absorbent

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Introduction: Volatile organic compounds from industrial activities are one of the most important pollutants released into the air and have adverse effects on human and environment. Therefore, they should be removed before releasing into atmosphere. The aim of the study was to evaluate xylene removal from air by nano-grapheme and nano-graphene oxide in comparison with activated carbon adsorbent.

Material and Method:  After preparing adsorbents of activated carbon, nano-graphene, and nano-graphene oxide, experiments adsorption capacity in static mode (Batch) were carried out in a glass vial. Some variables including contact time, the amount of adsorbent, the concentration of xylene, and the temperature were studied. Langmuir absorption isotherms were used in order to study the adsorption capacity of xylene on adsorbents. Moreover, sample analysis was done by gas chromatography with Flame Ionization Detector (GC-FID).

Results: The adsorption capacities of activated carbon, nano-graphene oxide and nano-graphene for removal of xylene were obtained 349.8, 14.5, and 490 mg/g, respectively. The results of Scanning Electron Microscope (SEM) for nano-graphene and nano-graphene oxide showed particle size of less than 100 nm. While, the results of Transmission Electron Microscope (TEM) showed particle size of 45nm for nano-graphene and 65 nm for nano-graphene oxide. Also, X-Ray Diffraction (XRD) showed cube structure of nano-adsorbents.

Conclusion: In constant humidity, increase in exposure time and temperature caused an increase in the adsorption capacity. The results revealed greater adsorption capacity of xylene removal for nano-graphene compared to the activated carbon, and nano-graphene oxide.

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Introduction: Volatile organic compounds (VOCs) are hazardous toxic pollutants in the air, which are released from various industrial sources. Due to the adverse effects of xylene on health, the effective removal of VOCs from the air by nano sorbents is crucial. In this study, nanographene (NG) and nanographene oxide (NGO) were used as adsorbents to investigate the efficiency of xylene removal.
Material and Methods: In this study, in order to investigate the absorption efficiency of nanographene and nanographene oxide after the synthesis of nano absorbents in a dynamic system, xylene vapor was produced in a chamber in pure air and stored in a Tedlar sampling bag and then transferred to the adsorbent. Subsequently, the effect of various parameters such as xylene concentration, inlet air flow rate, and absorbent mass values at 32% humidity and 25°C temperature on the absorption rate and performance of the desired absorbents was investigated. Finally, the gas chromatographic flame ion detector (GC-FID) determined the concentration of xylene in air after the adsorption-desorption process.
Results: The average adsorption efficiencies for NG and NGO were found to be 96.8% and 17.5%, respectively. The characteristics of the NG and NGO adsorbents indicated that the particle size range was less than 100 nanometers.
Conclusion: The results demonstrated that the adsorption efficiency of NG for the removal of xylene from the air is higher than that of NGO. The GC-MS method validated the proposed approach in real air samples.