Background and Aim: Problems related to conventional Fenton oxidation, including neccesity of having a low pH and production of considerable amounts of sludge, have prompted researchers to consider chelating agents to improve the pH operating range and iron nano-oxide particles to reduce excess sludge. The main objective of this study was to remove pyrene from contaminated soils by a modified Fenton oxidation method at neutral pH.
Materials and Methods: Experiments were conducted using various concentrations of H2O2 (0-500 mM), iron nano-oxides (0-60 mM), reaction times (0.5-24 hours) and several chelating agents, namely, sodium pyrophosphate, ethylene diamine tetra-acetic acid, sodium citrate, fulvic and humic acids, to eliminate pyrene from soil (concentrations of 100-500 mg/kg).
Results: The efficiency of removal of pyrene at an initial concentration of 100 mg/kg was 99 % at the following reaction conditions: H2O2 and iron nano-oxide concentrations of 300 mM and 30 mM, respectively pH=3 and a reaction time of 6 hours. The initial pyrene concentration of 100 mg/kg decreased to 7 mg/kg at optimum conditions using sodium pyrophosphate as the chelating agent at pH 7.
Conclusion: The modified Fenton oxidation method, using iron nano-oxide at optimum conditions as defined in this research, is an efficient alternative for chemical remediation or pre-treatment of soils contaminated wih pyrene at neutral pH.
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Scientific Journal of School of Public Health and Institute of Public Health Research /85
Vol. 11, No. 2, Summer 2013
Forecasting ambient air pollutants by time series models in Kerman, Iran
Mansouri, F., MS.c. Student, Dept of Environmental Health Engineering, Faculty of Public Health, Kerman Medical University, Kerman, Iran
Khanjani, N., Ph.D. Assistant Professor, Department of Epidemiology and Department of Environmental Health, Faculty of Public Health, Kerman Medical University, Kerman, Iran - Corresponding author: n_khanjani@kmu.ac.ir
Rananadeh Kalankesh, L., MS.c. Student, Department of Environmental Health Engineering, Faculty of Public Health, Kerman Medical University, Kerman, Iran
Pourmousa, R., MS.c. Lecturer, Department of Statistics, School of Mathematics and Statistics, Shahid Bahonar University, Kerman, Iran
Received: Apr 3, 2012 Accepted: Feb 14, 2013
ABSTRACT
Background and Aim: Air pollution is one of the most important problems of big cities in developing countries and can have several negative health effects on humans. Therefore studying these pollutants can help in developing programs for air pollution control. The aim of this study was to estimate and predict the changes of air pollutants in Kerman, Iran.
Materials and Methods: In this ecological study, data about seven important air pollutants in Kerman including NO, CO, NO2, NOx, PM10, SO2 and O3 from March 2006 until September 2010 was inquired from the Kerman Province Environmental Protection Agency. Then the data was calculated as averages per month and by incorporating time series models, predictions were done for each pollutant.
Results: All of the pollutants were steady in Kerman, except CO which is significantly decreasing and PM10 which is increasing. All of the pollutants had a seasonal pattern. Time series models with a 12, 3, 8, 12, 12, 12 and 6 month seasonal pattern were fit for O3 , SO2 , PM10 , NOx , NO2 , CO and NO consecutively.
Conclusion: The production of ambient CO is decreasing in Kerman and one reason is probably replacing and retiring old automobiles. However PM10 is increasing in Kerman and in most seasons it is above standard and therefore control initiatives should be implemented.
Background and Aim: A ssociations between air pollution and morbidity have been reported in several studies. Due to limited publications in the literature for Iran, this study aimed to determine the association between air pollution and hospital admissions of respiratory disease patients in Tabriz, Iran.
Materials and Methods: The methodology used in this study was case -crossover and the artificial neural network model. The variables of the model included air quality, hospital admission and air pollutants. Daily hospital admission data were collected from five hospitals in Tabriz, Iran based on the International Classification of Diseases (ICD-10) , air quality data including NO2, SO2, CO, PM10 and O3 from the six fixed online air quality monitoring stations, and the daily mean temperature and relative humidity data for the same period from the East Azerbaijan Meteorological Bureau.
Results : P articulate matter with a median aerometric diameter <10 μm (PM10) was found to be the most important pollutant affecting respiratory hospital admissions. The ANNs data showed that the most important causes of hospital admissions were for COPD NO2, NO and CO, for respiratory infections PM10, and for asthma PM10, O3 and CO. The highest associations were observed between hospital admissions due to COPD and asthma in females and those due to respiratory infections in males. The elderly (individuals over 65 years old) were at the highest risk.
Conclusion: The results show a significant relation between air pollutants and respiratory hospital admissions in Tabriz, Iran. The importance and necessity of enforcement of existing regulations and enacting laws to prevent and control the adverse health effects of air pollution are confirmed.
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